Chemical Procedures for Rhenium Extraction from Geological Samples: Optimising the Anion Resin Bead Clean‐up Step

Rhenium–osmium geochronometry for samples with low Re and complex matrices requires improved Re extraction methods. Here, we investigate plausible controls on efficiency and efficacy of Re extraction during our anion resin bead purification. Four different protocols are compared, each isolating a single variable to test. Rhenium concentrations for solutions at each step of each protocol document differences in chemical recovery/yield. The negative‐thermal ionisation mass spectrometry (N‐TIMS) signal intensity serves as a proxy for Re yield and purity. These data document correlations between the N‐TIMS signal intensity and (a) the duration of anion resin bead conditioning prior to loading with Re‐bearing solution, and (b) both duration and strength of nitric acid used during rinsing of the Re‐loaded anion resin bead. The optimal protocol improved Re signal intensity around fourteen times compared with our current Re extraction protocol, an aggregate of 2.4 times improvement in chemical recovery (yield) and 5.8 times improvement in emission efficiency (purity). Repeated N‐TIMS isotopic measurements on our in‐house Re standard solution (1407) verify that our optimal protocol‐3 does not fractionate Re isotopes. The improved anion resin bead method considerably lowers the Re detection limit and allows Re‐Os isotopic analysis of picogram‐level Re hosted in geological samples with complex matrices.     

Controls on the lateral channel-migration rate of braided channel systems in coarse non-cohesive sediment

Lateral movements of alluvial river channels control the extent and reworking rates of alluvial fans, floodplains, deltas, and alluvial sections of bedrock rivers. These lateral movements can occur by gradual channel migration or by sudden changes in channel position (avulsions). Whereas models exist for rates of river avulsion, we lack a detailed understanding of the rates of lateral channel migration on the scale of a channel belt. In a two-step process, we develop here an expression for the lateral migration rate of braided channel systems in coarse, non-cohesive sediment. On the basis of photographic and topographic data from laboratory experiments of braided channels performed under constant external boundary conditions, we first explore the impact of autogenic variations of the channel-system geometry (i.e. channel-bank heights, water depths, channel-system width, and channel slope) on channel-migration rates. In agreement with theoretical expectations, we find that, under such constant boundary conditions, the laterally reworked volume of sediment is constant and lateral channel-migration rates scale inversely with the channel-bank height. Furthermore, when channel-bank heights are accounted for, lateral migration rates are independent of the remaining channel geometry parameters. These constraints allow us, in a second step, to derive two alternative expressions for lateral channel-migration rates under different boundary conditions using dimensional analysis. Fits of a compilation of laboratory experiments to these expressions suggest that, for a given channel bank-height, migration rates are strongly sensitive to water discharges and more weakly sensitive to sediment discharges. In addition, external perturbations, such as changes in sediment and water discharges or base level fall, can indirectly affect lateral channel-migration rates by modulating channel-bank heights. © 2019 The Author. Earth Surface Processes and Landforms published by John Wiley & Sons, Ltd. © 2019 The Author. Earth Surface Processes and Landforms published by John Wiley & Sons, Ltd.     

A review of definitions of the Himalayan Main Central Thrust

International Journal of Earth Sciences - Most workers regard the Main Central Thrust (MCT) as one of the key high strain zones in the Himalaya because it accommodated at least 90 km of...     

Mechanisms of tropical precipitation biases in climate models

Climate Dynamics - We investigate the possible causes for inter-model spread in tropical zonal-mean precipitation pattern, which is divided into hemispherically symmetric and anti-symmetric modes...     

The origin of high δ<Superscript>18</Superscript>O zircons: marbles,megacrysts, and metamorphism

The oxygen isotope ratios (δ¹⁸O) of most igneous zircons range from 5 to 8‰, with 99% of published values from 1345 rocks below 10‰. Metamorphic zircons from quartzite, metapelite, metabasite, and eclogite record δ¹⁸O values from 5 to 17‰, with 99% below 15‰. However, zircons with anomalously high δ¹⁸O, up to 23‰, have been reported in detrital suites; source rocks for these unusual zircons have not been identified. We report data for zircons from Sri Lanka and Myanmar that constrain a metamorphic petrogenesis for anomalously high δ¹⁸O in zircon. A suite of 28 large detrital zircon megacrysts from Mogok (Myanmar) analyzed by laser fluorination yields δ¹⁸O from 9.4 to 25.5‰. The U–Pb standard, CZ3, a large detrital zircon megacryst from Sri Lanka, yields δ¹⁸O = 15.4 ± 0.1‰ (2 SE) by ion microprobe. A euhedral unzoned zircon in a thin section of Sri Lanka granulite facies calcite marble yields δ¹⁸O = 19.4‰ by ion microprobe and confirms a metamorphic petrogenesis of zircon in marble. Small oxygen isotope fractionations between zircon and most minerals require a high δ¹⁸O source for the high δ¹⁸O zircons. Predicted equilibrium values of Δ¹⁸O(calcite-zircon) = 2–3‰ from 800 to 600°C show that metamorphic zircon crystallizing in a high δ¹⁸O marble will have high δ¹⁸O. The high δ¹⁸O zircons (>15‰) from both Sri Lanka and Mogok overlap the values of primary marine carbonates, and marbles are known detrital gemstone sources in both localities. The high δ¹⁸O zircons are thus metamorphic; the 15–25‰ zircon values are consistent with a marble origin in a rock-dominated system (i.e., low fluid_(external)/rock); the lower δ¹⁸O zircon values (9–15‰) are consistent with an origin in an external fluid-dominated system, such as skarn derived from marble, although many non-metasomatized marbles also fall in this range of δ¹⁸O. High δ¹⁸O (>15‰) and the absence of zoning can thus be used as a tracer to identify a marble source for high δ¹⁸O detrital zircons; this recognition can aid provenance studies in complex metamorphic terranes where age determinations alone may not allow discrimination of coeval source rocks. Metamorphic zircon megacrysts have not been reported previously and appear to be associated with high-grade marble. Identification of high δ¹⁸O zircons can also aid geochronology studies that seek to date high-grade metamorphic events due to the ability to distinguish metamorphic from detrital zircons in marble.     

A longer-term perspective on soil moisture,groundwater and stream flow response to the 2018 drought in an experimental catchment in the Scottish Highlands

The drought of summer 2018, which affected much of Northern Europe, resulted in low river flows, biodiversity loss and threats to water supplies. In some regions, like the Scottish Highlands, the summer drought followed two consecutive, anomalously dry, winter periods. Here, we examine how the drought, and its antecedent conditions, affected soil moisture, groundwater storage, and low flows in the Bruntland Burn; a sub-catchment of the Girnock Burn long-term observatory in the Scottish Cairngorm Mountains. Fifty years of rainfall-runoff observations and long-term modelling studies in the Girnock provided unique contextualisation of this extreme event in relation to more usual summer storage dynamics. Whilst summer precipitation in 2018 was only 63% of the long-term mean, soil moisture storage across much of the catchment were less than half of their summer average and seasonal groundwater levels were 0.5 m lower than normal. Hydrometric and isotopic observations showed that ~100 mm of river flows during the summer (May-Sept) were sustained almost entirely by groundwater drainage, representing ~30% of evapotranspiration that occurred over the same period. A key reason that the summer drought was so severe was because the preceding two winters were also dry and failed to adequately replenish catchment soil moisture and groundwater stores. As a result, the drought had the biggest catchment storage deficits for over a decade, and likely since 1975–1976. Despite this, recovery was rapid in autumn/winter 2018, with soil and groundwater stores returning to normal winter values, along with stream flows. The study emphasizes how long-term data from experimental sites are key to understanding the non-linear flux-storage interactions in catchments and the “memory effects” that govern the evolution of, and recovery from, droughts. This is invaluable both in terms of (a) giving insights into hydrological behaviours that will become more common water resource management problems in the future under climate change and (b) providing extreme data to challenge hydrological models.     

Modern influences on chironomid distribution in western Ireland: potential for palaeoenvironmental reconstruction

Ireland provides a unique setting for the study of past climates, as its climate is dominated by westerly airflow from the North Atlantic and readily responsive to changes in North Atlantic circulation patterns. Although there has been substantial research on Ireland’s past environments, quantitative palaeolimnological research, especially chironomid-based research, has been lacking. In order to further develop chironomid-based palaeolimnological investigations, a calibration set was constructed to determine the dominant environmental controls on modern chironomids in western Ireland. Chironomid subfossils were collected from surface sediments of 50 lakes. The lakes were characterised with 36 environmental variables, including physical attributes, lake water characteristics, lake sediment characteristics and land cover within each catchment. In this exploratory study, no specific environmental variable was targeted and lakes were chosen to span gradients of latitude, elevation, depth and trophic status. Redundancy analysis showed that six environmental variables—mean July air temperature, lake depth, dissolved organic carbon, and percentage catchment land cover of agriculture, peat bog and scrubland—captured a large and statistically significant portion of the variance in the chironomid data. July temperature and agricultural land cover were the most dominant environmental variables, with July temperature proving the most suitable for inference model development. A classical weighted-averaging model was developed to estimate July air temperature, with a coefficient of determination (r _jack ² ) of 0.60 and root mean square error of prediction (RMSEP) of 0.57 °C. Results suggest that summer temperature is the dominant influence on chironomid distribution across a wide variety of lake types, and the relatively small RMSEP should allow for more accurate reconstructions of Ireland’s relatively subdued Holocene temperature fluctuations.     

Land surface coupling in regional climate simulations of the West African monsoon

Coupling of the Community Land Model (CLM3) to the ICTP Regional Climate Model (RegCM3) substantially improves the simulation of mean climate over West Africa relative to an older version of RegCM3 coupled to the Biosphere Atmosphere Transfer Scheme (BATS). Two 10-year simulations (1992–2001) show that the seasonal timing and magnitude of mean monsoon precipitation more closely match observations when the new land surface scheme is implemented. Specifically, RegCM3–CLM3 improves the timing of the monsoon advance and retreat across the Guinean Coast, and reduces a positive precipitation bias in the Sahel and Northern Africa. As a result, simulated temperatures are higher, thereby reducing the negative temperature bias found in the Guinean Coast and Sahel in RegCM3–BATS. In the RegCM3–BATS simulation, warmer temperatures in northern latitudes and wetter soils near the coast create excessively strong temperature and moist static energy gradients, which shifts the African Easterly Jet further north than observed. In the RegCM3–CLM3 simulation, the migration and position of the African Easterly Jet more closely match reanalysis winds. This improvement is triggered by drier soil conditions in the RegCM3–CLM3 simulation and an increase in evapotranspiration per unit precipitation. These results indicate that atmosphere–land surface coupling has the ability to impact regional-scale circulation and precipitation in regions exhibiting strong hydroclimatic gradients.     

Assessment of uncertainties in the response of the African monsoon precipitation to land use change simulated by a regional model

Land use and land cover (LULC) over Africa have changed substantially over the last 60 years and this change has been proposed to affect monsoon circulation and precipitation. This study examines the uncertainties of model simulated response in the African monsoon system and Sahel precipitation due to LULC change using a set of regional model simulations with different combinations of land surface and cumulus parameterization schemes. Although the magnitude of the response covers a broad range of values, most of the simulations show a decline in Sahel precipitation due to the expansion of pasture and croplands at the expense of trees and shrubs and an increase in surface air temperature. The relationship between the model responses to LULC change and the climatologists of the control simulations is also examined. Simulations that are climatologically too dry or too wet compared to observations and reanalyses have weak response to land use change because they are in moisture or energy limited regimes respectively. The ones that lie in between have stronger response to the LULC changes, showing a more significant role in land–atmosphere interactions. Much of the change in precipitation is related to changes in circulation, particularly to the response of the intensity and latitudinal position of the African Easterly Jet, which varies with the changes in meridional surface temperature gradients. The study highlights the need for measurements of the surface fluxes across the meridional cross-section of the Sahel to evaluate models and thereby allowing human impacts such as land use change on the monsoon to be projected more realistically.