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181.
Philip L. Verplanck D. Kirk Nordstrom Geoff S. Plumlee Richard B. Wanty Dana J. Bove Jonathan S. Caine 《中国地球化学学报》2006,25(B08):231-231
In southern Rocky Mountains, catchments characterized by acidic, metalliferous waters that are relatively unaffected by human activity usually occur within areas that have active or historical mining activity. The US Geological Survey has utilized these mineralized but unmined catchments to constrain geochemical processes that control the surface- and ground-water chemistry associated with near surface acid weathering as well as to estimate premining conditions. Study areas include the upper Animas River watershed, Lake City, Mt. Emmons, and Montezuma in Colorado and Questa in New Mexico. Although host-rock lithologies range from Precambrian gneisses to Cretaceous sedimentary units to Tertiary volcanic complexes, mineralization is Tertiary in age and associated with intermediate to felsic composition, porphyritic plutons. Pyrite is ubiquitous. Variability of metal concentrations in water is caused by two main factors: mineralogy and hydrology. Parameters that potentially affect water chemistry include: host-rock lithology, intensity of hydrothermal alteration, sulfide mineralogy and chemistry, gangue mineralogy, length of flow path, precipitation, evaporation, and redox conditions. Springs and headwater streams have pH values as low as 2.5, sulfate up to 3700 mg/L and high dissolved metal concentrations (for example: Al up to 170 mg/L; Fe up to 250 mg/L; Cu up to 3.5 mg/L and Zn up to 14 mg/L). With the exception of evaporative waters, the lowest pH values and highest Fe and Al concentrations occur in water draining the most intense hydrothermally altered areas consisting of the mineral assemblage quartz-sericite-pyrite. Stream beds tend to be coated with iron floc, and some reaches are underlain by ferricrete. When iron-rich ground water interacts with oxygenated waters in the stream or hyporheic zone, ferrous iron is oxidized to ferric iron, which is less soluble, leading to the precipitation of iron oxyhydroxides. 相似文献
182.
Robert G. Eppinger Paul H. Briggs Cynthia Dusel-Bacon Stuart A. Giles Larry P. Gough Jane M.Hammarstrom Bernard E. Hubbard 《中国地球化学学报》2006,25(B08):232-232
The Bonnifield district hosts 26 tmmined volcanogenic massive sulfide (VMS) occurrences. Environmental geochemical samples of water and stream sediment were collected at several occurrences, concentrating on the two best-exposed and largest deposits, Red Mountain (RM) and Sheep Creek (SC). Limited samples were also collected at the poorly exposed WTF deposit. The deposits are Late Devonian to Early Mississippian, and are hosted by felsic metavolcanic and carbonaceous schist members of the Totatlanika Schist or Keevy Peak Fm. Spring and stream waters at RM and SC have pH values commonly 〈3.5 (as low as 2.4 at RM and 2.5 at SC), high conductivity (up to 11000 μS/cm), and very high (Is to 100s mg/L) dissolved contents of Al, Cd, Co, Cu, Fe, Ni, and Pb. Waters at RM are characterized by extremely high REE contents (summed REE median 3200 μg/L, n=33). At both RM and SC, pyrite oxidation and dissolution produce low pH waters that interact with and dissolve bedrock minerals, resulting in acidic, metal-laden, naturally degraded streams that are mostly devoid of aquatic life. Ferricrete is common. In contrast, WTF barely produces a surficial environmental footprint, mostly due to topography and relief. RM and SC are well exposed in the areas of relatively high relief, and both exhibit extensive areas of quartz-sericite-pyrite-alteration. While WTF shares many of the same deposit-and alteration characteristics, it is concealed by tundra in a large, nearly flat area. Surface water at WTF is absent and outcrops are sparse. Even though WTF is roughly the same size as Red Mountain (both around 3 million tonnes) and has similar base- and precious-metal grades, the surficial geochemical manifestation of WTF is minimal. However, exposure through mining of the altered, mineralized rock at WTF potentially could initiate the same processes of pyrite oxidation, acid generation, and mineral dissolution that are observed naturally at RM and SC. 相似文献
183.
Huiwen HSIAO Susanne M. Ullrich Trevor W. Tanton 《中国地球化学学报》2006,25(B08):233-233
This research aims to establish the risks of hurnan exposure to modeling approach. The study site was located on the River Nura 1990s, an acetaldehyde production plant located in the industrial high environmental mercury levels, based on a quantitative risk in central Kazakhstan. From the 1950s until its closure in the mid city of Temirtau released mercury-containing wastewater into the river. River sediments are highly contaminated with mercury up to a distance of 25 km and beyond. In addition, a local power station released an estimated 6 million tonnes of fly-ash into the water and the mercury has become quite tightly associated with the ash deposits. River water, fish and agricultural land in the floodplain are also contaminated with mercury, yet the risks posed to the local population have not been evaluated to date. In June and July 2005, we took samples of soil, interior and exterior dust, drinking water, and food from individual households, communal areas and markets. Additionally, water and sediment samples and fish were taken from the river. Interviews were conducted with householders to establish their age and body weight, general living conditions and sources of irrigation and drinking water. A food frequency questionnaire (FFQ) was designed to investigate the frequencies of consumption of several common regional food items, including fish from the fiver and/or local market. Human hair samples were also collected to estimate the mercury bioburden and to enable the validity of the modeling approach to be established. The paper expands on the main pathways of contamination and looks at linkages between exposure pathways and mercury concentrations found in human hair. Uncertainties inherent in risk analysis as well as their influence on the relative importance of different exposure routes are also discussed. 相似文献
184.
Samantha R. Cook John M. Chamock Andrew Parker 《中国地球化学学报》2006,25(B08):247-247
The mainly 19th Century canal system in the UK, largely managed by British Waterways, has been increasingly brought back into operation over the last few decades, and is now widely used for both leisure, and, increasingly, transport. Both initial and routine dredging of the canal sediment is carried out and these sediments are generally disposed of to land. Because many of the canals were connected with primary industries, their sediments can locally be significantly contaminated with heavy metals, and the behaviour of these metals under differing redox conditions, when introduced into a new environment (i.e., on land) is of importance for environmental risk-assessment purposes. Canal sediments are often rich in sulfidic mineral phases, and we have attempted to quantify the influence of these sulfidic phases on the release and retention of metals in dredged canal sediments, using a combination of traditional chemical techniques (e.g. sequential extraction) and X-ray absorption spectroscopy (XAS). Sediment samples have been collected from urban fresh-water canals, one in the British Midlands and one in Northern France. It appears from XAS that Cd is largely associated with oxygen in air-dried sediment, and with sulphur in vacuum-dried sediment. 相似文献
185.
UKAEGBU V. U. EKWUEME B. N. 《中国地球化学学报》2006,25(2):122-131
1 IntroductionThe study area is part of the Obudu Plateau,which forms part of the Precambrian Pan-African tec-tonothermal belt, lying between the West African Cra-ton and the Gabon-Congo Craton ( Fig. 1). It isbounded by the Benue Trough, in the NE-SW axi… 相似文献
186.
Gehad M. Saleh 《中国地球化学学报》2006,25(4):307-317
1 Introduction The association of massive Fe-Ni-Cu sulfides andchromite is a very unusual feature of podiformchromitites occurring in mantle tectonites of ophioliticcomplexes. It has only been described in theSoutheastern Desert, Egypt, where sulfides a… 相似文献
187.
提出了一种用于处理多高光谱卫星数据的UPDM分析方法。研究结果证明.该方法应用干Landsat/TM(ETM^-)、Terra/MODIS和ADEOS—II/GLI等高光谱卫星传感器时.光谱重构均方根误差小于0.029适用于研究高光谱卫星遥感数据。 相似文献
188.
189.
J.R.DODSON A.RAMRATH 《地学前缘》2002,9(1):62-72
第三纪的板块运动驱动着澳大利亚的气候和植被进行演化。广布的湿润森林区是澳大利亚老第三纪的特征。一直到始新世 ,生物多样性都在不断地提高。毫无疑问 ,这是澳大利亚由高南纬区向北部中纬区运移的结果。从始新世到上新世 ,澳大利亚的气候总体上要比现在湿润 ,但降水量季节性变化的增强推动了中新世以后硬叶植物和旱生植物的发展。上新世晚期似乎与第四纪一样 ,都出现过周期性干旱。这种干旱与冰期条件有关 ,至少由南澳大利亚晚第四纪的记录可以认识到这一点 ,澳大利亚的这段历史与东亚的气候变迁是同步发生的。在东亚 ,印—澳板块的运动致使青藏高原抬升 ,从而引发了区内乃至全球气候的巨变。穿越赤道区的季风和信风的环流格局 ,致使新第三纪和第四纪中国与澳大利亚的气候系统的相关性更强。 相似文献
190.
利用欧洲资源卫星1号和2号获取的重轨干涉测量雷达数据,首先进行干涉测量数据相关性估测,并结合干涉测量数据的振幅信息,开展新疆喀什试验区地表土地类型的识别与分类,区分和识别出裸土、盐碱地、灌丛、裸岩/戈壁、沼泽和水体 6类土地类型。最后通过对不同土地类型的后向散射特性和相关性的分析,探讨了干涉测量数据相关性与干旱-半干旱地区地表特征的关系。 相似文献