On the siting of noble gases in E-chondrites

We have investigated the siting of noble gases in 6 E-chondrites, by analyzing fractions separated by density, grain size, and chemical resistance from Qingzhen (E3), Indarch (E4), Abee and Saint Sauveur (E4-5) and Yilmia and North West Forrest (E6).The new “subsolar” (i.e. Ar-rich) component in E6's is concentrated in the main, ensatite-rich fraction of the meteorites, with density 3.06–3.3 g/cm³. It is unaffected by HCl and HNO₃ treatments of such fractions and remains in unchanged concentration when the samples are partially dissolved by HF. These properties suggest that the subsolar component is located in enstatite, or less likely, in a phase closely associated with it. E4-5's have at least half of their subsolar gases in HCl- and HNO₃-resistant sites (enstatite?), but fail to show the increasing gas concentration with decreasing grain size that is characteristic of most other primordial gas carriers. This may mean that the subsolar gases originally were in some other phase, but were then transferred to enstatite by metamorphism.Most of the ¹²⁹Xe_r of E6's is concentrated in the same fractions as the subsolar gases, again suggesting enstatite or an associated phase as the host. Only a few percent of the ¹²⁹Xe_r is contained in fractions enriched in other major and minor minerals. In E4's, on the other hand, ¹²⁹Xe_r is enhanced in finegrained, low density fractions and is also partly associated with chondrules. Perhaps ¹²⁹I was originally contained in fine-grained matrix, but was transferred to enstatite during metamorphism.A carbon-rich fraction of Indarch (E4) is enhanced in Ne-A, CCF-Xe, and L-Xe. Interestingly, both the isotopic composition of Xe and the Ne/CCF-Xe ratios resemble those of C-chondrites, yet these two meteorite classes probably formed rather far apart. Thus, if these components were mixed at a late stage, it must have been in fairly constant ratio over a large scale. Alternatively, they may have been mixed at an earlier stage, into a common carrier that was spread through a significant portion of the solar nebula.The primordial gases of Qingzhen (E3) resemble those of Indarch: they are present in moderate amounts (${}^{20}\text{Ne}{}_{\mathrm{p}}\text{= 1.2 × 10}{}^{\mathrm{?8}}\text{cc/g,}{}^{132}\text{Xe = 10 × 10}{}^{\mathrm{?10}}\text{cc/g)}$, with little or no contribution from the subsolar component. Thus Qingzhen reinforces our earlier finding that E-chondrites show no regular increase in noble gas content with decreasing petrologic type. One notable feature of Qingzhen is its very low ${}^3\text{He}{}^{21}\text{Ne}$ ratio of 1.07, which indicates that ³He has been lost by solar heating. Solar heating may also account for its low, discordant gas retention ages (U,Th-He age = 1.1 AE, KAr age = 3.2AE).     

An unusual modern silica–carbonate sinter from Pavlova spring, Ngatamariki, New Zealand

ABSTRACT A silica–carbonate deposit is forming from the dilute alkali chloride waters of Pavlova spring, a small thermal pool and outflow channel (85 to <40 °C), situated at the northern extent of the South Orakonui area of the Ngatamariki geothermal field, Taupo Volcanic Zone (TVZ), New Zealand. It is one of a small but growing number of thermal spring features known to yield deposits of mixed mineralogy. At Pavlova, a distinctive, crustose, chalk‐white, meringue‐like sinter, comprising non‐crystalline opal‐A silica with subordinate calcite, is actively precipitating both around the margins of and as small islets within the spring, with an average accumulation rate of ≈ 2 mm year^?1. Both emergent and partly submerged substrates host the sinter, including fallen pine branches, twigs, needles and cones, gum leaves, grass blades, bracken fronds, pumice, sediment and microbial mats. The sinter is thin (25–35 mm thickness), finely laminated and contains three distinct types of stacked horizons. Submerged basal layers constitute stratiform to undulatory microstromatolites with pseudocolumns, which grew outwards and upwards on narrow twig nuclei. Emergent middle layers comprise discontinuous, spicular microstromatolites (to 10 mm height), with prostrate and erect microbial filaments, silica spheres and silicified mucus, overlain by silicified structures of probable fungal origin. In places, lower and middle sinter layers are capped by white, smooth, convex surfaces that coalesce into subdued, curved ridges, resembling laterally continuous peaks of egg‐white meringue. The meringue is internally laminated, with fossilized microbes preserved in thin horizons. Small lensoid masses of calcite crystals nestle between silica laminae throughout the sinter. The near‐neutral (pH ≈ 7·2) spring water is a dilute chloride‐carbonate type (HCO≈ 470 µg g^?1, Cl^–≈ 600 µg g^?1) with low (≈ 50 µg g^?1), typical of TVZ thermal fields where deep chloride fluid mixes with CO₂‐rich, steam‐heated shallow waters before discharge. The hot water changed little in composition from 1993 to 1999 and, despite dilution by meteoric waters, contains sufficient SiO₂ (≈ 220 µg g^?1) for opal‐A to deposit at the surface upon cooling. However, the concentration of Ca²⁺ (≈ 6 µg g^?1) is such that the precipitation of calcite is not expected without modification of spring waters. Precipitation occurs by evaporation of thin water films at exposed substrate surfaces, via meniscoid as well as capillary creep (wicking), through porous sinter horizons and across emergent vegetative surfaces in contact with spring water or steam. The height of the deposit above the water surface is restricted by the upper limit of moisture bathing these substrates. Splash and spray are not involved in the formation of Pavlova spicular microstromatolites, as is the case for other texturally similar deposits from hotsprings elsewhere. This young (< 15 years), mineralogically and morphologically complex hot‐spring deposit exhibits > 10 times lower accumulation rates than typical siliceous sinters in the TVZ, and deposition of both silica and calcite is controlled by microchemical conditions and local temperature gradients, rather than by bulk spring water chemistry.     

Comparing Conditions of Labor-Intensive Forestry and Fire Suppression Workers

Since the late 1970s, labor-intensive forest workers in the Pacific Northwest have been mostly Latino. These workers and their Anglo counterparts plant and thin trees, perform other forestry services, and fight wildland fires. Poor job quality has been persistent, especially for Latino workers. We compare working conditions between fire suppression and nonsuppression forest work across Latino and non-Latino populations in Oregon. We find that although both groups share some similar conditions, Latino workers often faced poorer conditions, including disrespectful treatment, uncompensated injuries, risk of being blackballed if they complained, and little opportunity for advancement. However, there were some important job quality improvements for Latinos in fire suppression, including compensation for travel and training. Differences in contracting market structure and federal oversight between fire suppression and other forest work may contribute to improved job quality. This suggests the potential for improving conditions by focusing on improving contracting markets and oversight.     

Linking Spatial and Temporal Variation at Multiple Scales in a Heterogeneous Landscape*

Anthropogenic, ecological, and land‐surface processes interact in landscapes at multiple spatial and temporal scales to create characteristic patterns. The relationships between temporally and spatially varying processes and patterns are poorly understood because of the lack of spatiotemporal observations of real landscapes over significant stretches of time. We report a new method for observing joint spatiotemporal landscape variation over large areas by analyzing multitemporal Landsat data. We calculate the spatiotemporal variation of the Normalized Difference Vegetation Index (NDVI) in the area covered by one Landsat scene footprint in north central Florida, over spatial windows of 10⁴–10⁸ m² and time steps of two to sixteen years. The correlations, slopes, and intercepts of spatial versus temporal regressions in the real landscape all differ significantly from results obtained using a null model of a randomized landscape. Spatial variances calculated within windows of 10⁵–10⁷ m² had the strongest relationships with temporal variances (regressions with both larger and smaller windows had lower coefficients of determination), and the relationships were stronger with longer time steps. Slopes and y‐intercepts increased with window size and decreased with increased time step. The spatial and temporal scales at which NDVI signals are most strongly related may be the characteristic scales of the processes that most strongly determine landscape patterns. For example, the important time and space windows correspond with areas and timing of fires and tree plantation harvests. Observations of landscape dynamics will be most effective if conducted at the characteristic scales of the processes, and our approach may provide a tool for determining those scales.     

Gender and physical geography in the United Kingdom

Summary This paper presents the results of a questionnaire survey of all higher education geography departments in the United Kingdom, in order to provide an overview of the current status of women employed in the discipline, particularly female physical geographers. The survey examined the position of female physical geographers of doctoral level and above, in terms of employment status, type of contract, career structure, research and teaching disciplines and successful grant applications. The publication records of female academic staff were also examined. The results of the survey demonstrate that women are under-represented in physical geography at all levels of the academic hierarchy and that the majority of female physical geography academic staff are below 40 years of age, and employed at the lecturer level on permanent contracts.     

Direct application of compound-specific radiocarbon analysis of leaf waxes to establish lacustrine sediment chronology

This study demonstrates use of compound-specific radiocarbon analysis (CSRA) for dating Holocene lacustrine sediments from carbonate-hosted Ordy Pond, O‘ahu, Hawai‘i. Long-chain odd-numbered normal alkanes (n-alkanes), biomarkers characteristic of terrestrial higher plants, were ubiquitous in Ordy Pond sediments. The δ¹³C of individual n-alkanes ranged from −29.9 to −25.5‰, within the expected range for n-alkanes synthesized by land plants using the C₃ or C₄ carbon fixation pathway. The ¹⁴C ages of n-alkanes determined by CSRA showed remarkably good agreement with ¹⁴C dates of rare plant macrofossils obtained from nearby sedimentary horizons. In general, CSRA of n-alkanes successfully refined the age-control of the sediments. The sum of n-alkanes in each sample produced 70–170 μg of carbon (C), however, greater age errors were confirmed for samples containing less than 80 μg of C. The ¹⁴C age of n-alkanes from one particular sedimentary horizon was 4,155 years older than the value expected from the refined age-control, resulting in an apparent and arguable age discrepancy. Several lines of evidence suggest that this particular sample was contaminated by introduction of ¹⁴C-free C during preparative capillary gas chromatography. This study simultaneously highlighted the promising potential of CSRA for paleo-applications and the risks of contamination associated with micro-scale ¹⁴C measurement of individual organic compounds.     

Diatom assemblage response to Iroquoian and Euro-Canadian eutrophication of Crawford Lake,Ontario, Canada

Diatom and geochemical data from Crawford Lake, Ontario, have been used to document limnological responses to periods of cultural disturbance resulting from native Iroquoian occupation of the watershed (1268–1486 AD) and Euro-Canadian agriculture and deforestation (1867 AD–present). Here, we further develop the high-resolution nature of the Crawford Lake sediment record to examine the physical, chemical and biological aspects of limnological response to human disturbances in the lake catchment area with exceptional detail. We report detailed diatom abundance and flux data for individual taxa from Crawford Lake, and further describe the relationship between assemblage composition and environmental conditions using canonical correspondence analysis (CCA). Diatom assemblage data are used to calculate diatom inferred-total phosphorus (DI-TP) concentrations for the past ∼1,000 years. We also examine the diatom community response during and after periods of disturbance by Iroquoian and Euro-Canadian populations, and compare this response to existing geochemical proxies of lake production and new elemental geochemical indicators of catchment area erosion. In particular, we explore the differing limnological response to the two distinct periods of cultural eutrophication and examine the limnological processes that occurred during the period of␣low (or no) human activity (1487–1866 AD), when geochemical indicators of lake production recovered to pre-disturbance conditions, but diatom assemblages notably did not. Our results illustrate the highly susceptible nature of diatom communities to periods of anthropogenic disturbance, and emphasize that ecological indicators (such as diatom assemblages) should be included with other proxies (such as nutrient concentrations and physical characteristics) when assessing disturbance and recovery in lake systems.     

全球重要农业文化遗产(GIAHS)保护与适应性管理(英文)

世界各地世代居住的农牧民,以多样化的自然资源为基础,通过因地制宜的生产实践活动,创造、形成并保持着许多独具特色的农业系统和景观。这些在本土知识和传统经验基础上所建立起来的农业文化遗产巧夺天工,充分反映了人类及其文化多样性和与自然环境之间深刻关系的演进历程。这些系统不仅维持并适应了具有全球重要意义的农业生物多样性,形成了丰富的本土知识体系,而且更为重要的是,还为人类持续提供了多样化的产品和服务,保障了食物安全和生计安全,提高了人们的生活质量。但是,许多这样的农业生产系统正面临着包括全球化在内的多种影响因素的威胁。2002年,联合国粮农组织发起了一个国际合作计划"全球重要农业文化遗产(GIAHS)保护与适应性管理"。这一全球性倡议旨在建立这些农业文化遗产及其有关的生物多样性、食物与生计安全、景观与文化的保护体系,并在世界范围内得到认可,实现动态保护和可持续管理。     

Quantification of Metals and Semimetals in Carbon‐Rich Rocks: A New Sequential Protocol Including Extraction from Humic Substances

We have developed a new sequential extraction technique that does not require complex procedures and is efficient in determining metal and semimetal contents of carbon‐rich rocks. Six geological reference materials (SBC‐1, SCHS‐1, SCo‐1, SDO‐1, SGR‐1b and SLg‐1) and an in‐house black shale (SH‐1) were selected to test the method, which consists of four main digestion steps involving: (a) dilute HCl acid; (b) NaOH; (c) aqua regia; and (d) hydrofluoric acid. Compared with traditional aqua regia + hydrofluoric acid attack, this new protocol recovers more of the moderately volatile elements during early extraction of humic substances. In addition when compared with reference values, those for most elements are in agreement within uncertainty. Furthermore, this new protocol reveals important information on the partitioning of elements; for instance, steps one and two indicate which elements are associated with carbonates and organic phases from fulvic and humic acid extractions, whereas step three provides results for which elements are associated with sulfide minerals and step four indicates which elements remained in the silicate and oxide phases.