Li isotopes and trace elements as a petrogenetic tracer in zircon: insights from Archean TTGs and sanukitoids

We report δ⁷Li, Li abundance ([Li]), and other trace elements measured by ion probe in igneous zircons from TTG (tonalite, trondhjemite, and granodiorite) and sanukitoid plutons from the Superior Province (Canada) in order to characterize Li in zircons from typical Archean continental crust. These data are compared with detrital zircons from the Jack Hills (Western Australia) with U–Pb ages greater than 3.9 Ga for which parent rock type is not known. Most of the TTG and sanukitoid zircon domains preserve typical igneous REE patterns and CL zoning. [Li] ranges from 0.5 to 79 ppm, typical of [Li] in continental zircons. Atomic ratios of (Y + REE)/(Li + P) average 1.0 ± 0.7 (2SD) for zircons with magmatic composition preserved, supporting the hypothesis that Li is interstitial and charge compensates substitution of trivalent cations. This substitution results in a relatively slow rate of Li diffusion. The δ⁷Li and trace element data constrain the genesis of TTGs and sanukitoids. [Li] in zircons from granitoids is significantly higher than from zircons in primitive magmas in oceanic crust. TTG zircons have δ⁷Li (3 ± 8‰) and δ¹⁸O in the range of primitive mantle-derived magmas. Sanukitoid zircons have average δ⁷Li (7 ± 8‰) and δ¹⁸O higher than those of TTGs supporting genesis by melting of fluid-metasomatized mantle wedge. The Li systematics in sanukitoid and TTG zircons indicate that high [Li] in pre-3.9-Ga Jack Hills detrital zircons is a primary igneous composition and suggests the growth in proto-continental crust in magmas similar to Archean granitoids.     

Structural controls on groundwater flow in a fractured bedrock aquifer underlying an agricultural region of northwestern New Brunswick,Canada

A hydrogeological study was conducted in northwestern New Brunswick, Canada, to improve the predictability of fracture-dominated groundwater flow within folded bedrock composed of fine-grained turbidites. Borehole televiewer logging and outcrop mapping, integrated with hydraulic packer tests revealed enhanced hydraulic conductivity associated with northeasterly striking bedding-plane fractures formed during folding and flexural slip. These fractures impart azimuthal anisotropy to the aquifer because of moderately dipping fold limbs. High-angle fractures form a well-developed non-stratabound network, comprising two open fracture sets striking NNE parallel to the current direction of principal stress, and WNW parallel to the direction of principal stress that dominated during the Acadian orogeny. The subset of fractures showing significant oxidation, deemed most important to the groundwater flow system, is dominated by bedding-plane and high-angle fractures striking near-parallel to the maximum principal stress direction, resulting in extensional opening and enhanced hydraulic conductivities. An equivalent porous media model, incorporating anisotropy and varying hydraulic conductivity with depth, indicates that horizontal flow dominates the aquifer with relatively minor exchange between different model layers. These findings have implications for understanding flow directions in the Black Brook Watershed and elsewhere in the Matapédia Basin where fractures formed under similar stress conditions.     

Water quality and thermal regime of the Motueka River: Influences of land cover,geology and position in the catchment

We examined the effects of land use, geology, and longitudinal position within the river network on water quality and thermal regime at 23 sites within the Motueka River catchment. The concentrations of suspended solids, nitrate nitrogen, total nitrogen, Escherichia coli, and Campylobacter were higher at sites draining pastoral and horticultural land than in similar‐sized native or plantation forest streams. Average daily mean temperature and minimum temperature in summer and maximum winter temperature were higher in unshaded pastoral and horticultural streams than at native forest sites. Differences in water quality and thermal regime were also observed among sites with contrasting geology. Conductivity, pH, and minimum winter temperatures were highest at sites draining marble terrain. In contrast, longitudinal patterns in water quality and temperature regime along the 120‐km length of the river were relatively weak, although longitudinal patterns in amplitude of daily temperature fluctuation matched theoretical predictions. In this study, differences in land use appeared to have the strongest influence on most water quality and thermal variables examined. However, geology was an important factor explaining variation in certain variables (e.g., pH and conductivity). Longitudinal patterns in water quality and temperature were relatively weak and in many instances were linked with longitudinal patterns in land use and geology rather than catchment location alone.     

Radiometric and stratigraphic constraints on terminal Ediacaran (post-Gaskiers) glaciation and metazoan evolution

Radiometric constraints on mid-Ediacaran Period glaciation (Gaskiers) in Newfoundland narrowed the known temporal gap between widespread ice ages and the evolution of complex metazoans to several million years. To further evaluate this claim we studied an Ediacaran glacial diamictite at the base of the Fauquier Formation of northern Virginia, and discovered a conformable relationship between the post-glacial cap carbonate and overlying volcanic rocks of the Catoctin Formation. U/Pb zircon age constraints for the rift-related volcanic flows suggest initial emplacement around 571 million years ago. Application of the Catoctin age to the Fauquier succession indicates the occurrence of an ice age about 10 million years younger than the 582 Ma Gaskiers event, supporting the view of multiple Ediacaran Period glaciations. Furthermore, the age constraint from eastern Laurentia falls within radiometric uncertainty of fossiliferous strata in Avalonia, indicating that the Fauquier glaciation was coincident with early metazoan evolution.     

Trophic Relationships of a Marsh Bird Differ Between Gulf Coast Estuaries

Much of North America’s tidal marsh habitat has been significantly altered by both natural and man-made processes. Thus, there is a need to understand the trophic ecology of organisms endemic to these ecosystems. We applied carbon (δ ¹³C) and nitrogen (δ ¹⁵N) stable isotope analysis, along with isotope mixing models, to egg yolk, liver, and muscle tissues of clapper rails (Rallus longirostris) and their likely prey items. This analysis enabled us to explore variation in trophic niche and diet composition in this important marsh bird in two northern Gulf of Mexico tidal marshes that are river and ocean-dominated. For the river-associated estuary, δ ¹³C and δ ¹⁵N of egg yolks, liver, and pectoral muscle tissue samples provided evidence that clapper rails maintained a similar diet during both the winter and the breeding season. A trophic link between C₃ primary productivity and the clapper rail’s diet was also indicated as the δ ¹³C of clapper rail egg yolks related negatively with the aerial cover of C₃ macrophytes. Clapper rails from the ocean-dominated estuary had a narrower trophic niche and appeared to be utilizing marine resources, particularly, based on modeling of liver stable isotope values. Variation in stable isotope values between egg yolk and liver/muscle in both systems suggests that endogenous resources are important for egg production in clapper rails. These results demonstrate that diet composition, prey source, and niche width of clapper rails can vary significantly across different estuaries and appear to be influenced by hydrological conditions.     

Iron isotope compositions of carbonatites record melt generation, crystallization, and late-stage volatile-transport processes

Carbonatites define the largest range in Fe isotope compositions yet measured for igneous rocks, recording significant isotopic fractionations between carbonate, oxide, and silicate minerals during generation in the mantle and subsequent differentiation. In contrast to the relatively restricted range in δ⁵⁶Fe values for mantle-derived basaltic magmas (δ⁵⁶Fe?=?0.0?±?0.1‰), calcite from carbonatites have δ⁵⁶Fe values between ?1.0 and +0.8‰, similar to the range defined by whole-rock samples of carbonatites. Based on expected carbonate-silicate fractionation factors at igneous or mantle temperatures, carbonatite magmas that have modestly negative δ⁵⁶Fe values of ~ ?0.3‰ or lower can be explained by equilibrium with a silicate mantle. More negative δ⁵⁶Fe values were probably produced by differentiation processes, including crystal fractionation and liquid immiscibility. Positive δ⁵⁶Fe values for carbonatites are, however, unexpected, and such values seem to likely reflect interaction between low-Fe carbonates and Fe³⁺-rich fluids at igneous or near-igneous temperatures; the expected δ⁵⁶Fe values for Fe²⁺-bearing fluids are too low to produced the observed positive δ⁵⁶Fe values of some carbonatites, indicating that Fe isotopes may be a valuable tracer of redox conditions in carbonatite complexes. Further evidence for fluid-rock or fluid-magma interactions comes from the common occurrence of Fe isotope disequilibrium among carbonate, oxide, silicate, and sulfide minerals in the majority of the carbonatites studied. The common occurrence of Fe isotope disequilibrium among minerals in carbonatites may also indicate mixing of phenocyrsts from distinct magmas. Expulsion of Fe³⁺-rich brines into metasomatic aureols that surround carbonatite complexes are expected to produce high-δ⁵⁶Fe fenites, but this has yet to be tested.