Stable isotopic evidence for Middle Pleistocene environmental change from a loess‐paleosol sequence: Kärlich,Germany

Loess‐paleosol sequences are important terrestrial archives of palaeoenvironmental change. Such sequences are rich in pedogenic carbonate, the oxygen and carbon isotopic values of which can provide important palaeoenvironmental information. Although some studies have pioneered the use of O and C isotopes in loess‐paleosol sequences, they are not routinely used as palaeoclimate proxies. In this study we analysed the sedimentology, micromorphology, geochronology and isotopic geochemistry of a Middle Pleistocene loess‐paleosol section, located at Kärlich, Germany. The section studied correlates with the Elsterian glacial (MIS 12) and Holsteinian interglacial (MIS 11). Embedded tephra layers yielded ⁴⁰Ar/³⁹Ar ages of 466±3 ka, 447±1 ka and 361±3 ka. The sedimentology and micromorphology of the sequence record a shift from accretionary loess accumulation (MIS 12) to prolonged pedogenesis at a stable land surface (MIS 11). Soil carbonate δ¹⁸O values record an enrichment of ～3‰ during the accumulation of the loess, reaching peak values comparable with those found in the MIS 11 soil. The δ¹⁸O signal is interpreted as reflecting temperature, highlighting the potential of δ¹⁸O analysis of European loess soil carbonates as a means of reconstructing palaeotemperature history.     

Estimating fractal dimension of profiles: A comparison of methods

This paper examines the characteristics of four different methods of estimating the fractal dimension of profiles. The semi-variogram, roughness-length, and two spectral methods are compared using synthetic 1024-point profiles generated by three methods, and using two profiles derived from a gridded DEM and two profiles from a laser-scanned soil surface. The analysis concentrates on the Hurst exponent H,which is linearly related to fractal dimension D,and considers both the accuracy and the variability of the estimates of H.The estimation methods are found to be quite consistent for Hnear 0.5, but the semivariogram method appears to be biased for Happroaching 0 and 1, and the roughness-length method for Happroaching 0. The roughness-length or the maximum entropy spectral methods are recommended as the most suitable methods for estimating the fractal dimension of topographic profiles. The fractal model fitted the soil surface data at fine scales but not at broad scales, and did not appear to fit the DEM profiles well at any scale.     

Microtextural constraints on the interplay between fluid–rock reactions and deformation

Schists from two mylonitic localities in the footwall of a low-angle normal fault in the eastern Alps record different degrees of embrittlement during exhumation, depending on the extent to which fluid–rock reactions proceeded. At one site, graphitic schists preserve textural evidence for two metamorphic reactions that modified and/or fluid volume: (1) reaction between graphite and aqueous fluid that increased without changing the molar amount of fluid, and (2) replacement of titanite by rutile, calcite, and quartz. The latter reaction involved net consumption of increasingly CO₂-rich fluid. Areas where the first reaction proceeded are associated with abundant Mode I microcracks. Fluid inclusion arrays within the microcracks show that increased from ∼0.1 to 0.6 during decompression from 4.75 to 2 kbar at a reference temperature of 500°C. Titanite consumption is most pronounced within transgranular Mode I microcracks, but microcracks do not crosscut products of this reaction; fluid consumption during reaction was coeval with the end of microcracking, at least on a local scale. At the other site, graphitic schists lack small-scale Mode I cracks as well as evidence for graphite consumption during decompression. SEM imaging shows that graphite is anhedral and pitted at the first site, but occurs in clusters of euhedral grains at the second site. Mass balance calculations demonstrate that rocks with partially consumed graphite were infiltrated by an externally derived, H₂O-rich fluid that drove subsequent graphite-fluid reaction. Evidence for similar fluid infiltration is absent at the second site. Variations in the degree of reaction progress indicate that fluid pathways and deformation style were heterogeneous on the scale of millimeters to kilometers during exhumation from mid-crustal depths.     

The use of genetic algorithms to model protoplanetary discs

The protoplanetary discs of T Tauri and Herbig Ae/Be stars have previously been studied using geometric disc models to fit their spectral energy distribution (SED). The simulations provide a means to reproduce the signatures of various circumstellar structures, which are related to different levels of infrared excess. With the aim of improving our previous model, which assumed a simple flat-disc configuration, we adopt here a reprocessing flared-disc model that assumes hydrostatic, radiative equilibrium. We have developed a method to optimize the parameter estimation based on genetic algorithms (GAs). This paper describes the implementation of the new code, which has been applied to Herbig stars from the Pico dos Dias Survey catalogue, in order to illustrate the quality of the fitting for a variety of SED shapes. The star AB Aur was used as a test of the GA parameter estimation, and demonstrates that the new code reproduces successfully a canonical example of the flared-disc model. The GA method gives a good quality of fit, but the range of input parameters must be chosen with caution, as unrealistic disc parameters can be derived. It is confirmed that the flared-disc model fits the flattened SEDs typical of Herbig stars; however, embedded objects (increasing SED slope) and debris discs (steeply decreasing SED slope) are not well fitted with this configuration. Even considering the limitation of the derived parameters, the automatic process of SED fitting provides an interesting tool for the statistical analysis of the circumstellar luminosity of large samples of young stars.     

Strategic priorities for assessing ecological impacts of marine renewable energy devices in the Pentland Firth (Scotland,UK)

The Pentland Firth, located between the north coast of mainland Scotland (UK) and the Orkney Islands, is recognised as an excellent location for the utilisation of tidal stream technology. Potential ecological impacts associated with tidal stream technology may ultimately depend on device design, array size and deployment location. Available ecological data for the Pentland Firth is summarised and strategic priorities for assessing ecological impacts are provided. Baseline data on marine species and habitats in the Pentland Firth is severely lacking and consequently the integrity of any environmental impact assessment could be compromised by this lack of data.     

Implementation/optimization of moving least squares response surfaces for approximation of hurricane/storm surge and wave responses

One of the important recent advances in the field of hurricane/storm modelling has been the development of high-fidelity numerical simulation models for reliable and accurate prediction of wave and surge responses. The computational cost associated with these models has simultaneously created an incentive for researchers to investigate surrogate modelling (i.e. metamodeling) and interpolation/regression methodologies to efficiently approximate hurricane/storm responses exploiting existing databases of high-fidelity simulations. Moving least squares (MLS) response surfaces were recently proposed as such an approximation methodology, providing the ability to efficiently describe different responses of interest (such as surge and wave heights) in a large coastal region that may involve thousands of points for which the hurricane impact needs to be estimated. This paper discusses further implementation details and focuses on optimization characteristics of this surrogate modelling approach. The approximation of different response characteristics is considered, and special attention is given to predicting the storm surge for inland locations, for which the possibility of the location remaining dry needs to be additionally addressed. The optimal selection of the basis functions for the response surface and of the parameters of the MLS character of the approximation is discussed in detail, and the impact of the number of high-fidelity simulations informing the surrogate model is also investigated. Different normalizations of the response as well as choices for the objective function for the optimization problem are considered, and their impact on the accuracy of the resultant (under these choices) surrogate model is examined. Details for implementation of the methodology for efficient coastal risk assessment are reviewed, and the influence in the analysis of the model prediction error introduced through the surrogate modelling is discussed. A case study is provided, utilizing a recently developed database of high-fidelity simulations for the Hawaiian Islands.     

Hydrology of hillslope‐wetland streams,Polar Bear Pass,Nunavut, Canada

Polar Bear Pass is a large High Arctic low‐gradient wetland (100 km²) bordered by low‐lying hills which are notched by a series of v‐shaped valleys. The spring and summer hydrology of two High Arctic hillslope‐wetland catchments, a first‐order stream, 0·2 km² Landing Strip Creek (LSC) and a larger second‐order basin, 4·2 km² Windy Creek (WC), is described here. A water balance framework was employed in 2008 to examine the movement of water from upland reaches into the low‐lying wetland. Snowcover was low in both basins (<50 mm in water equivalent units), but they both exhibited nival‐type regimes. After the main snowmelt season ended, runoff ceased in the smaller catchment (LSC), but not at the larger basin (WC) which continued to flow throughout the summer. Both basins responded to summer rains in different ways. At LSC, late‐summer continuous streamflow occurred only when rainfall satisfied the large soil moisture deficit in the upper bowl‐shaped zone of the basin. At WC, the presence of thinly thawed, ice‐rich polygonal terrain within the stream channel and in the upper reaches of the catchment likely limited infiltration in these near‐stream zones and enhanced runoff in response to both moderate and high rainfall. Subsequently, seasonal runoff ratios differed between the two sites (0·19 vs 0·68) as did the seasonal storage + residual (+16 vs ?50 mm). This suggests that the post‐snowmelt season runoff response to summer precipitation is very much modified by the unique basin characteristics (soil‐type, vegetation, ground ice) and their location within each stream order type. Copyright © 2010 John Wiley & Sons, Ltd.     

Carbon dioxide and carbon monoxide photoproduction quantum yields in the Delaware Estuary

Photochemical mineralization of dissolved organic matter (DOM) plays an important role in the cycling of carbon in estuarine systems. A key to modeling this process is knowledge of apparent quantum yields (AQYs) for the photochemical products. Here we determined spectral AQYs for carbon dioxide (CO₂) and carbon monoxide (CO), the main products of DOM photomineralization, along the main axis of the Delaware Estuary. Apparent quantum yields for CO₂ photoproduction were determined shipboard using a multi-spectral irradiation system. Carbon monoxide AQYs were determined in stored samples by employing a narrow band spectral irradiation system. A single AQY spectrum described carbon dioxide photochemical production within the estuary whereas CO AQY spectra varied with salinity, suggesting different precursors and mechanisms for the production of these two species. CO₂ AQYs were used along with shipboard measurements of DOM absorbance and solar irradiance to calculate photoproduction rates. Calculated CO₂ photoproduction rates agreed with directly measured rates (2 to 4 μM CO₂ d^? 1) within experimental error, supporting the further development and use of AQYs to calculate regional-scale photochemical fluxes.