Petrogenesis and Geodynamic Implications of Late Cenozoic Basalts in North Queensland, Australia: Trace-element and Sr-Nd-Pb Isotope Evidence

Radiogenic isotopic (Sr–Nd–Pb) and trace-elementcompositions of late Cenozoic basalts from two discrete geographicalregions in North Queensland, Australia, can be used to identifycontributions from geochemically distinctive mantle source components.The North Queensland basalts have positive     

Anatomy of an avulsion

The Cumberland Marshes in east-central Saskatchewan, Canada, occupy over 5000 km² and contain a variety of active and abandoned fluvial features, including straight to sinuous isolated channels, anastomosed channel systems, levees, and crevasse splays in addition to marshes, lakes and bogs. In 1873, an avulsion of the Saskatchewan River diverted most of its flow into a portion of the Cumberland Marshes (locally termed the breakout area), and altered the alluvial terrain as the invaded wetlands adjusted to the influx of sediment and water. These adjustments continue today, and so far over 500 km² of wetlands have been affected by the avulsion. Avulsion-controlled modification of the wetlands involves the initiation and evolution of crevasse splays and splay complexes. Three intergradational forms are recognized, each associated with characteristic sand-body geometries. Stage I splays are small, lobate in plan, crossed by unstable distributary channels, and form wedge-shaped sheets which depositionally overlie fine-grained, organic-rich wetland sediments. Stage II splays and splay complexes evolve both spatially and temporally from Stage I splays. They are larger, contain dense networks of anastomosed channels, and form disconnected tabular sand bodies or continuous sand sheets, some of which incise underlying wetland sediments. Stage III splays develop from either Stage I or II splays and contain few but stable anastomosed channels that deposit isolated stringer sands encased in fine-grained floodplain sediments. Although sand bodies deposited by splays comprise important components of the evolving floodplain, various fine-grained facies occurring in levees, shallow lakes, abandoned splay channels, and interchannel floodplains dominate the avulsion deposits. The post-1873 record of deposition and terrain modification in the breakout area suggests four stages of floodplain evolution following avulsion. In the initial avulsion stage, new channels and splay complexes increase in numbers rapidly as diverted discharge of water and sediment overwhelm the adjacent floodbasin. The anastomosed stage is characterized by an approximate balance between rates of new channel and splay development, and abandonment of old ones. This stage continues for as long as new floodplain areas are invaded. The rate of new splay development eventually decreases as accessible floodplain becomes aggraded, forcing a higher rate of channel abandonment and concentration of remaining flow into fewer but larger channels (reversion stage). The result of reversion is eventual return to a single channel stage, completing the avulsive sequence and initiating a new alluvial ridge. For the Saskatchewan River, this final-stage single channel will likely produce a meander belt which occupies only a portion of the more extensive avulsion belt which preceded it.     

The composition and thickness of the crust of Mars estimated from rare earth elements and neodymium-isotopic compositions of Martian meteorites

Abstract— Isotopic and trace element compositions of Martian meteorites show that early differentiation of Mars produced complementary crustal and mantle reservoirs that were sampled by later magmatic events. This paper describes a mass balance model that estimates the rare earth element (REE) content and thickness of the crust of Mars from the compositions of shergottites. The diverse REE and Nd isotopic compositions of shergottites are most easily explained by variable addition of light rare earth element (LREE)–enriched crust to basaltic magmas derived from LREE-depleted mantle source regions. Antarctic shergottites EET 79001, ALH 77005, LEW 88516, and QUE 94201 all have strongly LREE-depleted patterns and positive initial ¹⁴³Nd isotopic compositions, which is consistent with the generation of these magmas from depleted mantle sources and little or no interaction with enriched crust. In contrast, Shergotty and Zagami have negative initial ¹⁴³Nd isotopic compositions and less pronounced depletions of the LREE, which have been explained by incorporation of enriched crustal components into mantle-derived magmas (Jones, 1989; Longhi, 1991; Borg et al., 1997). The mass balance model presented here derives the REE composition of the crustal component in Shergotty by assuming it represents a mixture between a mantle-derived magma similar in composition to EET 79001A and a LREE-enriched crustal component. The amount of crust in Shergotty is constrained by mixing relations based on Nd-isotopic compositions, which allows the REE pattern of the crustal component to be calculated by mass balance. The effectiveness of this model is demonstrated by the successful recovery of important characteristics of the Earth's continental crust from terrestrial Columbia River basalts. Self-consistent results for Nd-isotopic compositions and REE abundances are obtained if Shergotty contains ～10–30% of LREE-enriched crust with >10 ppm Nd. This crustal component would have moderately enriched LREE (Sm/Nd = 0.25–0.27; ¹⁴⁷Sm/¹⁴⁴Nd = 0.15–0.17; La/Yb = 2.7–3.8), relatively unfractionated heavy rare earth elements (HREE), and no Eu anomaly. Crust with these characteristics can be produced from a primitive lherzolitic Martian mantle by modest amounts (2–8%) of partial melting, and it would have a globally averaged thickness of <45 km, which is consistent with geophysical estimates. Mars may serve as a laboratory to investigate planetary differentiation by extraction of a primary basaltic crust.     

Vegetation patterns, recent pollen deposition and distribution of non-pollen palynomorphs in a polygon mire near Chokurdakh (NE Yakutia, NE Siberia)

Fine-scaled distribution patterns of vegetation and palynomorphs in a polygon mire in NE Siberia were studied in 31 × 31 plots of 1 m² (vegetation) and along a transect at intervals of 1 m (palynomorphs). Pollen and non-pollen-palynomorph contents clearly reflect differences between polygon ridges and centres. For most single pollen types, however, no unambiguous relation with actual plant abundances and distribution exists. High pollen values are restricted to the immediate vicinity of the pollen sources, which is attributed to the low height of the vegetation. For several plant taxa, high pollen values were found to be restricted to particular plant specimens in the population. High values of pollen ascribed to taxa currently absent at the relevant plot show that the sampled mosses contain a pollen signal of several years. Betula exilis produces two morphologically clearly distinct pollen types. The distribution of selected non-pollen palynomorphs correlates to microrelief, moisture regime and/or trophic conditions. The study shows that single palaeo-sections from arctic peatlands should not be over-interpreted with respect to their palaeoecological value. Local vegetation types and site conditions, however, can be accurately reconstructed from the total assemblages and from combined occurrences of specific palynomorph types.     

Organic Gases in Fluid Inclusions of Ore Minerals and Their Constraints on Ore Genesis: A Case Study of the Changkeng Au-Ag Deposit, Guangdong, China

The newly discovered Changkeng Au-Ag deposit is a new type of sediment-hosted precious metal deposit. Most of the previous researchers believed that the deposit was formed by meteoric water convection. By using a high vacuum quadrupole gas mass spectrometric system, nine light hydrocarbons have been recognized in the fluid inclusions in ore minerals collected from the Changkeng deposit. The hydrocarbons are composed mainly of saturated alkanes C1-4 and unsaturated alkenes C2-4 and aromatic hydrocarbons, in which the alkanes are predominant, while the contents of alkenes and aromatic hydrocarbons are very low. The Σalka/Σalke ratio of most samples is higher than 100, suggesting that those hydrocarbons are mainly generated by pyrolysis of kerogens in sedimentary rocks caused by water-rock interactions at medium-low temperatures, and the metallogenic processes might have not been affected by magmatic activity. A thermodynamic calculation shows that the light hydrocarbons have reached chemical equilibrium     

Light Hydrocarbons in Fluid Inclusions and Their Constraints on Ore Genesis: A Case Study of the Songxi Ag (Sb) Deposit, Eastern Guangdong, China

The Songxi deposit is a newly discovered large Ag (Sb) deposit. By using a suite of high-vacuum quadrupole gas mass spectrometer systems, the authors have recognized many kinds of light hydrocarbons in fluid inclusions of minerals. These hydrocarbons are mainly composed of C1-C4 saturated alkanes, while the contents of C2-C4 unsaturated alkenes and aromatic hydrocarbons are quite low, suggesting that the metallogenic processes have not been affected by magmatic activities. Chemical equilibrium studies show that these hydrocarbons may be a mixture of organic gases generated by microorganism activity and those by thermal cracking of type-n kerogens (kukersite) in sedimentary host rocks, and the former may constitute more than two-thirds, implying that microorganism might have played an important role in the metallogenesis. The equilibrium temperature of the latter is about 300℃, which is much higher than the geothermal temperature at the estimated depth of metallogenesis. Thus, the light hydrocarbons gen     

QUANTITATIVE ANALYSIS OF TRACE ELEMENTS IN GEOLOGICAL MATERIALS BY LASER ABLATION ICPMS: INSTRUMENTAL OPERATING CONDITIONS AND CALIBRATION VALUES OF NIST GLASSES

A UV laser ablation microprobe coupled to an ICPMS has been used to determine trace element concentrations in solids with a spatial resolution of 50 microns and detection limits ranging from 2 μg/g for Ni to 50 ng/g for the REE, The, and U. Experiments designed to optimize laser operating conditions show that pulse rates of 4 Hz produce a steady state signal with less inter-element fractionation per unit time than higher pulse rates (10–20 Hz). Comparisons of laser microprobe analyses of garnets and pyroxenes using the NIST 610 and 612 glasses as calibration standards, with proton microprobe, solution ICPMS, INAA and XRF data show no significant matrix effects. Laser microprobe analyses of the NIST 610 and 612 glasses have a precision and accuracy of 2–5%, and error analysis shows that counting statistics and the precision on the internal standard concentration accounts for the analytical uncertainty. The NIST glasses appear to be useful calibration materials for trace element analysis of geological materials by laser microprobe.