Experimental constraints on degassing and permeability in volcanic conduit flow

This study assesses the effect of decompression rate on two processes that directly influence the behavior of volcanic eruptions: degassing and permeability in magmas. We studied the degassing of magma with experiments on hydrated natural rhyolitic glass at high pressure and temperature. From the data collected, we defined and characterized one degassing regime in equilibrium and two regimes in disequilibrium. Equilibrium bubble growth occurs when the decompression rate is slower than 0.1 MPa s^–1, while higher rates cause porosity to deviate rapidly from equilibrium, defining the first disequilibrium regime of degassing. If the deviation is large enough, a critical threshold of super-saturation is reached and bubble growth accelerates, defining the second disequilibrium regime. We studied permeability and bubble coalescence in magma with experiments using the same rhyolitic melt in open degassing conditions. Under these open conditions, we observed that bubbles start to coalesce at ~43 vol% porosity, regardless of decompression rate. Coalescence profoundly affects bubble texture and size distributions, and induces the melt to become permeable. We determined coalescence to occur on a time scale (~180 s) independent of decompression rate. We parameterized and incorporated our experimental results into a 1D conduit flow model to explore the implications of our findings on eruptive behavior of rhyolitic melts with low crystal contents stored in the upper crust. Compared to previous models that assume equilibrium degassing of the melt during ascent, the introduction of disequilibrium degassing reduces the deviation from lithostatic pressure by ~25%, the acceleration at high porosities (>50 vol%) by a factor 5, and the associated decompression rate by an order of magnitude. The integration of the time scale of coalescence to the model shows that the transition between explosive and effusive eruptive regimes is sensitive to small variations of the initial magma ascent speed, and that flow conditions near fragmentation may significantly be affected by bubble coalescence and gas escape.Editorial responsibility: D. Dingwell     

Dynamics of dissolved major (Na,K, Ca,Mg, and Si) and trace (Al,Fe, Mn,Zn, Cu,and Cr) elements along the lower Orinoco River

This study addresses the changes in dissolved major and trace element concentrations along the Orinoco River, including the mixing zone between the Orinoco and Apure Rivers. Water samples from the Apure and Orinoco Rivers were collected monthly in four sectors over a period of 15 months. Auxiliary parameters (pH, dissolved oxygen, conductivity, and temperature), total suspended sediments, dissolved organic carbon (DOC), and major (Na, K, Ca, Mg, and Si) and trace (Al, Fe, Mn, Zn, Cu, and Cr) element concentrations were measured in all sectors. The relative contribution of both rivers after the Apure–Orinoco confluence was determined using Ca as a tracer. Moreover, a mixing model was developed to determine whether dissolved species exhibit a conservative behavior during mixing. The results indicate that DOC is removed from waters during the Apure–Orinoco mixing, probably due to absorption of DOC on mineral phases supplied by the Apure River. Dissolved Na, Ca, and Mg behave conservatively during the mixing processes, and their concentrations are controlled by a dilution process. The anomaly in the temporal pattern of K in the Orinoco is caused by the input of biogenic K originating from the Apure River during the high‐water stage. The loss of dissolved Si during the low‐water stage can be explained by the uptake of Si by diatoms. Dissolved Mn, Zn, Al, and Fe showed a non‐conservative behavior during the Apure–Orinoco mixing. The removal of Mn and Zn from the dissolved phase can be explained by the formation of Mn‐oxyhydroxides and the scavenging of Zn onto Mn oxides. Dissolved Fe is controlled by redox processes, although the removals of Fe and Al due to the preferential adsorption of large organometallic complexes by mineral surfaces after the Apure–Orinoco confluence can affect the mobility of both elements during transport. The conservative behavior shown by Cu and Cr can be related to the tendency of both elements to be complexed with small organic colloids, which are not preferentially adsorbed by clays.     

Hydrocarbons in surface sediments from the Sfax coastal zone, (Tunisia) Mediterranean Sea

The Semi-enclosed Mediterranean Sea records various signals of high anthropic pressures from surrounding countries and the industrialized European countries. This is particularly true for oil pollution. Although accounting for 1% of the world's ocean surface, it receives about 25% of the petroleum inputs to the ocean. To achieve a global budget we need to collect information from different parts of the Mediterranean. Particularly, we focus in this paper on the Southern Mediterranean, where data are presently very scarce. In this context, the University of Sfax has undertaken an estimation of hydrocarbon pollution along the coasts of Sfax and Gabès Gulf. Non-aromatic hydrocarbons were analysed in 8 surface sediments by FT/IR and GC/MS. Non-aromatic hydrocarbon concentrations vary in the range 310-1406 microg g(-1) sediments dry weight, which is high, compared to other Mediterranean sites. GC/MS data indicate a large group of unresolved compounds suggesting a petroleum contamination, confirmed by the identification of hopanes with predominant C29 and C30alpha,beta compounds and steranes with predominance of C27 over C28) and C29 compounds.     

Pesticide contamination of the coastline of Martinique

In January and February 2002, the presence of certain agricultural pesticides throughout the coastline of the Caribbean island of Martinique was investigated. The tropical climate of the French West Indies is suitable for banana production, which requires intensive use of pesticides. An inventory of all pesticides used on the island (compounds and tonnage) was compiled. Surveys and analyses revealed the presence of pesticides in the plumes of seven rivers. The organochlorine chlordecone and metabolites of aldicarb were detected at nearly all of the monitored sites, even though the use of chlordecone has been prohibited since 1993. Two triazines (ametryn and simazine) were also identified. The concentrations of carbamates and triazines detected in the water and sediment samples from Martinique are comparable to those reported for mainland France. Chlordecone concentrations in the sediment and particulate matter samples were, however, particularly high in the samples from Martinique. Toxicological implications are discussed. Of particular concern are the high levels of chlordecone (which is bioaccumulating and carcinogenic) and further monitoring of this compound is recommended, especially in fish and other sea-food products.     

A multifractal formalism for vector-valued random fields based on wavelet analysis: application to turbulent velocity and vorticity 3D numerical data

Extreme atmospheric events are intimately related to the statistics of atmospheric turbulent velocities. These, in turn, exhibit multifractal scaling, which is determining the nature of the asymptotic behavior of velocities, and whose parameter evaluation is therefore of great interest currently. We combine singular value decomposition techniques and wavelet transform analysis to generalize the multifractal formalism to vector-valued random fields. The so-called Tensorial Wavelet Transform Modulus Maxima (TWTMM) method is calibrated on synthetic self-similar 2D vector-valued multifractal measures and monofractal 3D vector-valued fractional Brownian fields. We report the results of some application of the TWTMM method to turbulent velocity and vorticity fields generated by direct numerical simulations of the incompressible Navier–Stokes equations. This study reveals the existence of an intimate relationship between the singularity spectra of these two vector fields which are found significantly more intermittent than previously estimated from longitudinal and transverse velocity increment statistics.

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Use of a Sodar to Improve the Forecast of Fogs and Low Clouds on Airports

A sodar was deployed at Roissy–Charles de Gaulle airport near Paris, France, in 2008 with the aim of improving the forecast of low visibility conditions there. During the winter of 2008–2009, an experiment was conducted that showed that the sodar can effectively detect and locate the top of fog layers which is signaled by a strong peak of acoustic reflectivity. The peak is generated by turbulence activity in the inversion layer that contrasts sharply with the low reflectivity recorded in the fog layer below. A specific version of the 1D-forecast model deployed at Roissy for low visibility conditions (COBEL-ISBA) was developed in which fogs’ thicknesses are initialized by the sodar measurements rather than the information derived from the down-welling IR fluxes observed on the site. It was tested on data archived during the winters of 2008–2009 and 2009–2010 and compared to the version of the model presently operational. The results show a significant improvement—dissipation times of fogs are better predicted.     

Temporal variability of suspended sediment sources in an alpine catchment combining river/rainfall monitoring and sediment fingerprinting

Influence of the rainfall regime on erosion and transfer of suspended sediment in a 905‐km² mountainous catchment of the southern French Alps was investigated by combining sediment monitoring, rainfall data, and sediment fingerprinting (based on geochemistry and radionuclide concentrations). Suspended sediment yields were monitored between October 2007 and December 2009 in four subcatchments (22–713 km²). Automatic sediment sampling was triggered during floods to trace the sediment origin in the catchment. Sediment exports at the river catchment outlet (330 ± 100 t km^‐2 yr^‐1) were mainly driven (80%) by widespread rainfall events (long duration, low intensities). In contrast, heavy, local and short duration storms, generated high peak discharges and suspended sediment concentrations in small upstream torrents. However, these upstream floods had generally not the capacity to transfer the sediment down to the catchment outlet and the bulk of this fine sediment deposited along downstream sections of the river. This study also confirmed the important contribution of black marls (up to 70%) to sediment transported in rivers, although this substrate only occupies c. 10% of the total catchment surface. Sediment exports generated by local convective storms varied significantly at both intra‐ and inter‐flood scales, because of spatial heterogeneity of rainfall. However, black marls/marly limestones contribution remained systematically high. In contrast, widespread flood events that generate the bulk of annual sediment supply at the outlet were characterized by a more stable lithologic composition and by a larger contribution of limestones/marls, Quaternary deposits and conglomerates, which corroborates the results of a previous sediment fingerprinting study conducted on riverbed sediment. Copyright © 2012 John Wiley & Sons, Ltd.     

gvSOS: A New Client for the OGC® Sensor Observation Service Interface Standard

A key problem with sensor networks is achieving interoperability between different networks potentially built using different software and hardware platforms. Services interfaced by the Open Geospatial Consortium (OGC) specifications allow GIS clients to access geospatial data without knowing the details about how these data are gathered or stored. Currently, OGC is working on a set of interoperable interfaces and metadata encodings known as Sensor Web Enablement (SWE) that enables the integration of heterogeneous sensor systems and measurements into geospatial information infrastructures. In this article we present the implementation of gvSOS, a new module for gvSIG to connect to Sensor Observation Services (SOS). The gvSOS client module allows gvSIG users to interact with SOS servers, displaying the information gathered by sensors as a layer composed by features. We present the software engineering development process followed to build the module. For each step of the process we specify the main obstacles found during the development such as restrictions of the gvSIG architecture, inaccuracies in the OGC specifications, and a set of common problems found in current SOS server implementations available on the Internet. For most of the problems found we propose a solution, or at least we present a path that might lead to it.     

The Northwestern (Maghreb) boundary of the Nubia (Africa) Plate

A study of the present compressional deformation of the Northwestern (Maghreb) Nubia (Africa) margin is derived from the analysis of more than 20,000 km of seismic profiles. In the western part the compression is distributed in a large zone with on-land compression in Algeria, mainly strike-slip deformation on the Algerian margin and folds and strike-slip faulting in Eastern Spain. In the middle of the Algerian margin, around Algiers, the evidences of compression become more obvious. In this area a ridge trending N–S that is interpreted as a middle to late Miocene spreading center interacted with the transpressional margin that trends E–W. North of the location of the Boumerdes–Zemmouri earthquake the oceanic crust is deformed by blind thrusts up to 60 km from the coast. These thrusts are south dipping and with the northward dipping thrusts located onshore form a wedge that maybe a positive flower structure at a crustal scale related to the right-lateral transpression of the margin. In the eastern part of the Northwestern (Maghreb) Nubia (Africa) Deformed Belt, off eastern Algeria and Tunisia, the deformation is more intense but limited to the north by the continental slope. Large late Miocene Tortonian folds are cut by the Messinian erosional surface but the present deformation is also evident. It is suggested that the deformation with a double vergence may be followed up to the north of Sicily. After the docking (18 Ma) of the Kabylies to the Africa Plate, the crust has been thinned and the Algerian Basin opened during the middle-late Miocene with an E–W direction. From the late Miocene to the Present the margin has been rethickened by transpression and uplifted.     

Utilisation de dépôts d'argile sur lame de verre pour leur étude en spectroscopie infrarouge

IR spectra of clay samples can be collected in transmission through oriented deposits onto glass slide and are similar to the IR spectra of the same samples obtained by traditional way (KBr pellets). As examples, it is shown that it is possible to differentiate dickite from kaolinite and smectites of various chemistries, as easily by both ways. It is thus possible to use oriented clay deposits onto glass slide for both XRD and IR studies and to easily take benefit of the complementarity of both techniques. To cite this article: S. Petit et al., C. R. Geoscience 335 (2003).