In vitro simulation of oxic/suboxic diagenesis in an estuarine fluid mud subjected to redox oscillations

Estuarine turbidity maxima (ETMs) are sites of intense mineralisation of land-derived particulate organic matter (OM), which occurs under oxic/suboxic oscillating conditions owing to repetitive sedimentation and resuspension cycles at tidal and neap-spring time scales. To investigate the biogeochemical processes involved in OM mineralisation in ETMs, an experimental set up was developed to simulate in vitro oxic/anoxic oscillations in turbid waters and to follow the short timescale changes in oxygen, carbon, nitrogen, and manganese concentration and speciation. We present here the results of a 27-day experiment (three oxic periods and two anoxic periods) with an estuarine fluid mud from the Gironde estuary. Time courses of chemical species throughout the experiment evidenced the occurrence of four distinct characteristic periods with very different properties. Steady oxic conditions were characterised by oxygen consumption rates between 10 and 40 μmol L⁻¹ h⁻¹, dissolved inorganic carbon (DIC) production of 9–12 μmol L⁻¹ h⁻¹, very low NH₄⁺ and Mn²⁺ concentrations, and constant NO₃⁻ production rates (0.4 - 0.7 μmol L⁻¹ h⁻¹) due to coupled ammonification and nitrification. The beginning of anoxic periods (24 h following oxic to anoxic switches) showed DIC production rates of 2.5–8.6 μmol L⁻¹ h⁻¹ and very fast NO₃⁻ consumption (5.6–6.3 μmol L⁻¹ h⁻¹) and NH₄⁺ production (1.4–1.5 μmol L⁻¹ h⁻¹). The latter rates were positively correlated to NO₃⁻ concentration and were apparently caused by the predominance of denitrification and dissimilatory nitrate reduction to ammonia. Steady anoxic periods were characterised by constant and low NO₃⁻ concentrations and DIC and NH₄⁺ productions of less than 1.3 and 0.1 μmol L⁻¹ h⁻¹, respectively. Mn²⁺ and CH₄ were produced at constant rates (respectively 0.3 and 0.015 μmol L⁻¹ h⁻¹) throughout the whole anoxic periods and in the presence of nitrate. Finally, reoxidation periods (24–36 h following anoxic to oxic switches) showed rapid NH₄⁺ and Mn²⁺ decreases to zero (1.6 and 0.8–2 μmol L⁻¹ h⁻¹, respectively) and very fast NO₃⁻ production (3 μmol L⁻¹ h⁻¹). This NO₃⁻ production, together with marked transient peaks of dissolved organic carbon a few hours after anoxic to oxic switches, suggested that particulate OM mineralisation was enhanced during these transient reoxidation periods. An analysis based on C and N mass balance suggested that redox oscillation on short time scales (day to week) enhanced OM mineralisation relative to both steady oxic and steady anoxic conditions, making ETMs efficient biogeochemical reactors for the mineralisation of refractory terrestrial OM at the land-sea interface.     

Draconids 2011: Outburst Observations by the Croatian Meteor Network

The predicted Draconid meteor shower outburst during October 2011 had been observed by a portion of the Croatian Meteor Network whose stations encountered clear weather. A total of 95 Draconid orbits have been calculated from 18 contributing stations, and in this paper we present results for 63 orbits obtained from the fully automatic observation and processing pipeline. Two methods of trajectory estimation were applied, showing better fit results using a linearly changing velocity model versus a constant velocity model. The estimated mean radiant position has been found to be at RA = 262.6°, Dec = +55.7°, with estimated geocentric velocity Vg = 20.7 km/s.     

100-yr mass-loss modulations on the asymptotic giant branch

We analyse the differences in infrared circumstellar dust emission between oxygen-rich Mira and non-Mira stars, and find that they are statistically significant. In particular, we find that these stars segregate in the K–[12] versus [12]–[25] colour–colour diagram, and have distinct properties of the IRAS LRS spectra, including the peak position of the silicate emission feature. We show that the infrared emission from the majority of non-Mira stars cannot be explained within the context of standard steady-state outflow models.
The models can be altered to fit the data for non-Mira stars by postulating non-standard optical properties for silicate grains, or by assuming that the dust temperature at the inner envelope radius is significantly lower (300–400 K) than typical silicate grain condensation temperatures (800–1000 K) . We argue that the latter is more probable and provide detailed model fits to the IRAS LRS spectra for 342 stars. These fits imply that two-thirds of non-Mira stars and one-third of Mira stars do not have hot dust (>500 K) in their envelopes.
The absence of hot dust can be interpreted as a recent (∼100 yr) decrease in the mass-loss rate. The distribution of best-fitting model parameters agrees with this interpretation and strongly suggests that the mass loss resumes on similar time-scales. Such a possibility appears to be supported by a number of spatially resolved observations (e.g. recent Hubble Space Telescope images of the multiple shells in the Egg Nebula) and is consistent with new dynamical models for mass loss on the asymptotic giant branch.     

Thermal stability of extended clusters in dravite: a combined EMP,SREF and FTIR study

A dravite from Yemen of near end-member composition was treated in air and hydrogen atmospheres at 600–900 °C to reveal changes in Mg and Al order over the octahedrally coordinated Y and Z sites, and to explore related changes in the characteristic vibrational bands in the principal (OH)-stretching frequency. Relevant information was obtained using electron microprobe analysis (EMPA), structural refinement (SREF) and polarized infrared (IR) single-crystal spectroscopy. Overall, the EMPA, SREF and IR data show that only minor changes occur during thermal treatment up to at least 800 °C, including variations in structural parameters, Mg–Al order–disorder and (OH)-stretching bands, indicating limited hydrogen loss. Untreated and treated dravite samples have very similar long-range and short-range atomic structures, which may be related to the occurrence of stable Al–Mg extended clusters around the O1 (=W) and O3 (=V) sites: ^W(F)–^Y(MgMgMg)–^V(OH)₃–^Z[AlAlAlAlAl(Al,Mg)]; ^W(OH)–^Y(MgMgAl)–^V(OH)₃–^Z[AlAlAlAlAl(Al,Mg)]; ^W(O^2–)–^Y(AlAlAl)–^V(OH)₃–^Z[AlAlAlAlAl(Al,Mg)]. These extended clusters remain stable to temperatures close to the observed start of decomposition (~900 °C).     

Mercury contents in the vertical profiles through alluvial sediments as a reflection of mining in Idrija (Slovenia)

The influence of geomorphological factors to Hg contamination of the Idrijca River alluvial sediments because of the historical mining and ore roasting activities has been studied. Main source of Hg in alluvial sediments was dumping of ore roasting residues and mining waste into the river channel and its erosion downstream. The position of the material in relation to the geomorphological properties is highly related with its Hg content. Floodplains were found to be the most contaminated geomorphological units (mean Hg content 335 mg/kg), with Hg concentration rapidly dropping in the first terrace (155 mg/kg). The least contaminated material was found in the higher terraces (3.8 mg/kg). Sampling upstream Idrija (average Hg content is 22.1 mg/kg) shows that not only mine and ore roasting plant increased Hg levels in alluvial deposits but also contaminated sites upstream Idrija contribute to Hg contamination. Geochemical background for alluvial sediments for this area is estimated to be 0.75 mg/kg. Downstream Idrija, 9 hotspots were determined where highly contaminated material is actively eroded and carries a high risk of further contamination of the So?a River and northern Adriatic Sea ecosystems.     

Modelling of atmospheric dispersion of heavy metals in the Celje area,Slovenia

The aim of this research was to determine how fast the level of heavy metal concentrations in the air decreases in relation to increasing distance from the source of pollution and what the influence area is of the zinc smelting plant which existed for 100 years in Celje. In that period it produced approximately 580,000 tons of raw Zn from sphalerite ore by the pyrometallurgical process. The production left behind a heavily contaminated area, where the concentrations of Pb and Zn in the soil can be expressed as a percentage. A model has been made on the basis of the data of concentrations of Zn and Cd in the soil and attic dust regarding the distance and direction from the source of the pollution. Because Celje lies in a basin we chose a linear model, which describes the decreasing of the concentrations of Zn and Cd only in one direction. Sampling has been conducted on the four river valleys which stretch from the source of the pollution in all four directions: north, west, south and east, up to 13 km from the source. The power function with a negative exponent was used. With the solution to the calculated functions according to the distance, we can estimate the theoretical distance when the concentrations drop to the natural background level. The range of influence of the zinc smelting plant has been estimated to be between 14 and 52 km for the presence of anthropogenic Zn in attic dust and between 9 and 14 km for the presence of anthropogenic Zn in the soil, depending on the direction from the plant. Correlations between the measured values and the ones from the model are high: from 0.75 up to 0.98.     

Growth of complex sheeted zones during recycling of older magmatic units into younger: Sawmill Canyon area,Tuolumne batholith,Sierra Nevada,California

In Sawmill Canyon, located near the eastern margin of the Tuolumne batholith, central Sierra Nevada, California, a series of petrologically and structurally complex, magmatic sheeted zones intrude older granodioritic units (Kuna Crest and equigranular Half Dome) and in one case truncate these units along a sharp contact. These sheeted zones (a) consist of numerous batches of (now frozen) magma, (b) display clear outward growth directions, (c) were actively deforming during and after emplacement resulting in magmatic folds, faults and multiple magmatic mineral fabrics, and (d) are the location of numerous, but localized magma flow structures (schlieren-bounded tubes, troughs, megacryst-rich pipes) and instabilities (load casts, flame structures, slumps, diapirs, ridge and pillar structures). Geochemical data indicate that the sheeted zones largely consist of magmas derived from the Half Dome granodiorite with some late Cathedral Peak granodiorite pulses, and with fractionation and flow sorting forming widespread layering in the above structures.     

Climate Change Impacts and Adaptation Strategies in Spring Barley Production in the Czech Republic

The crop model CERES-Barley was used to assess the impacts of increased concentration of atmospheric CO₂ on growth and development of the most important spring cereal in Central and Western Europe, i.e., spring barley, and to examine possible adaptation strategies. Three experimental regions were selected to compare the climate change impacts in various climatic and pedological conditions. The analysis was based on multi-year crop model simulations run with daily weather series obtained by stochastic weather generator and included two yield levels: stressed yields and potential yields. Four climate change scenarios based on global climate models and representing 2 × CO₂ climate were applied. Results: (i) The crop model is suitable for use in the given environment, e.g., the coefficient of determination between the simulated and experimental yields equals 0.88. (ii) The indirect effect related to changed weather conditions is mostly negative. Its magnitude ranges from ?19% to +5% for the four scenarios applied at the three regions. (iii) The magnitude of the direct effect of doubled CO₂ on the stressed yields for the three test sites is 35–55% in the present climate and 25–65% in the 2 × CO₂ climates. (iv) The stressed yields would increase in 2 × CO₂ conditions by 13–52% when both direct and indirect effects were considered. (v) The impacts of doubled CO₂ on potential yields are more uniform throughout the localities in comparison with the stressed yields. The magnitude of the indirect and direct effects ranges from ?1 to ?9% and from +31 to +33%, respectively. Superposition of both effects results in 19–30% increase of the potential yields. (vi) Application of the earlier planting date (up to 60 days) would result in 15–22% increase of the yields in 2 × CO₂ conditions. (vii) Use of a cultivar with longer vegetation duration would bring 1.5% yield increase per one extra day of the vegetation season. (viii) The initial water content in the soil water profile proved to be one of the key elements determining the spring barley yield. It causes the yields to increase by 54–101 kg.ha^?1 per 1% increase of the available soil water content on the sowing day.