Nouvelle interprétation structurale de la « faille Nord- Pyrénéenne » en vallée d'Aspe (Pyrénées-Atlantiques). Remise en question d'un plutonisme ophitique danien dans le secteur de Bedous

In the Aspe Valley (western Pyrenees), the Europe/Iberia boundary corresponds to a complex fracturing zone, called the ‘Bielle–Accous Wrench-Faulting Corridor’, which represents the classical ‘North-Pyrenean Fault’. Located between the High Primary Range and the North-Pyrenean Zone, the BAWC shows different south-verging sheets mainly composed of Triassic materials. The Bedous ophite, associated with Muschelkalk and Keuper sediments, is also Triassic in age and involved in the same Pyrenean thrusting structures. So, contrary to a recent interpretation, this magmatic rock cannot be related to a supposed Danian plutonism inducing metamorphic processes in the surrounding Mesozoic formations. To cite this article: J. Canérot et al., C. R. Geoscience 336 (2004).     

Geochemical characteristics of mineral air particles emitted inside a clay atomisation plant which introduces waste recycling processes

The objective of this work is to assess the concentrations of three factions of air particles (settable particles, TSP and PM10) and the levels of several toxic elements in a clay atomisation industry through aerosol sampling at several points inside an industrial plant. Mechanical activities, which produce diffuse emissions, are the main process of discharge of particles in both indoor and outdoor workplace environments in the atomisation plant. The levels of As, Cd, Pb, Zn, Ba and Ni increase in the zones with higher concentrations of particles and lower ventilation. The concentrations of As and F are not influenced by the recycling processes. The levels of Cd and Pb do not show great enrichment in air particles collected inside the atomisation plant although the content of both elements is associated with ceramic muck recycling. Finally, the content of B in waste water is mainly transferred in gaseous phase to the atmosphere during the process of drying by atomisation.     

Les laves du mont Bangou : une première manifestation volcanique éocène, à affinité transitionnelle,de la Ligne du Cameroun

Mount Bangou, an Eocene volcano (⁴⁰K–⁴⁰Ar ages between 44.7 and 43.1 ± 1 Ma) is the oldest dated volcano of the Cameroon Line. In this region, two magmatic series, evolving by fractional crystallization, show transitional affinities that are exceptionally known in this sector. Mineral compositions of basaltic rocks (scarce modal olivine and occurrence of normative hypersthene) as well as geochemical characteristics (low Ba, La, Ta contents and high Y/Nb ratios) are in agreement with this trend. The succession of magmas evolving in time from transitional to more typical alkaline compositions is evidenced in a continental setting. To cite this article: J. Fosso et al., C. R. Geoscience 337 (2005).     

Mise au point d'un milieu de culture pour l'étude de l'altération de silicates en présence de Pseudomonas aeruginosa

The influence of microorganisms on mineral alteration is not easy to determine in environmental conditions, because of the difficulty to raise for comparison purposes an identical but abiotic system. Another problem in this context is the choice of reliable tracers to evaluate the alteration rate of materials during in vitro experiments. To face such difficulties, we elaborated a defined medium allowing both the growth of Pseudomonas aeruginosa and a precise measurement of the elements solubilized from the minerals. Thanks to this medium, we were able to quantitatively determine the amounts of major elements solubilized from the materials in the presence of bacterial growth, compared to a sterile system. Moreover, the analysis by ICP-MS of trace elements was possible after a chromatographic treatment, which selectively eliminated 99% of the sodium content of the medium. To cite this article: G. Aouad et al., C. R. Geoscience 337 (2005).     

An Overview of Dissolved and Suspended Matter Fluxes in the Loire River Basin: Natural and Anthropogenic Inputs

The spatial and temporal distributions of major elements were investigated in the surface waters and in associated suspended matter at two sites of the upper Loire basin (Orleans and Brehemont) between 1995 and 1998.According to geochemical and isotopic patterns, the dissolved load appears to result from a process of mixing rainwater inputs, weathering processes of carbonate and silicate bedrock, and agricultural and urban inputs. Natural inputs influence 60% of water chemical composition at both sites. Annual dissolved fluxes were estimated to be 1300 10³ t/y at Orleans and 1620 10³ t/y at Brehemont. Major elements are transported mainly in the dissolved fraction. After correcting for atmospheric and anthropogenic inputs, the silicate specific export rate was calculated to be 11 t/y/km² throughout the basin and the carbonate specific export rate to be from 47 t/y/km² at Orleans to 23 t/y/km² at Brehemont.The suspended load appears to result from at least two particle reservoirs: a silicate reservoir and a carbonate reservoir. The silicate reservoir has a detrital origin, mainly during periods of high flow, while the carbonate reservoir has a detrital origin during periods of high flow and an authigenic origin during periods of low flow. Of the total annual flow of suspended matter, this authigenic material represents 16% at Orleans, 25% at Brehemont and 37% in the fluvial part of the estuary. After correcting authigenic inputs, the specific export rate due to mechanical weathering was estimated to be 8 t/y/km² throughout the Loire basin.     

A Compilation of Silicon,Rare Earth Element and Twenty‐One other Trace Element Concentrations in the Natural River Water Reference Material SLRS‐5 (NRC‐CNRC)

The natural river water certified reference material SLRS‐5 (NRC‐CNRC) was routinely analysed in this study for major and trace elements by ten French laboratories. Most of the measurements were made using ICP‐MS. Because no certified values are assigned by NRC‐CNRC for silicon and 35 trace element concentrations (rare earth elements, Ag, B, Bi, Cs, Ga, Ge, Li, Nb, P, Rb, Rh, Re, S, Sc, Sn, Th, Ti, Tl, W, Y and Zr), or for isotopic ratios, we provide a compilation of the concentrations and related uncertainties obtained by the participating laboratories. Strontium isotopic ratios are also given.     

The Removal of Dissolved Metals by Hydroxysulphate Precipitates during Oxidation and Neutralization of Acid Mine Waters, Iberian Pyrite Belt

This study examines the removal of dissolved metals during the oxidation and neutralization of five acid mine drainage (AMD) waters from La Zarza, Lomero, Esperanza, Corta Atalaya and Poderosa mines (Iberian Pyrite Belt, Huelva, Spain). These waters were selected to cover the spectrum of pH (2.2–3.5) and chemical composition (e.g., 319–2,103 mg/L Fe; 2.85–33.3 g/L SO₄⁼) of the IPB mine waters. The experiments were conducted in the laboratory to simulate the geochemical evolution previously recognized in the field. This evolution includes two stages: (1) oxidation of dissolved Fe(II) followed by hydrolysis and precipitation of Fe(III), and (2) progressive pH increase during mixing with fresh waters. Fe(III) precipitates at pH < 3.5 (stages 1 and 2) in the form of schwertmannite, whereas Al precipitates during stage 2 at pH 5.0 in the form of several hydroxysulphates of variable composition (hydrobasaluminite, basaluminite, aluminite). During these stages, trace elements are totally or partially sorbed and/or coprecipitated at different rates depending basically on pH, as well as on the activity of the SO₄⁼ anion (which determines the speciation of metals). The general trend for the metals which are chiefly present as aqueous free cations (Pb²⁺, Zn²⁺, Cu²⁺, Cd²⁺, Mn²⁺, Co²⁺, Ni²⁺) is a progressive sorption at increasing pH. On the other hand, As and V (mainly present as anionic species) are completely scavenged during the oxidation stage at pH < 3.5. In waters with high activities (> 10⁻¹) of the SO ₄⁼ ion, some elements like Al, Zn, Cd, Pb and U can also form anionic bisulphate complexes and be significantly sorbed at pH < 5. The removal rates at pH 7.0 range from around 100% for As, V, Cu and U, and 60–80% for Pb, to less than 20% for Zn, Co, Ni and Mn. These processes of metal removal represent a significant mechanism of natural attenuation in the IPB.     

Anthropogenic climate change over the Mediterranean region simulated by a global variable resolution model

Two 30-year simulations corresponding to 1960-1989 and 2070-2099 have been performed with a variable resolution atmospheric model. The model has a maximum horizontal resolution of 0.5° over the Mediterranean Sea. Simulations are driven by IPCC-B2 scenario radiative forcing. Sea surface temperatures (SSTs) are prescribed from monthly observations for the present climate simulation, and from a blend of observations and coupled simulations for the scenario. Another pair of forced atmospheric simulations has been run under these forcings with the same uniform low resolution as the coupled model. Comparisons with observations show that the variable resolution model realistically reproduces the main climate characteristics of the Mediterranean region. At a global scale, changes in latitudinal temperature profiles are similar for the forced and coupled models, justifying the time-slice approach. The 2 m temperature and precipitation responses predict a warming and drying of the Mediterranean region. A comparison with the coupled simulation and forced low-resolution simulation shows that this pattern is robust. The decrease in mean precipitation is associated with a significant decrease in soil wetness, and could involve considerable impact on water resources around the Mediterranean basin.     

North Atlantic atmospheric circulation and surface wind in the Northeast of the Iberian Peninsula: uncertainty and long term downscaled variability

The variability and predictability of the surface wind field at the regional scale is explored over a complex terrain region in the northeastern Iberian Peninsula by means of a downscaling technique based on Canonical Correlation Analysis. More than a decade of observations (1992–2005) allows for calibrating and validating a statistical method that elicits the main associations between the large scale atmospheric circulation over the North Atlantic and Mediterranean areas and the regional wind field. In an initial step the downscaling model is designed by selecting parameter values from practise. To a large extent, the variability of the wind at monthly timescales is found to be governed by the large scale circulation modulated by the particular orographic features of the area. The sensitivity of the downscaling methodology to the selection of the model parameter values is explored, in a second step, by performing a systematic sampling of the parameters space, avoiding a heuristic selection. This provides a metric for the uncertainty associated with the various possible model configurations. The uncertainties associated with the model configuration are considerably dependent on the spatial variability of the wind. While the sampling of the parameters space in the model set up moderately impact estimations during the calibration period, the regional wind variability is very sensitive to the parameters selection at longer timescales. This fact illustrates that downscaling exercises based on a single configuration of parameters should be interpreted with extreme caution. The downscaling model is used to extend the estimations several centuries to the past using long datasets of sea level pressure, thereby illustrating the large temporal variability of the regional wind field from interannual to multicentennial timescales. The analysis does not evidence long term trends throughout the twentieth century, however anomalous episodes of high/low wind speeds are identified.