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921.
The chemical speciation of dissolved mercury in surface waters of Galveston Bay was determined using the concentrations of mercury-complexing ligands and conditional stability constants of mercury-ligand complexes. Two classes of natural ligands associated with dissolved organic matter were determined by a competitive ligand exchange-solvent solvent extraction (CLE-SSE) method: a strong class (Ls), ranging from 19 to 93 pM with an average conditional stability constant (KHgLs) of 1028, and a weak class (Lw) ranging from 1.4 to 9.8 nM with an average KHgLs of 1023. The range of conditional stability constants between mercury and natural ligands suggested that sulfides and thiolates are important binding sites for dissolved mercury in estuarine waters. A positive correlation between the estuarine distribution of dissolved glutathione and that of mercury-complexing ligands supported this suggestion. Thermodynamic equilibrium modeling using stability constants for HgL, HgClx, Hg(OH)x, and HgCl(OH) and concentrations of each ligand demonstrated that almost all of the dissolved mercury (> 99%) in Galveston Bay was complexed by natural ligands associated with dissolved organic matter. The importance of low concentrations of high-affinity ligands that may originate in the biological system (i.e., glutathione and phytochelatin) suggests that the greater portion of bulk dissolved organic matter may not be important for mercury complexation in estuarine surface waters.  相似文献   
922.
A geomorphological and statistical analysis of slope canyons from the northern KwaZulu-Natal continental margin is documented and compared with submarine canyons from the Atlantic margin of the USA. The northern KwaZulu-Natal margin is characterized by increasing upslope relief, concave slope-gradient profiles and features related to upslope growth of the canyon forms. Discounting slope-gradient profile, this morphology is strikingly similar to canyon systems of the New Jersey slope. Several phases of canyon incision indicate that downslope erosion is also an important factor in the evolution of the northern KwaZulu-Natal canyon systems. Despite the strong similarities between the northern KwaZulu-Natal and New Jersey slope-canyon systems, key differences are evident: (1) the concavity of the northern KwaZulu-Natal slope, contrasting with the ∼linear New Jersey slope; (2) the relative isolation of the northern KwaZulu-Natal canyons, rather than the dense clustering of the New Jersey canyons; and (3) the absence of strongly shelf-breaching canyons along the northern KwaZulu-Natal margin. In comparison with the New Jersey margin, we surmise a more youthful stage of canyon evolution, a result of either the canyons themselves being younger or the formative processes being less active. Less complicated patterns of erosion resulting from reduced sediment availability have developed in northern KwaZulu-Natal. The reduction in slope concavity on the New Jersey margin may be the result of grading of the upper slope by intensive headward erosion, a process more subdued—or less evident—on the KwaZulu-Natal margin.  相似文献   
923.
This session presented a wide range of papers on cooperativeresearch, design of alternative gears and fishing strategies,and new analyses to support management. The contributed papersreflected a real desire to explore different approaches andstrategies to fishery management. It is apparent that fishery policy has had a mixed record ofsuccess and failure at best. In most regions of the world, manystocks are still being overfished or have been severely overfishedin the past. Although rebuilding programmes for overfished stockshave been developed, nationally as well as internationally,only a few have been successful, many others are works in progressand, in too many cases, rebuilding  相似文献   
924.
A comparison of methods for the calculation of the hydrodynamic characteristics of arrays of wave power devices is presented. In particular, the plane-wave approximation and an exact multiple scattering formulation have been used to compute exciting wave forces, hydrodynamic coefficients and q factors for arrays of interacting wave power devices. The results obtained are compared with each other, and accuracy aspects of the computations are stressed and critically assessed.  相似文献   
925.
Considerable metal enrichments have been found in hydrothermal fluids and metalliferous sediments off the central Lesser Antilles Volcanic Arc. The elements variably enriched in the fluids as a result of the hydrothermal activity are Fe, Mn, As, Si, B, Li and in the sediments, Fe, P, Mo, As, Sb, Hg, Cu and Pb. Variations in the concentrations of these elements in both fluids and sediments along the arc result from a number of factors, the most important of which is the stage that each island's volcano has reached in its eruptive cycle. Although hydrothermal mineralization on the sea floor off the islands is only low grade, phase separation in the hydrothermal fluids at depth could be leading to higher grade stockwork mineralization below the vent fields or the discharge of metal rich brines on the lower flanks of the volcanic islands.  相似文献   
926.
The analytical method developed by Svendsen (1968) for a forced heave motion is extended to the general problem of wave induced heave, roll and sway motions of a long ship at a depth of water which is only slightly larger than the draught of the ship. This corresponds, for example, to the situation of a fully loaded ship in a harbour area.After linearization of the problem, the water motion is considered for each of the three individual motions and for the wave reflection-transmission problem for a fixed ship. The ensuing results for the forces on the ship are then synthesized to form the equations of motion, which are presented with all coefficients given, including mooring forces.Analytical and numerical results are given for the three components of motion, for the associated resonance frequencies, and for the hydrodynamic masses and moments of inertia. Finally, the assumptions used are analyzed and evaluated by comparison with measurements and with other results for a special case.  相似文献   
927.
928.
929.
Water surface profiles and horizontal and vertical water particle velocity components have been measured to investigate the properties of intermediate depth waves generated in the laboratory. The data has been compared with linear wave theory. It was found that linear theory predicted the attenuation of velocity field with depth successfully and that it overestimates both components of velocity slightly.  相似文献   
930.
A 9.1 m yacht hull was instrumented to measure its three-dimensional motion when moored in the open sea. The hull was deployed on three occasions for a total period of about 2 months and encountered a wide range of wind-wave conditions including a strong gale. The data have been analysed to give the response for each component of motion in terms of amplitude and relative phases. The hull motion is compared spectrally to the waves observed by a nearby Waverider. The hull was found to behave as a surface-keyed buoy, with a well defined response for a wide range of conditions. The presence of a resonance in pitch and roll is evident in the data with typical rms values being 5° and 10°, respectively, for significant wave height of 5 m. From data on the mooring dynamics it is concluded that the peaks observed in the tension are a result of the viscous drag opposing the change in the catenary of the mooring and the slow drift oscillations of the buoy. This type of hull is a versatile and economical candidate as a platform for meteorological and oceanographic instrumentation.  相似文献   
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