Petrology and geochemistry of a silicate clast from the Mount Padbury mesosiderite: Implications for metal‐silicate mixing events of mesosiderite

Abstract— Petrological and bulk geochemical studies were performed on a large silicate clast from the Mount Padbury mesosiderite. The silicate clast is composed mainly of pyroxene and plagioclase with minor amounts of ilmenite, spinel, and other accessory minerals, and it shows subophitic texture. Pyroxenes in the clast are similar to those in type 5 eucrites and could have experienced prolonged thermal metamorphism after rapid crystallization from a near‐surface melt. Ilmenite and spinel vary chemically, indicating growth under disequilibrium conditions. The clast seems to have experienced an episode of rapid reheating and cooling, possibly as a result of metal‐silicate mixing. Abundances of siderophile elements are obviously higher than in eucrites, although the clast is also extremely depleted in highly siderophile elements. The fractionated pattern can be explained by injection of Fe‐FeS melts generated by partial melting of metallic portions during metal‐silicate mixing. The silicate clast had a complex petrogenesis that could have included: 1) rapid crystallization from magma in a lava flow or a shallow intrusion; 2) prolonged thermal metamorphism to equilibrate the mineral compositions of pyroxene and plagioclase after primary crystallization; 3) metal‐silicate mixing probably caused by the impact of solid metal bodies on the surface of the mesosiderite parent body; and 4) partial melting of metal and sulfide portions (and silicate in some cases) caused by the collisional heating, which produced Fe‐FeS melts with highly fractionated siderophile elements that were injected into silicate portions along cracks and fractures.     

Double diffusive convection in a rotating system

Linear instability theory of double diffusive convection is generalized to a rotating system. For sufficiently large rotation, rotation has a stabilizing effect, and viscosity stabilizes most of oscillatory modes but destabilizes direct modes. The following behavior is found in oscillatory modes in the case of destabilizing temperature distribution and stabilizing solute distribution. With the fixed destabilizing temperature distribution (1) the system is stable when the stabilizing solute gradient is large, (2) it becomes unstable with respect to oscillatory modes when the gradient is less than a certain value. (3) When the gradient is reduced further, the system becomes stable again. This anomalous phenomenon happens only when the Prandtle number is less than unity and larger than the ratio of the diffusivity of solute and that of temperature, under the existence of rotation.     

The sea surface temperature product algorithm of the Ocean Color and Temperature Scanner (OCTS) and its accuracy

The Ocean Color and Temperature Scanner (OCTS) aboard the Advanced Earth Observing Satellite (ADEOS) can observe ocean color and sea surface temperature (SST) simultaneously. This paper explains the algorithm for the OCTS SST product in the NASDA OCTS mission. In the development of the latest, third version (V3) algorithm, the OCTS match-up dataset plays an important role, especially when the coefficients required in the MCSST equation are derived and the equation form is adjusted. As a result of the validation using the OCTS match-up dataset, the algorithm has improved the root mean square (rms) error of the OCTS SST up to 0.698°C although some problems remain in the match-up dataset used in the present study.     

A submersible study of the western intersection of the Mid-Atlantic ridge and Kane fracture zone (WMARK)

In 1994, a joint Japanese-American dive program utilizing the worlds deepest diving active research submersible (SHINKAI 6500) was carried out at the western ridge-transform intersection (RTI) of the Mid-Atlantic Ridge and Kane transform in the central North Atlantic Ocean. A total of 15 dives were completed along with surface-ship geophysical mapping of bathymetry, magnetic and gravity fields. Dives at the RTI traced the neovolcanic zone up to, and for a short distance (2.5 km) along, the Kane transform. At the RTI, the active trace of the transform is marked by a narrow valley (<50 m wide) that separates the recent lavas of the neovolcanic zone from the south wall of the transform. The south wall of the transform at the western RTI consists of a diabase section near its base between 5000 and 4600 m depth overlain by basaltic lavas, with no evidence of gabbro or deeper crustal rocks. The south wall is undergoing normal faulting with considerable strike-slip component. The lavas of the neovolcanic zone at the RTI are highly magnetized (17 A m^–1) compared to the lavas of the south wall (4 A m^–1), consistent with their age difference. The trace of the active transform changes eastwards into a prominent median ridge, which is composed of heavily sedimented and highly serpentinized peridotites. Submersible observations made from SHINKAI find that the western RTI of the Kane transform has a very different seafloor morphology and lithology compared to the eastern RTI. Large rounded massifs exposing lower crustal rocks are found on the inside corner of the eastern RTI whereas volcanic ridge and valley terrain with hooked ridges are found on the outside corner of the eastern RTI. The western RTI is much less asymmetric with both inside and outside corner crust showing a preponderance of volcanic terrain. The dominance of low-angle detachment faulting at the eastern RTI has resulted in a seafloor morphology and architecture that is diagnostic of the process whereas crust formed at the WMARK RTI must clearly be operating under a different set of conditions that suppresses the initiation of such faulting.     

Submersible observations of manganese nodule and crust deposits on the Tenpo Seamount,Northwestern Pacific

Pavements of manganese nodules and crusts and outcrops of Miocene limestones were observed on the flanks and flat top of the Tenpo Seamount during three Shinkai 2000 dives. The pre‐Miocene volcano supplied nuclei of volcanic rocks and hydrothermal manganese deposits, and subsequent slow or no sedimentation promoted deposition of abundant hydrogenetic nodules and crusts, mainly on the upper flank of the seamount. Nodule pavements generally cover calcareous sand surface sediments, while crusts cover hard outcrops composed probably of volcanic rocks. The fields of crusts and nodules are sparsely distributed with each other on scales of meters to tens of meters. The on‐site observation suggests the deposits have encountered tectonic and/or mass movements that resulted in unusual occurrences of densely stacked nodules and occasionally the nodules resting directly on crusts or hard substrates. Mineralogical and chemical compositions reveal that for nodules and crusts the encrusting manganese layers of around 1 cm thickness are composed of hydrogenetic vernadite, and diagenetic influence is negligible.     

Deposition of hydrogenetic and hydrothermal manganese minerals in the Ogasawara (Bonin) Arc Area,Northwest Pacific

A widespread distribution of hydrothermal and hydrogenetic manganese deposits is described in the results of the Hakurei‐Maru cruises conducted in the Bonin Arc areas of the West Pacific from 1984 to 1989. Manganese deposits occur in the active volcano chains, back‐arc basins, remnant back‐arc ridges, and oceanic seamounts.

The hydrogenetic iron‐manganese deposits commonly form earthly black crusts and nodules on the topographic highs of inactive ridges and old seamounts, sometimes as thick as 10 cm. They are always composed of the iron‐manganese mineral vernadite. Co and Ni contents are relatively high in the crusts from the seamounts in the open Pacific Ocean (up to 1.1% Co and 1.0% Ni). Two generations of distinct chemistry and texture are typical of these crusts, which can be compared to reported thick crusts from the Central Pacific seamounts.

The hydrothermal deposits, characterized by dense, submetallic, and gray appearance, are dominant in the recent and also in past submarine volcanoes of the island‐arc systems. Evidence of past hydrothermal activity was ascertained as fossil hydrothermal manganese deposits inside the hydrogenetic nodules or beneath the hydrogenetic crusts over the Tertiary island arc. Their component minerals are considered to be todorokite and bimessite (stable and contractible upon dehydration), having almost negligible amounts of Fe, Si, Al, Ni, Co, Zn, Pb, Cu, etc. In the small model site, the Kaikata Seamount hydrothermal area, the presumably recent hydrothermal activity has yielded thin slabs of pure manganate deposits growing downward within volcanic and sand layers.

Early diagenetic influence is negligible on nodules of this area.     

Origin of Bornite Pods in Intrusive Rocks at the Kingking Porphyry Copper-gold Deposit, Southeastern Mindanao, Philippines

At the Kingking porphyry copper-gold deposit, Compostela Valley, south-eastern Mindanao, Philippines, bornite pods occur in the brecciated parts in the biotite diorite porphyry, together with the volcanic rock and diorite fragments without associated stockworks of quartz veinlets. These pods are generally elongated in shape and measure several centimeters across their longest axes. They are composed of bornite and chalcopyrite with traces of calaverite. The δ³⁴S of bornite and subordinate chalcopyrite of bornite pods ranging from −2.2‰ to +0.1‰ are similar to the δ³⁴S of sulfides associated with quartz veinlets such as bornite and chalcopyrite ranging from −4.7‰ to ±0.0‰. This suggests that the ultimate source of sulfur is identical for bornite pods and sulfides associated with quartz veinlets. Bornite pods are associated with volcanic rock and dioritic fragments in the brecciated portion of the biotite diorite porphyry. It was observed that some dioritic fragments contain quartz veinlets, which may indicate an earlier episode of mineralization. Fragments of the earlier dioritic intrusive rocks and the volcanic rocks, together with the sulfides were incorporated into the biotite diorite porphyry magma. A molten sulfide is possible for the composition between bornite and intermediate solid solution at ∼800°C. The sulfides from the earlier dioritic intrusive rocks in the molten state were segregated and then eventually coalesce to form the bornite pods in the brecciated section of the biotite diorite porphyry.     

Seismological evidence for compositional variations at the base of the mantle transition zone under Japan Islands

Temperature and water content anomalies just above the 660-km discontinuity under the Japan Islands are estimated from seismological observations. Two sets of seismological observations of P-wave velocity perturbations and depth variations of the 660-km discontinuity are used, which are (1) long-wavelength (~ 500 km) variations from seismic tomography based on a grid parameterization and waveform analysis of ScS reverberations and (2) moderate-wavelength (~ 150 km) variations from seismic tomography with a block parameterization and receiver-function analysis. To estimate temperature and water content anomalies, partial derivatives of velocity and depth variations with respect to temperature and water content determined by mineral physics studies are used. Under Southwest Japan, low temperature and high water-content anomalies are obtained from both sets of seismological observations, which have already been found by a previous study. Under Northeast Japan, however, there are discrepancies between the results estimated from the two data sets, possibly due to the different resolution scales. This discrepancy is dismissed when examining distributions of the temperature and water content anomalies. These anomalies can be grouped into two geographical locations, one group under Southwest Japan, the other under Northeast Japan. The two groups are clearly separated and exhibit common features in both sets of the seismological observations. The grouping is interpreted by a compositional difference between the subducting Pacific slab under Southwest Japan and a normal mantle under Northeast Japan.     

Modeling of damage,permeability changes and pressure responses during excavation of the TSX tunnel in granitic rock at URL,Canada

This paper presents numerical modeling of excavation-induced damage, permeability changes, and fluid-pressure responses during excavation of a test tunnel associated with the tunnel sealing experiment (TSX) at the Underground Research Laboratory (URL) in Canada. Four different numerical models were applied using a wide range of approaches to model damage and permeability changes in the excavation disturbed zone (EDZ) around the tunnel. Using in situ calibration of model parameters, the modeling could reproduce observed spatial distribution of damage and permeability changes around the tunnel as a combination of disturbance induced by stress redistribution around the tunnel and by the drill-and-blast operation. The modeling showed that stress-induced permeability increase above the tunnel is a result of micro and macrofracturing under high deviatoric (shear) stress, whereas permeability increase alongside the tunnel is a result of opening of existing microfractures under decreased mean stress. The remaining observed fracturing and permeability changes around the periphery of the tunnel were attributed to damage from the drill-and-blast operation. Moreover, a reasonably good agreement was achieved between simulated and observed excavation-induced pressure responses around the TSX tunnel for 1 year following its excavation. The simulations showed that these pressure responses are caused by poroelastic effects as a result of increasing or decreasing mean stress, with corresponding contraction or expansion of the pore volume. The simulation results for pressure evolution were consistent with previous studies, indicating that the observed pressure responses could be captured in a Biot model using a relatively low Biot-Willis’ coefficient, α ≈ 0.2, a porosity of n ≈ 0.007, and a relatively low permeability of k ≈ 2 × 10⁻²² m², which is consistent with the very tight, unfractured granite at the site.     

A case study on the influence of THM coupling on the near field safety of a spent fuel repository in sparsely fractured granite

In order to demonstrate the feasibility of geological disposal of spent CANDU fuel in Canada, a safety assessment was performed for a hypothetical repository in the Canadian Shield. The assessment shows that the maximum long term radionuclide release from such repository would meet international criteria for dose rate; however, uncertainties in the assumed evolution of the repository were identified. Such uncertainties could be resolved by the consideration of coupled Thermal-Hydro-Mechanical-Chemical (THMC) processes. In Task A of the DECOVALEX-THMC project, THM models were developed within the framework of the theory of poroelasticity. Such model development was performed in an iterative manner, using experimental data from laboratory and field tests. The models were used to perform near-field simulations of the evolution of the repository in order to address the above-mentioned uncertainties. This paper presents the definition and rationale of task A and the results of the simulations. From a repository safety point of view, the simulations predict that the maximum temperature would be well below the design target of 100°C; however, the stress on the container can marginally exceed the design value of 15 MPa. However, the most important finding from the simulations is that a rock damage zone could form around the emplacement borehole. Such damage zone can extend a few metres from the walls of the emplacement holes, with permeability values that are orders of magnitude higher than the initial values. The damage zone has the potential to increase the radionuclide transport flux from the geosphere; the effect of such an increase should be taken into account in the safety assessment and mitigated if necessary by the provision of sealing systems. Prepared for publication in Environmental Geology. DECOVALEX-THMC Special Issue.