Metamorphism of Greater and Lesser Himalayan rocks exposed in the Modi Khola valley, central Nepal

Thermobarometric estimates for Lesser and Greater Himalayan rocks combined with detailed structural mapping in the Modi Khola valley of central Nepal reveal that large displacement thrust-sense and normal-sense faults and ductile shear zones mostly control the spatial pattern of exposed metamorphic rocks. Individual shear zone- or fault-bounded domains contain rocks that record approximately the same peak metamorphic conditions and structurally higher thrust sheets carry higher grade rocks. This spatial pattern results from the kinematics of thrust-sense faults and shear zones, which usually place deeper, higher grade rocks on shallower, lower grade rocks. Lesser Himalayan rocks in the hanging wall of the Ramgarh thrust equilibrated at about 9 kbar and 580°C. There is a large increase in recorded pressures and temperatures across the Main Central thrust. Data presented here suggest the presence of a previously unrecognized normal fault entirely within Greater Himalayan strata, juxtaposing hanging wall rocks that equilibrated at about 11 kbar and 720°C against footwall rocks that equilibrated at about 15 kbar and 720°C. Normal faults occur at the structural top and within the Greater Himalayan series, as well as in Lesser Himalayan strata 175 and 1,900 m structurally below the base of the Greater Himalayan series. The major mineral assemblages in the samples collected from the Modi Khola valley record only one episode of metamorphism to the garnet zone or higher grades, although previously reported ca. 500 Ma concordant monazite inclusions in some Greater Himalayan garnets indicate pre-Cenozoic metamorphism.     

Virtual observatories for space and solar physics research

As soon as the first data became available online over the Internet, it was obvious that different sites holding related datasets should appear to the end user as a single data system, even if the data itself is stored at multiple locations. To achieve this objective in the context of continuing parallel development of multiple data centres, in 2003 several actors in the realm of space plasmas created the international consortium Space Physics Archive Search and Extract (SPASE). Since 2005 US participation in SPASE has been supported by NASA, and early in 2006 NASA funded five new Virtual Observatories to cater for different aspects of solar system plasma science. This paper outlines the current status of the SPASE effort, the opportunities it offers, its specificities with respect to other parts of the astronomical virtual observatory, and the possibilities it offers for space weather.

Direct Trace Element Determination in Oil and Gas Produced Waters with Inductively Coupled Plasma‐Optical Emission Spectrometry: Advantages of High‐Salinity Tolerance

Waters co‐produced during petroleum extraction are the largest waste streams from oil and gas development. Reuse or disposal of these waters is difficult due to their high salinities and the sheer volumes generated. Produced waters (PWs) may also contain valuable mineral commodities. While an understanding of produced water trace element composition is required for evaluating the associated resource and waste potential of these materials, measuring trace elements in brines is challenging due to the dilution requirements of typical methods. Alternatively, inductively coupled plasma‐optical emission spectrometry (ICP‐OES) has shown promise as being capable of direct measurements of trace elements within PWs with minimal dilution. Here, we evaluate direct ICP‐OES trace element quantification in PWs for seventeen trace elements (As, Al, Ba, Be, Cd, Cr, Co, Cu, Hg, Mo, Ni, Pb, Rb, Sb, U, V and Zn) within fifteen PWs from five U.S. continuous reservoirs. The total analytical uncertainties associated with the trace element levels determined using ICP‐OES were estimated to be better than ± 30% (2s) except for Rb, which could not be determined due to ionisation interferences. The ICP‐OES results are compared with trace element levels determined using inductively coupled plasma‐mass spectrometry from the same samples. Our results demonstrate the potential for direct analysis of high‐salinity waters using ICP‐OES with minimal dilution and provide trace element concentrations in waters from several important U.S. petroleum‐generating reservoirs where available data are sparse.     

Five hundred million years of punctuated addition of juvenile crust during extension in the Goochland Terrane,central Appalachian Piedmont Province

ABSTRACT

The Goochland Terrane is an enigmatic crustal block in the Appalachian Piedmont Province of central Virginia, USA. Sparse exposures of terminal Mesoproterozoic and late Neoproterozoic igneous rocks in the central Goochland Terrane offer the opportunity to investigate both the continental affinity of the terrane during the Proterozoic Eon and the timing and mechanisms of crustal growth. We apply multiple geochemical tools to these rocks: tectonic discrimination using whole-rock major and trace element abundances; whole-rock Sm-Nd isotopes; O, U-Pb, and Lu-Hf isotope analyses of spots in zircon; and measurement of O isotopes in multi-grain quartz separates. Eruption of the Sabot Amphibolite protolith is difficult to date, but we tentatively assign an age of 552 ± 11 Ma. Goochland Terrane continental crust first separated from the mantle prior to ca. 1050–1010 Ma intrusion of the Montpelier Anorthosite and the State Farm Gneiss protolith. The granitic magma that became the State Farm Gneiss protolith could have been derived entirely from partial melting of this initial Goochland Terrane crust. In contrast, the magmas that became the Montpelier Anorthosite, Neoproterozoic granitoid, and the Sabot Amphibolite were mixtures of mantle melt and preexisting Goochland Terrane crust. This production of juvenile continental crust occurred during continental extension and, eventually, rifting. The timing and compositions of terminal Mesoproterozoic magmatism in the Goochland Terrane closely match those in the nearby Blue Ridge Province. Although the compositions of the Neoproterozoic magmas in the two regions are similar, intrusion and possibly eruption occurred about 10 M.y. later in the Goochland Terrane.     

Influence of an Observed Decadal Decline in Wind Speed on Turbidity in the San Francisco Estuary

Turbidity is an important habitat component in estuaries for many fishes and affects a range of other ecological functions. Decadal timescale declines in turbidity have been observed in the San Francisco Estuary (Estuary), with the declines generally attributed to a reduction in sediment supply to the Estuary and changes to the erodible sediment pool in the Estuary. However, we analyzed hourly wind data from 1995 through 2015 and found statistically significant declines of 13 to 48% in wind speed around the Estuary. This study applied a 3-D hydrodynamic, wave, and sediment transport model to evaluate the effects of the observed decrease in wind speed on turbidity in the Estuary. The reduction in wind speed over the past 20 years was predicted to result in a decrease in turbidity of 14 to 55% in Suisun Bay from October through January. These results highlight that the observed declines in both wind speed and sediment supply over the past 20 years have resulted in reduced turbidity in the San Francisco Estuary from October through January. This decline in turbidity in Suisun Bay potentially has negative effects on habitat for fish like the endangered Delta Smelt which are more commonly caught in relatively turbid water.     

Tectonic configuration of the Apuseni–Banat—Timok–Srednogorie belt, Balkans-South Carpathians, constrained by high precision Re–Os molybdenite ages

The Apuseni–Banat–Timok–Srednogorie magmatic–metallogenic belt (ABTS belt), forms a substantial metallogenic province in the Balkan-South Carpathian system in southeastern Europe. The belt hosts porphyry, skarn, and epithermal deposits mined since pre-Roman times. Generally, the deposits, prospects, and occurrences within the belt are linked to magmatic centers of calc-alkaline affinity. Fifty-one rhenium-osmium (Re–Os) ages and Re concentration data for molybdenites define systematic geochronologic trends and constrain the geochemical-metallogenic evolution of the belt in space and time. From these data and additional existing geologic-geochemical data, a general tectonic history for the belt is proposed. Mineralization ages in Apuseni-Banat, Timok, and Panagyurishte (the central district of the larger E–W Srednogorie Zone) range from 72–83, 81–88, and 87–92 Ma, respectively, and clearly document increasing age from the northwestern districts to the southeastern districts. Further, Re–Os ages suggest rapidly migrating pulses of Late Cretaceous magmatic–hydrothermal activity with construction of deposits in ~1 m.y., districts in ~10 m.y., and the entire 1,500 km belt in ~20 m.y. Ages in both Timok and Panagyurishte show systematic younging, while deposit ages in Banat and Apuseni are less systematic reflecting a restricted evolution of the tectonic system. Systematic differences are also observed for molybdenite Re concentrations on the belt scale. Re concentrations generally range from hundreds to thousands of parts per million, typical of subduction-related Cu–Au–Mo–(PGE) porphyry systems associated with the generation of juvenile crust. The geochronologic and geochemical trends are compatible with proposed steepening of subducting oceanic slab and relaxation of upper continental plate compression. Resulting influx of sub-continental mantle lithosphere (SCML) and asthenosphere provide a fertile metal source and heat, while the subducting slab contributes connate and mineral dehydration fluids, which facilitate partial melting and metal leaching of SCML and asthenosphere. Cu–Au–Mo–(PGE) porphyry deposits may develop where melts are trapped at shallow crustal levels, often with associated volcanism and epithermal-style deposits (South Banat, Timok, and Panagyurishte). Mo–Fe–Pb–Zn skarn deposits may develop where felsic melts are trapped adjacent to Mesozoic limestones at moderate crustal levels (North Banat and Apuseni). Systematic spatial variations in deposit style, commodity enrichment, Re–Os ages, and Re concentrations support specific tectonic processes that led to ore formation. In a post-collisional setting, subduction of Vardar oceanic crust may have stalled, causing slab steepening and rollback. The slab rollback relaxes compression, facilitating and enhancing orogenic collapse of previously thickened Balkan-South Carpathian crust. The progression of coupled rollback-orogenic collapse is evidenced by the width of Late Cretaceous extensional basins and northward younging of Re–Os ages, from Panagyurishte (~60 km; 92–87 Ma) to Timok (~20 km; 88–81 Ma) to Apuseni-Banat (~5 km; 83–72 Ma). Generation of a well-endowed mineral belt, such as the ABTS, requires a temporally and spatially restricted window of magmatic–hydrothermal activity. This window is quickly opened as upper plate compression relaxes, thereby inducing melt generation and ingress of melt to higher crustal levels. The window is just as quickly closed as upper plate compression is reinstated. The transient tectonic state responsible for economic mineralization in the ABTS belt may be a paleo-analogue to transient intervals in the present subduction tectonics of SE Asia where much mineral wealth has been created in the last few million years.     

Isotopic Ratios Reveal Mixed Seasonal Variation Among Fishes from Two Subtropical Estuarine Systems

Characterizing dietary resources and species interactions in estuaries is challenging, particularly when considering the dynamic nature of these ecosystems, the ranges in body sizes of species, and the potential for trophic roles to vary with ontogeny. We examined the influence of season and location on relationships between body size and δ¹⁵N, δ¹³C, and δ³⁴S values across a range of fishes from two subtropical estuaries. The results suggest that isotopic values of estuarine fishes are independent of body size. However, seasonal variation propagated throughout the assemblage as the majority of fishes integrated different δ¹⁵N, δ¹³C, or δ³⁴S values. The absence of δ¹⁵N–, δ¹³C–, and δ³⁴S–body size relationships suggests that either (1) dietary preference of these fishes do not shift within the range of body sizes sampled, (2) these fishes shift to an alternate diet that is not isotopically distinct, or (3) that spatial and temporal variation in isotopic signatures of prey negate any size-based relationships. Seasonal variability in the isotopic values of these fishes suggests either movement to an alternative habitat or a shift in organic matter source associated with the transition of dry to wet seasons. Moreover, variance distributions of the best-fit models indicate that seasonal dietary preferences of conspecifics do not vary over moderate spatial scales. Seasonal variability among fishes in these estuaries suggests plasticity in feeding strategies that may afford greater adaptive flexibility to these species in response to changes in food availability resulting from variable environmental conditions.     

The filtering capacity of a tropical riverine wetland: II. Sediment and nutrient balances

The ability of wetlands to improve the quality of water has long been recognized and has led to the proliferation of wetlands as a means to treat diffuse and point source pollutants from a range of land uses. However, much of the existing research has been undertaken in temperate climates with a paucity of information on the effectiveness of wetlands, particularly natural wetlands, in tropical regions. This paper contributes to addressing this issue by presenting a comprehensive measurement based assessment of the potential for a naturally occurring tropical riverine wetland to improve the quality of the water entering it. We found small net imports and exports of sediment to/from the wetland in individual years, but over the longer term this kind of wetland is neither a sink nor source of sediment. In contrast, phosphorus was continually removed by the wetland with an overall net reduction of 14%. However, it should be noted that there is no ‘permanent’ gaseous loss mechanism for phosphorus, and its removal from the water column is equal to its accumulation in the wetland soil. We found very little removal of nitrogen by this type of wetland from several analyses including: (i) Surface and groundwater fluxes, (ii) Estimation of water column and soil denitrification rates, (iii) Wetland residence times, and (iv) Hydraulic loading. We also found no clear evidence for transformation of nitrogen to more or less bio‐available forms. Hence, while the benefits of using wetlands to improve water quality in controlled environments have been demonstrated in the literature, these benefits may not always be directly translated to unmanaged natural wetland systems when there is strong seasonality in flows and short residence time during the periods of maximum sediment and nutrient load. Copyright © 2011 John Wiley & Sons, Ltd.     

Single-Well Injection-Drift Test to Estimate Groundwater Velocity

A simple algebraic equation is presented here to estimate the magnitude of groundwater velocity based on data from a single-well injection-drift test thereby eliminating the time-consuming and costly extraction phase. A volume of tracer-amended water was injected by forced-gradient into a single well followed by monitoring of the conservative solute tracers under natural-gradient conditions as their upgradient portions drifted back through the well. The breakthrough curve data from the single well during the drift phase was analyzed to determine the mean travel times of the tracers. The estimated mean upgradient travel distance back through the single well and the mean travel times of the tracers were used in a simple algebraic equation to estimate groundwater velocity. The groundwater velocity based on the single-well injection-drift test was estimated to be approximately 0.64 ft per day. Two transects of observation wells were used to monitor the natural-gradient tracer transport downgradient of the injection well. The one-dimensional, or dual-well, transport of the tracer from the injection well to the nearest downgradient observation well indicated that the groundwater velocity was 0.55 ft per day. The two-dimensional, or multi-well, transport of the center of mass of the tracers indicated that the groundwater velocity was 0.60 ft per day; the dual- and multi-well results were in excellent agreement with those from the single-well and validated the simple algebraic equation. The new single-well method presented here is relatively simple, rapid, and does not require an extraction phase.