Comparison of binding abilities of fulvic and humic acids extracted from recent marine sediments with UO2

Potentiometric titrations were used to measure conditional stability constants of UO₂²⁺-fulvic acid and UO₂²⁺-humic acid complexes. Both 2:1 and 1:1 COO^-:UO₂²⁺ binding were observed. With decreasing metal concentration (2.5·10⁻⁴-6.25·10⁻⁵ M) increasing amounts of UO₂²⁺ were in the form of 1:1 humate complexes and 2:1 fulvate complexes. Despite the high nitrogen content and the low acidic OH group content, the successive stability constant values were similar to those determined for divalent cations associated with fulvic and humic compounds isolated from soils. Stability constant values increase simultaneously with increasing ionization of the humic (or fulvic) acid polyelectrolytes and with decreasing metal concentration.     

Deep mantle roots and continental emergence: implications for whole-Earth elemental cycling,long-term climate,and the Cambrian explosion

Elevations on Earth are dominantly controlled by crustal buoyancy, primarily through variations in crustal thickness: continents ride higher than ocean basins because they are underlain by thicker crust. Mountain building, where crust is magmatically or tectonically thickened, is thus key to making continents. However, most of the continents have long passed their mountain building origins, having since subsided back to near sea level. The elevations of the old, stable continents are lower than that expected for their crustal thicknesses, requiring a subcrustal component of negative buoyancy that develops after mountain building. While initial subsidence is driven by crustal erosion, thermal relaxation through growth of a cold thermal boundary layer provides the negative buoyancy that causes continents to subside further. The maximum thickness of this thermal boundary layer is controlled by the thickness of a chemically and rheologically distinct continental mantle root, formed during large-scale mantle melting billions of years ago. The final resting elevation of a stabilized continent is controlled by the thickness of this thermal boundary layer and the temperature of the Earth’s mantle, such that continents ride higher in a cooler mantle and lower in a hot mantle. Constrained by the thermal history of the Earth, continents are predicted to have been mostly below sea level for most of Earth’s history, with areas of land being confined to narrow strips of active mountain building. Large-scale emergence of stable continents occurred late in Earth’s history (Neoproterozoic) over a 100–300 million year transition, irreversibly altering the surface of the Earth in terms of weathering, climate, biogeochemical cycling and the evolution of life. Climate during the transition would be expected to be unstable, swinging back and forth between icehouse and greenhouse states as higher order fluctuations in mantle dynamics would cause the Earth to fluctuate rapidly between water and terrestrial worlds.     

Palaeomagnetic,geochronological and geological constraints on the tectonic evolution of the Mejillones Peninsula,northern Chile

Palaeomagnetic and geochronological data from an Early Palaeozoic high grade metamorphic complex (Jorgina Formation) and Jurassic layered basic intrusion (Moreno Complex) are reported from the Mejillones Peninsula of northern Chile (23–23°30'S). ⁴⁰Ar–³⁹Ar dates from the Lower Palaeozoic Jorgina Formation and the Moreno Complex are between 170 and 158 Ma, coincident with a phase of emplacement of the north Chilean coastal batholith. This suggests that intrusion and magnetization of the Moreno Complex and the metamorphism and remagnetization of the Jorgina Formation were related to batholith emplacement. Extracted stable components of magnetization from all units (17 sites) define site-mean directions with a scattered distribution. The scatter in site-mean directions is interpreted as being due to minor, localized, non-uniform, block-fault related (normal or strike-slip, or both) rotation after 158 Ma. The palaeomagnetic and geochronological data indicate that no significant large-scale latitudinal translation of crustal blocks has taken place in this part of northern Chile since the Late Jurassic. In addition, they indicate that the uniform clockwise rotation after the mid-Cretaceous which affected the adjacent Cordillera de la Costa either did not extend into the Mejillones Peninsula or took the form of localized block-fault rotations. The restriction of palaeomagnetically defined styles of rotation to discrete areas within the north Chilean forearc indicates that forearc wide block-fault rotation models are not applicable to the Pacific margin of northern Chile.