Cl and Na Fluxes in an Andean Foreland Basin of the Peruvian Amazon: An Anthropogenic Impact Evidence

The dissolved load of the Amazon River is generally considered to be lowly impacted by anthropogenic activities. In this work, based on the chemical and hydrological database of the Environmental Research Observatory—HYBAM (http://www.ore-hybam.org), we explore the importance of the Peruvian Foreland petroleum activity on the dissolved Na and Cl fluxes of the Amazon River. The main result of this study allows us suggesting that oil extraction activity, concentrated in the El Tigre River basin, a small foreland watershed in the Peruvian Amazon, influenced drastically the Na and Cl exportation of the Amazon River during the 2006–2007 period. During these years,  the dissolved exportations of this basin represented almost 20 % of the annual dissolved Cl Amazon flux and almost 12 % of the annual dissolved Na Amazon flux for a mean annual discharge <1 % of the Amazon River discharge. Since the last decades, the anthropogenic activities are increasing over the whole Amazon basin, especially in Andean countries. In this context, our results demonstrate that extractive activity cannot be considered as negligible on the hydro-chemistry of the Amazonian Rivers especially for the weathering budget estimation based on river-dissolved loads. Moreover, Cl and Na can be used to trace the formation waters derived from oil extraction at a large spatial scale. The environmental impacts of contaminants associated with deep water released to the hydrosystem (polycyclic aromatics hydrocarbons, metallic trace elements, etc.) at local and regional scales are still underestimated and should be monitored to map their local and regional influence and to prevent their risks on human health.     

Zinc mobility and speciation in soil covered by contaminated dredged sediment using micrometer-scale and bulk-averaging X-ray fluorescence, absorption and diffraction techniques

The mobility and solid-state speciation of zinc in a pseudogley soil (pH = 8.2-8.3) before and after contamination by land-disposition of a dredged sediment ([Zn] = 6600 mg kg⁻¹) affected by smelter operations were studied in a 50 m² pilot-scale test site and the laboratory using state-of-the-art synchrotron-based techniques. Sediment disposition on land caused the migration of micrometer-sized, smelter-related, sphalerite (ZnS) and franklinite (ZnFe₂O₄) grains and dissolved Zn from the sediment downwards to a soil depth of 20 cm over a period of 18 months. Gravitational movement of fine-grained metal contaminants probably occurred continuously, while peaks of Zn leaching were observed in the summer when the oxidative dissolution of ZnS was favored by non-flooding conditions. The Zn concentration in the <50 μm soil fraction increased from ∼61 ppm to ∼94 ppm in the first 12 months at 0-10 cm depth, and to ∼269 ppm in the first 15 months following the sediment deposition. Higher Zn concentrations and enrichments were observed in the fine (<2 μm) and very fine (<0.2 μm) fractions after 15 months (480 mg kg⁻¹ and 1000 mg kg⁻¹, respectively), compared to 200 mg kg⁻¹ in the <2 μm fraction of the initial soil. In total, 1.2% of the Zn initially present in the sediment was released to the environment after 15 months, representing an integrated quantity of ∼4 kg Zn over an area of 50 m². Microfocused X-ray fluorescence (XRF), diffraction (XRD) and extended X-ray absorption fine structure (EXAFS) spectroscopy techniques were used to image chemical associations of Zn with Fe and Mn, and to identify mineral and Zn species in selected points-of-interest in the uncontaminated and contaminated soil. Bulk average powder EXAFS spectroscopy was used to quantify the proportion of each Zn species in the soil. In the uncontaminated soil, Zn is largely speciated as Zn-containing phyllosilicate, and to a minor extent as zincochromite (ZnCr₂O₄), ^IVZn-sorbed turbostratic birnessite (δ-MnO₂), and Zn-substituted goethite. In the upper 0-10 cm of the contaminated soil, ∼60 ± 10% of total Zn is present as ZnS inherited from the overlying sediment. Poorly-crystalline Zn-sorbed Fe (oxyhydr)oxides and zinciferous phyllosilicate amount to ∼20-30 ± 10% each and, therefore, make up most of the remaining Zn. Smaller amounts of franklinite (ZnFe₂O₄), Zn-birnessite and Zn-goethite were also detected. Further solubilization of the Zn inventory in the sediment, and also remobilization of Zn from the poorly-crystalline neoformed Fe (oxyhydr)oxide precipitates, are expected over time. This study shows that land deposition of contaminated dredged sediments is a source of Zn for the covered soil and, consequently, presents environmental hazards. Remediation technologies should be devised to either sequester Zn into sparingly soluble crystalline phases, or remove Zn by collecting leachates beneath the sediment.     

Diachronic metamorphic and structural evolution of the Connecticut Valley–Gaspé trough,Northern Appalachians

The Connecticut Valley–Gaspé (CVG) trough represents a major, orogen-scale Silurian–Devonian basin of the Northern Appalachians. From Gaspé Peninsula to southern New England, the CVG trough has experienced a contrasting metamorphic and structural evolution during the Acadian orogeny. Along its strike, the CVG trough is characterized by increasing strain and polyphase structures, and by variations in the intensity of regional metamorphism and contrasting abundance of c. 390–370 Ma granitic intrusions. In southern Quebec and northern Vermont, a series of NW–SE transects across the CVG trough have been studied in order to better understand these along-strike variations. Detailed structural analyses, combined with phase equilibria modelling, Raman spectrometry, and muscovite ⁴⁰Ar/³⁹Ar dating highlight a progressive and incremental deformation involving south–north variation in the timing of metamorphism. Deformation evolves from a D₁ crustal thickening event which originates in Vermont and progresses to southern Québec where it peaked at 0.6 GPa/380°C at c. 375 Ma. This was followed by a D₂ event associated with continuous burial in Vermont from 378 to 355 Ma, which produced peak metamorphic conditions of 0.85 GPa/380°C and exhumation in Quebec from 368 to 360 Ma. The D₃ compressional exhumation event also evolved from south to north from 345 to 335 Ma. D₁ to D₃ deformation events form part of a continuum with an along-strike propagation rate of ~50 km/Ma During D₁, the burial depth varied by more than 15 km between southern Quebec and Vermont, and this can be attributed to the occurrence of a major crustal indenter, the Bronson Hill Arc massif, in the New England segment of the Acadian collision zone.     

Mn, Fe, Zn and As speciation in a fast-growing ferromanganese marine nodule

The speciation of Mn, Fe, As, and Zn in a fast-growing (0.02mm/yr), shallow-marine, ferromanganese nodule has been examined by micro X-ray fluorescence, micro X-ray diffraction, and micro X-ray absorption spectroscopy. This nodule exhibits alternating Fe-rich and Mn-rich layers reflecting redox variations in water chemistry. Fe occurs as two-line ferrihydrite. The As is strictly associated with Fe and is mostly pentavalent, with an environment similar to that of As sorbed on or coprecipitated with synthetic ferrihydrite. The Mn is in the form of turbostratic birnessite with ∼10% trivalent manganese in the layers and probably ∼8% corner-sharing metal octahedra in the interlayers. The Zn is enriched on the rim of the nodule, associated with Mn. The Zn is completely (>90%) tetrahedrally coordinated and sorbed in the interlayers of birnessite on vacant layer Mn sites. The Zn and Mn species are similar to ones found in soils, suggesting common structural principles despite the differing formation conditions in these systems.     

Optimal deterministic guidance for bounded-thrust spacecrafts

The minimum-propellant deterministic guidance law for bounded-thrust, constant jetexhaust velocity, spacecrafts is developed using the neighboring extremal theory. Minimization of the first-order variation in cost between a multi-burn nominal extremal and the perturbed trajectory eliminates all correction strategies except small changes in the nominal thrust-on, thrust-off times and small rotations of the thrust vector. Optimal values of these corrective controls for fixed values of initial state deviations, x ₀, are found by minimizing the second variation in cost subject to the variational state and adjoint equations — an accessory minimum problem. The solution takes the linear feedback form u=A ^–1 ₂₂ A ₂₁x ₀, where the matricesA ₂₂ andA ₂₁ are functions only of transition matrices calculated along the nominal trajectory. The solution is applied to a three-burn Earth-Mars transfer.     

Adaptive model of plankton dynamics for the North Atlantic

Plankton ecosystems in the North Atlantic display strong regional and interannual variability in productivity and trophic structure, which cannot be captured by simple plankton models. Additional compartments subdividing functional groups can increase predictive power, but the high number of parameters tends to compromise portability and robustness of model predictions. An alternative strategy is to use property state variables, such as cell size, normally considered constant parameters in ecosystem models, to define the structure of functional groups in terms of both behaviour and response to physical forcing. This strategy may allow us to simulate realistically regional and temporal differences among plankton communities while keeping model complexity at a minimum.We fit a model of plankton and DOM dynamics globally and individually to observed climatologies at three diverse locations in the North Atlantic. Introducing additional property state variables is shown to improve the model fit both locally and globally, make the model more portable, and help identify model deficiencies. The zooplankton formulation exerts strong control on model performance. Our results suggest that the current paradigm on zooplankton allometric functional relationships might be at odds with observed plankton dynamics. Our parameter estimation resulted in more realistic estimates of parameters important for primary production than previous data assimilation studies.Property state variables generate complex emergent functional relationships, and might be used like tracers to differentiate between locally produced and advected biomass. The model results suggest that the observed temperature dependence of heterotrophic growth efficiency [Rivkin, R.B., Legendre, L., 2001. Biogenic carbon cycling in the upper ocean: effects of microbial respiration. Science 291 (5512) 2398-2400] could be an emergent relation due to intercorrelations among temperature, nutrient concentration and growth efficiency. A major advantage of using property state variables is that no additional parameters are required, such that differences in model performance can be directly related to model structure rather than parameter tuning.     

Topological changes of the photospheric magnetic field inside active regions: A prelude to flares?

The detection of magnetic field variations as a signature of flaring activity is one of the main goals in solar physics. Past efforts gave apparently no unambiguous observations of systematic changes. In the present study, we discuss recent results from observations that scaling laws of turbulent current helicity inside a given flaring active region change in response to large flares in that active region. Such changes can be related to the evolution of current structures by a simple geometrical argument, which has been tested using high Reynolds number direct numerical simulations of the MHD equations. Interpretation of the observed data within this picture indicates that the change in scaling behavior of the current helicity seems to be associated with a topological reorganization of the footpoint of the magnetic field loops, namely with the dissipation of small scales structures in turbulent media.     

The contribution to IHY from the COST296 Action MIERS: Mitigation of Ionospheric Effects on Radio Systems

The objective of the COST296 Action MIERS (Mitigation of Ionospheric Effects on Radio Systems) is to develop an increased knowledge of the effects imposed by the ionosphere on practical radio systems, and for the development and implementation of techniques to mitigate the deleterious effects of the ionosphere on such systems (http://www.cost296.rl.ac.uk). The COST296 Community contributes to the international efforts of IHY with scientific and outreach activities as well. After the realization of a web site hosted by Istituto Nazionale di Geofisica e Vulcanologia (INGV), developed also to promote the ionospheric physics to the open public, the COST296 Community supported an initiative addressed to the pupils of the primary school of several European Countries: the realization of a school-calendar dedicated to the Sun and to the Sun-Earth connections.     

Pre-explosive conduit conditions of the 1997 Vulcanian explosions at Soufrière Hills Volcano,Montserrat: II. Overpressure and depth distributions

A type example of Vulcanian eruptive dynamics is the series of 88 explosions that occurred between August and October 1997 at Soufrière Hills volcano on Montserrat Island. These explosions are interpreted to be caused by the pressurization of a conduit by a shallow highly crystalline and degassed magma plug. We test such an interpretation by combining the pressures and porosities of the pre-explosive magma column proposed by Burgisser et al. (2010, doi:10.1016/j.jvolgeores.2010.04.008) into a physical model that reconstructs a depth-referenced density profile of the column for four mechanisms of pressure buildup. Each mechanism yields a different overpressure profile: 1) gas accumulation, 2) conduit wall elasticity, 3) microlite crystallization, and 4) magma flowage. For the first three mechanisms, the three-part vertical layering of the conduit prior to explosion was spatially distributed as a dense cap atop the conduit with a thickness of a few tens of meters, a transition zone of 400–700 m with heterogeneous vesicularities, and, at greater depth, a more homogeneous, low-porosity zone that brings the total column length to ~ 3.5 km. A shorter column can be obtained with mechanism 4: a dense cap of less than a few meters, a heterogeneous zone of 200–500 m, and a total column length as low as 2.5 km. Inflation/deflation cycles linked to a periodic overpressure source offer a dataset that we use to constrain the four overpressure mechanisms. Magma flowage is sufficient to cause periodic edifice deformation through semi-rigid conduit walls and build overpressures able to trigger explosions. Gas accumulation below a shallow plug is also able to build such overpressures and can occur regardless of magma flowage. The concurrence of these three mechanisms offers the highest likelihood of building overpressures leading to the 1997 explosion series. We also explore the consequences of sudden (eruptive) overpressure release on our magmatic columns to assess the role of syn-explosive vesiculation and pre-fragmentation column expansion. We find that large shallow overpressures and efficient syn-explosive vesiculation cause the most dramatic pre-fragmentation expansion. This leads us to depict two end-member pictures of a Vulcanian explosion. The first case corresponds to the widely accepted view that the downward motion of a fragmentation front controls column evacuation. In the second case, syn-explosive column expansion just after overpressure release brings foamed-up magma up towards an essentially stationary and shallow fragmentation front.     

Constraints on the ore fluids in the Sando Alcalde AuAg epithermal deposit,southwestern Peru: fluid inclusions and stable isotope data

The Sando Alcalde ore deposit (southwestern Peru) has been studied in order to characterize the physicochemical parameters of the ore fluids and to determine the fluid process (mixing or boiling) which involves the precious metal mineralization. Mineralogy, ${\delta }^{18}{\mathrm{O}}_{\mathrm{quartz}}$ isotopic values and fluid inclusion data give arguments in favour of a boiling phenomenon. This conclusion corroborates fluid inclusion studies previously performed in this area on the low-sulphidation epithermal deposits of Arcata, Orcopampa and Apacheta, where boiling has been described as the main factor for ore deposition. To cite this article: A.-S. André-Mayer et al., C. R. Geoscience 337 (2005).