The Creston,California, meteorite fall and the origin of L chondrites

It has been proposed that all L chondrites resulted from an ongoing collisional cascade of fragments that originated from the formation of the ~500 Ma old asteroid family Gefion, located near the 5:2 mean‐motion resonance with Jupiter in the middle Main Belt. If so, L chondrite pre‐atmospheric orbits should be distributed as expected for that source region. Here, we present contradictory results from the orbit and collisional history of the October 24, 2015, L6 ordinary chondrite fall at Creston, CA (here reclassified to L5/6). Creston's short 1.30 ± 0.02 AU semimajor axis orbit would imply a long dynamical evolution if it originated from the middle Main Belt. Indeed, Creston has a high cosmic ray exposure age of 40–50 Ma. However, Creston's small meteoroid size and low 4.23 ± 0.07° inclination indicate a short dynamical lifetime against collisions. This suggests, instead, that Creston originated most likely in the inner asteroid belt and was delivered via the ν₆ resonance. The U‐Pb systematics of Creston apatite reveals a Pb‐Pb age of 4,497.1 ± 3.7 Ma, and an upper intercept U‐Pb age of 4,496.7 ± 5.8 Ma (2σ), circa 70 Ma after formation of CAI, as found for other L chondrites. The K‐Ar (age ~4.3 Ga) and U,Th‐He (age ~1 Ga) chronometers were not reset at ~500 Ma, while the lower intercept U‐Pb age is poorly defined as 770 ± 320 Ma. So far, the three known L chondrites that impacted on orbits with semimajor axes a <2.0 AU all have high (>3 Ga) K‐Ar ages. This argues for a source of some of our L chondrites in the inner Main Belt. Not all L chondrites originate in a continuous population of Gefion family debris stretching across the 3:1 mean‐motion resonance.     

Analytical development of the lunisolar disturbing function and the critical inclination secular resonance

We provide a detailed derivation of the analytical expansion of the lunar and solar disturbing functions. Although there exist several papers on this topic, many derivations contain mistakes in the final expansion or rather (just) in the proof, thereby necessitating a recasting and correction of the original derivation. In this work, we provide a self-consistent and definite form of the lunisolar expansion. We start with Kaula’s expansion of the disturbing function in terms of the equatorial elements of both the perturbed and perturbing bodies. Then we give a detailed proof of Lane’s expansion, in which the elements of the Moon are referred to the ecliptic plane. Using this approach the inclination of the Moon becomes nearly constant, while the argument of perihelion, the longitude of the ascending node, and the mean anomaly vary linearly with time. We make a comparison between the different expansions and we profit from such discussion to point out some mistakes in the existing literature, which might compromise the correctness of the results. As an application, we analyze the long-term motion of the highly elliptical and critically-inclined Molniya orbits subject to quadrupolar gravitational interactions. The analytical expansions presented herein are very powerful with respect to dynamical studies based on Cartesian equations, because they quickly allow for a more holistic and intuitively understandable picture of the dynamics.     

Scale invariant characteristics of the Storegga Slide and implications for large-scale submarine mass movements

This study documents the fractal characteristics of submarine mass movement statistics and morphology within the Storegga Slide. Geomorphometric mapping is used to identify one hundred and fifteen mass movements from within the Storegga Slide scar and to extract morphological information about their headwalls. Analyses of this morphological information reveal the occurrence of spatial scale invariance within the Storegga Slide. Non-cumulative frequency-area distribution of mass movements within the Storegga Slide satisfies an inverse power law with an exponent of 1.52. The headwalls exhibit geometric similarity at a wide range of scales and the lengths of headwalls scale with mass movement areas. Composite headwalls are self-similar.One of the explanations of the observed spatial scale invariance is that the Storegga Slide is a geomorphological system that may exhibit self-organized criticality. In such a system, the input of sediment is in the form of hemipelagic sedimentation and glacial sediment deposition, and the output is represented by mass movements that are spatially scale invariant. In comparison to subaerial mass movements, the aggregate behavior of the Storegga Slide mass movements is more comparable to that of the theoretical ‘sandpile’ model. The origin of spatial scale invariance may also be linked to the retrogressive nature of the Storegga Slide. The geometric similarity in headwall morphology implies that the slope failure processes are active on a range of scales, and that modeling of slope failures and geohazard assessment can extrapolate the properties of small landslides to those of larger landslides, within the limits of power law behavior. The results also have implications for the morphological classification of submarine mass movements, because headwall shape can be used as a proxy for the type of mass movement, which can otherwise only be detected with very high resolution acoustic data that are not commonly available.     

Geomorphological and seismostratigraphic evidence for multidirectional polyphase glaciation of the northern Celtic Sea

High-resolution seismic and bathymetric data offshore southeast Ireland and LIDaR data in County Waterford are presented that partially overlap previous studies. The observed Quaternary stratigraphic succession offshore southeast Ireland (between Dungarvan and Kilmore Quay) records a sequence of depositional and erosional events that supports regional glacial models derived from nearby coastal sediment stratigraphies and landforms. A regionally widespread, acoustically massive facies interpreted as the ‘Irish Sea Till’ infills an uneven, channelized bedrock surface overlying irregular mounds and deposits in bedrock lows that are probably earlier Pleistocene diamicts. The till is truncated and overlain by a thin, stratified facies, suggesting the development of a regional palaeolake following ice recession of the Irish Sea Ice Stream. A north–south oriented seabed ridge to the north is interpreted as an esker, representing southward flowing subglacial drainage associated with a restricted ice sheet advance of the Irish Ice Sheet onto the Celtic Sea shelf. Onshore topographic data reveal streamlined bedforms that corroborate a southerly advance of ice onto the shelf across County Waterford. The combined evidence supports previous palaeoglaciological models. Significantly, for the first time, this study defines a southern limit for a Late Midlandian Irish Ice Sheet advance onto the Celtic Sea shelf. © 2020 John Wiley & Sons, Ltd.     

Recharge seasonality based on stable isotopes: Nongrowing season bias altered by irrigation in Nebraska

The sustainability of groundwater resources for agricultural and domestic use is dependent on both the groundwater recharge rate and the groundwater quality. The main purpose of this study was to improve the understanding of the timing, or seasonality, of groundwater recharge through the use of stable isotopes. Based on 768 groundwater samples collected from aquifers underlying natural resources districts in Nebraska, the isotopic composition of groundwater (δ²H and δ¹⁸O) was compared with that of precipitation by (a) mapping the isotopic composition of groundwater samples and (b) mapping a seasonality index for groundwater. Results suggest that for the majority of the state, groundwater recharge has a nongrowing season signature (October–April). However, the isotopic composition of groundwater suggests that in some intensively irrigated areas, human intervention in the water cycle has shifted the recharge signature towards the growing season. In other areas, a different human intervention (diversion of Platte River water for irrigation) has likely produced an apparent but possibly misleading nongrowing season recharge signal because the Platte River water differs isotopically from local precipitation. These results highlight the need for local information even when interpreting isotopic data over larger regions. Understanding the seasonality of recharge can provide insight into the optimal times to apply fertilizer, specifically in highly conductive soils with high leaching potential. In areas with high groundwater nitrate concentrations, this information is valuable for protecting the groundwater from further degradation. Although previous studies have framed nongrowing season recharge within the context of future climate change, this study also illustrates the importance of understanding how historical human intervention in the water cycle has affected groundwater recharge seasonality and subsequent implications for groundwater recharge and quality.     

Heterogeneous distributions of amino acids provide evidence of multiple sources within the Almahata Sitta parent body,asteroid 2008 TC3

Abstract– Two new fragments of the Almahata Sitta meteorite and a sample of sand from the related strewn field in the Nubian Desert, Sudan, were analyzed for two to six carbon aliphatic primary amino acids by ultrahigh performance liquid chromatography with UV‐fluorescence detection and time‐of‐flight mass spectrometry (LC‐FT/ToF‐MS). The distribution of amino acids in fragment #25, an H5 ordinary chondrite, and fragment #27, a polymict ureilite, were compared with results from the previously analyzed fragment #4, also a polymict ureilite. All three meteorite fragments contain 180–270 parts‐per‐billion (ppb) of amino acids, roughly 1000‐fold lower than the total amino acid abundance of the Murchison carbonaceous chondrite. All of the Almahata Sitta fragments analyzed have amino acid distributions that differ from the Nubian Desert sand, which primarily contains l ‐α‐amino acids. In addition, the meteorites contain several amino acids that were not detected in the sand, indicating that many of the amino acids are extraterrestrial in origin. Despite their petrological differences, meteorite fragments #25 and #27 contain similar amino acid compositions; however, the distribution of amino acids in fragment #27 was distinct from those in fragment #4, even though both are polymict ureilites from the same parent body. Unlike in CM2 and CR2/3 meteorites, there are low relative abundances of α‐amino acids in the Almahata Sitta meteorite fragments, which suggest that Strecker‐type chemistry was not a significant amino acid formation mechanism. Given the high temperatures that asteroid 2008 TC₃ appears to have experienced and lack of evidence for aqueous alteration on the asteroid, it is possible that the extraterrestrial amino acids detected in Almahata Sitta were formed by Fischer‐Tropsch/Haber‐Bosch type gas‐grain reactions at elevated temperatures.     

Unusual nonterrestrial l‐proteinogenic amino acid excesses in the Tagish Lake meteorite

Abstract– The distribution and isotopic and enantiomeric compositions of amino acids found in three distinct fragments of the Tagish Lake C2‐type carbonaceous chondrite were investigated via liquid chromatography with fluorescence detection and time‐of‐flight mass spectrometry and gas chromatography isotope ratio mass spectrometry. Large l ‐enantiomeric excesses (l _ee ～ 43–59%) of the α‐hydrogen aspartic and glutamic amino acids were measured in Tagish Lake, whereas alanine, another α‐hydrogen protein amino acid, was found to be nearly racemic (d ≈ l ) using both techniques. Carbon isotope measurements of d ‐ and l ‐aspartic acid and d ‐ and l ‐alanine in Tagish Lake fall well outside of the terrestrial range and indicate that the measured aspartic acid enantioenrichment is indigenous to the meteorite. Alternate explanations for the l ‐excesses of aspartic acid such as interference from other compounds present in the sample, analytical biases, or terrestrial amino acid contamination were investigated and rejected. These results can be explained by differences in the solid–solution phase behavior of aspartic acid, which can form conglomerate enantiopure solids during crystallization, and alanine, which can only form racemic crystals. Amplification of a small initial l ‐enantiomer excess during aqueous alteration on the meteorite parent body could have led to the large l ‐enrichments observed for aspartic acid and other conglomerate amino acids in Tagish Lake. The detection of nonterrestrial l ‐proteinogenic amino acid excesses in the Tagish Lake meteorite provides support for the hypothesis that significant enantiomeric enrichments for some amino acids could form by abiotic processes prior to the emergence of life.     

Compound‐specific carbon,nitrogen, and hydrogen isotopic ratios for amino acids in CM and CR chondrites and their use in evaluating potential formation pathways

Abstract– Stable hydrogen, carbon, and nitrogen isotopic ratios (δD, δ¹³C, and δ¹⁵N) of organic compounds can reveal information about their origin and formation pathways. Several formation mechanisms and environments have been postulated for the amino acids detected in carbonaceous chondrites. As each proposed mechanism utilizes different precursor molecules, the isotopic signatures of the resulting amino acids may indicate the most likely of these pathways. We have applied gas chromatography with mass spectrometry and combustion isotope ratio mass spectrometry to measure the compound‐specific C, N, and H stable isotopic ratios of amino acids from seven CM and CR carbonaceous chondrites: CM1/2 Allan Hills (ALH) 83100, CM2 Murchison, CM2 Lewis Cliff (LEW) 90500, CM2 Lonewolf Nunataks (LON) 94101, CR2 Graves Nunataks (GRA) 95229, CR2 Elephant Moraine (EET) 92042, and CR3 Queen Alexandra Range (QUE) 99177. We compare the isotopic compositions of amino acids in these meteorites with predictions of expected isotopic enrichments from potential formation pathways. We observe trends of decreasing δ¹³C and increasing δD with increasing carbon number in the α‐H, α‐NH₂ amino acids that correspond to predictions made for formation via Strecker‐cyanohydrin synthesis. We also observe light δ¹³C signatures for β‐alanine, which may indicate either formation via Michael addition or via a pathway that forms primarily small, straight‐chain, amine‐terminal amino acids (n‐ω‐amino acids). Higher deuterium enrichments are observed in α‐methyl amino acids, indicating formation of these amino acids or their precursors in cold interstellar or nebular environments. Finally, individual amino acids are more enriched in deuterium in CR chondrites than in CM chondrites, reflecting different parent‐body chemistry.     

A propensity for n‐ω‐amino acids in thermally altered Antarctic meteorites

Abstract– Asteroids and their fragments have impacted the Earth for the last 4.5 Gyr. Carbonaceous meteorites are known to contain a wealth of indigenous organic molecules, including amino acids, which suggests that these meteorites could have been an important source of prebiotic organic material during the origins of life on Earth and possibly elsewhere. We report the detection of extraterrestrial amino acids in thermally altered type 3 CV and CO carbonaceous chondrites and ureilites recovered from Antarctica. The amino acid concentrations of the thirteen Antarctic meteorites ranged from 300 to 3200 parts‐per‐billion (ppb), generally much less abundant than in amino acid‐rich CI, CM, and CR carbonaceous chondrites that experienced much lower temperature aqueous alteration on their parent bodies. In contrast to low‐temperature aqueously altered meteorites that show complete structural diversity in amino acids formed predominantly by Strecker–cyanohydrin synthesis, the thermally altered meteorites studied here are dominated by small, straight‐chain, amine terminal (n‐ω‐amino) amino acids that are not consistent with Strecker formation. The carbon isotopic ratios of two extraterrestrial n‐ω‐amino acids measured in one of the CV chondrites (δ¹³C approximately ?25‰) are consistent with ¹³C‐depletions observed previously in hydrocarbons produced by Fischer‐Tropsch type reactions. The predominance of n‐ω‐amino acid isomers in thermally altered meteorites hints at cosmochemical mechanisms for the preferential formation and preservation of a small subset of the possible amino acids.     

The filtering capacity of a tropical riverine wetland: I. Water balance

Wetlands in the coastal catchments adjacent to the Great Barrier Reef lagoon play an important role in local hydrological processes and provide important ecological habitats for terrestrial and aquatic species. Although many wetlands have been removed or degraded by agricultural expansion, there is now great interest in their protection and restoration as important aquatic ecosystems and potential filters of pollutant runoff. However, the filtering capacity of tropical wetlands is largely unknown, so the current study was established to quantify the water, sediment and nutrient balance of a natural riverine wetland in tropical north Queensland. Surface and groundwater fluxes of water, sediment and nutrients into and out of the wetland were monitored for a 3‐year period. This paper focuses on the water balance of this natural wetland and a companion paper presents its sediment and nutrient balance and estimates of water quality filtering. Wetland inflows and outflows were dominated by surface flows which varied by 3–4 orders of magnitude through the course of the year, with 90% of the annual flow occurring during the period January to March. Although groundwater inputs to the wetland were only 5% of the annual water balance, they are very important to sustaining the wetland during the dry season, when they can be the largest input of water (up to 90%). Water retention times in this type of wetland are very short, particularly when most of the flow and any associated materials are passing through it (i.e. 1–2 h), so there is little time to filter most of the annual flux of water through this wetland. Longer retention times occur at the end of the dry season (up to 8·5 days); but this is when the lowest fluxes of water pass through the wetland. Copyright © 2011 John Wiley & Sons, Ltd.