The photoelectron spectra of some Tl-Sb sulphosalts

The results of X-ray induced photoelectron spectroscopy (XPS) experiments on several phases of the ternary system Tl-Sb-S are reported. The binding energies of the inner S, Sb and Tl electrons increase with increasing quantities of Sb and decreasing amounts of Tl in these compounds. This is explained by the influences of the proportions of the bonded metals on the effective electron affinity of S. The higher proportions of the more electronegative element bonded to S cause the increase of its effective electron affinity. The results for Tl₂S (carlinite), Tl₃SbS₃, TlSbS₂ (weissbergite), TlAsS₂ (lorandite) and Sb₂S₃ (antimonite) can be interpreted in this way. The results for Tl₄S₃ suggest a predominantly covalent character of bonding for both Tl(III) and Tl(I), which are present in this sulfide. From comparison with Tl₃SbS₄ it could be supposed that Tl(III)-S bond has a more covalent character than Sb(V)-S bond. The results for Tl₃SbS₄ are in agreement with crystal structure data and the results of Moessbauer spectroscopy. For AsS (realgar) the binding energies of the inner electrons of As and S significantly increase, showing that the electrons in molecular orbitals are less strongly bonded to individual atoms, as compared to pure elements. The results for the amorphous TlSb₅S₈ (corresponding in composition to parapierrotite) suggest that in amorphous compound the Tl-S bonding is stronger and the coordination of Tl more regular than in a crystalline one.     

Magmatic structures in the Krkonoše–Jizera Plutonic Complex,Bohemian Massif: evidence for localized multiphase flow and small-scale thermal–mechanical instabilities in a granitic magma chamber

The present paper examines magmatic structures in the Jizera and Liberec granites of the Krkonoše–Jizera Plutonic Complex, Bohemian Massif. The magmatic structures are here interpreted to preserve direct field evidence for highly localized magma flow and other processes in crystal-rich mushes, and to capture the evolution of physical processes in an ancient granitic magma chamber. We propose that after chamber-wide mixing and hybridization, as suggested by recent petrological studies, laminar magma flow became highly localized to weaker channel-like domains within the higher-strength crystal framework. Mafic schlieren formed at flow rims, and their formation presumably involved gravitational settling and velocity gradient flow sorting coupled with interstitial melt escape. Local thermal or compositional convection may have resulted in the formation of vertical schlieren tubes and ladder dikes whereas subhorizontal tubes or channels formed during flow driven by lateral gradients in magma pressure. After the cessation or deceleration of channel flow, gravity-driven processes (settling of crystals and enclaves, gravitational differentiation, development of downward dripping instabilities), accompanied by compaction, filter pressing and melt segregation, dominated in the crystal mush within the flow channels. Subsequently, magmatic folds developed in schlieren layers and the magma chamber recorded complex, late magmatic strains at high magma crystallinities. Late-stage magma pulsing into localized submagmatic cracks represents the latest events of magmatic history of the chamber prior to its final crystallization. We emphasize that the most favorable environments for the formation and preservation of magmatic structures, such as those hosted in the Jizera and Liberec granites, are slowly cooling crystal-rich mushes. Therefore, where preserved in plutons, these structures may lend strong support for a “mush model” of magmatic systems.     

The chemical compositions and surface structures of two roAp stars with lithium spots (HD 83368 and HD 60435)

The spectra of two roAp stars have been analyzed as part of a project to study lithium in magnetic Ap stars. Variability of the Li I 6708 Å resonance doublet and rare-earth lines was detected, which can be explained using an oblique rotator model with the lithium spots located at the magnetic poles. Synthetic spectra obtained at different rotational phases have yielded the first data on the atmospheric chemical compositions of these spotted stars. Using refined atomic data and the most complete line lists has enabled a detailed study of the spectra near the Li I 6708 Å line and computation of the Li I line profile taking into account the spotted distribution of the lithium over the stellar surfaces. The positions of two lithium spots and lithium abundances for each of the spots have been determined.     

Improvement of Vertical Diffusion Analytic Schemes Under Stable Atmospheric Conditions

Based on gradient transport theory or K-theory, turbulent transport in the atmosphere has long been parameterized using the eddy diffusivity. Due to its simplicity, this approach has often been applied in many numerical models but rarely tested with observations. Here, the widely used O’Brien cubic polynomial approach has been validated together with an exponential approach against eddy diffusivity profiles determined from measurements and from large-eddy simulation data in stable conditions. Verification is completed by analyzing the variability effects on pollutant concentrations of two different vertical diffusion (K(z)) schemes incorporated in an atmospheric chemical model. It is shown that the analytical, exponential solution agrees better with observations than the O’Brien profile and should be used henceforth in practical applications.     

Anion chemistry on Titan: A possible route to large N-bearing hydrocarbons

The reaction of CN^? with cyanoacetylene (HC₃N), has been studied as a function of the HC₃N pressure in a quadrupole tandem mass spectrometer. The mass spectra revealed the fast depletion of the CN^? parent ion and formation of larger anions of rapidly growing size. Most of the ions observed were found to belong to two series of products: (HC₃N)_x·C_2p+1N^? and (HC₃N)_x·C_2pN^? resulting from the sequential additions of HC₃N molecules and loss of HCN or HCCN molecules. The mechanism and energetics of the first two reaction steps are briefly discussed. The laboratory data are compared with those from the Cassini CAPS-ELS spectrometer. It is believed that the reactions observed could account for the growth of anions in Titan’s ionosphere.     

IM‐based and EDP‐based decision models for the verification of the seismic collapse safety of buildings

Decision models for the verification of seismic collapse safety of buildings are introduced. The derivations are based on the concept of the acceptable (target) annual probability of collapse, whereas the decision making involves comparisons between seismic demand and capacity, which is familiar to engineering practitioners. Seismic demand, which corresponds to the design seismic action associated with a selected return period, can be expressed either in terms of an intensity measure (IM) or an engineering demand parameter (EDP). Seismic capacity, on the other hand, is defined by dividing the near‐collapse limit‐state IM or EDP by an appropriate risk‐targeted safety factor (γ _im or γ _edp ), which is the only safety factor used in the proposed decision model. Consequently, the seismic performance assessment of a building should be based on the best possible estimate. For a case study, it is shown that if the target collapse risk is set to 10^?4 (0.5% over a period of 50 years), and if the seismic demand corresponds to a return period of 475 years (10% over a period of 50 years), then it can be demonstrated that γ _im is approximately equal to 2.5 for very stiff buildings, whereas for buildings with long periods the value of γ _im can increase up to a value of approximately 5. The model using γ _edp is equal to that using γ _im only if it can be assumed that displacements, with consideration of nonlinear behavior, are equal to displacements from linear elastic analysis.     

Experimental investigation of seismic behaviour of the ancient Protiron monument model

Throughout history, dry-stone masonry structures have been strengthened with different types of metal connectors in order to increase their resistance which enabled their survival, especially in the seismically active area. One such example is the ancient Protiron monument placed in the Peristyle square of the Diocletian's Palace in Split, Croatia. The Protiron was built at the turn of the 3rd century as a stone masonry structure with dowels embedded between its base, columns, capitals and broad gable. The stone blocks in the broad gable were connected by metal clamps during restoration at the beginning of the 20th century. In order to study the seismic performance of the strengthened stone masonry structures, an experimental investigation of seismic behaviour of a physical model of the Protiron was performed on the shaking table. The model was designed as a true replica model in a length scale of 1:4 and exposed to representative earthquake with increasing intensities up to collapse. The tests provided a clear insight into system behaviour, damage mechanism and failure under intensive seismic load, especially into the efficiency of connecting elements, which had a special role in increasing seismic resistance and protection of the structure from collapse. Additionally, this experiment provided valuable data for verification and calibration of numerical models for strengthened stone masonry structures.     

Formulation of risk-targeted seismic action for the force-based seismic design of structures

A risk-targeted design spectral acceleration and the corresponding seismic design action for the force-based design of structures is introduced by means of two formulations. The first one called direct formulation utilizes the seismic hazard function at the site of the structure. Because the seismic action defined in the codes is often associated with a designated return period, an indirect formulation is also introduced. It incorporates a risk-targeted safety factor that can be used to define a risk-targeted reduction factor. It is shown that the proposed formulations give analogical results and provide an insight into the concept of the reduction of seismic forces for the force-based seismic design of structures if the objective is defined by a target collapse risk. The introduced closed-form solution for the risk-targeted reduction factor can be used to investigate how the target collapse risk, the seismic hazard parameters, the randomness of the seismic action, and the conventional parameters (ie, the overstrength factor and the deformation and energy dissipation capacity) affect the seismic design forces in the case of force-based design. However, collaborative research is needed in order to develop appropriate models of these parameters. In the second part of the paper, the proposed formulations are demonstrated by estimating the risk-targeted seismic design action for a six-storey reinforced concrete building. By verifying the collapse risk of the designed structure, it is demonstrated that the risk-targeted seismic action, in conjunction with a conventional force-based design, provided structure with acceptable performance when measured in terms of collapse risk.     

Glaciokarst landforms and processes of the southern Dinaric Alps

Glaciokarst is a landscape which combines karst features and hydrology as well as inherited glacial features. It is a result of glaciation upon a karst geomorphological system. The relationship between glaciers and karst is rather poorly known and inadequately recognized. This research focuses on three distinct karst areas along the Adriatic coast in the southern Dinaric Alps that were affected by the Quaternary glaciations. An insight into specific glaciokarst processes and surface features was provided through the study of the areas of the Lov?en, Orjen and Vele? Mountains. A glaciokarst geomorphology is in general well preserved due to the prevailing vertically oriented chemical denudation following de‐glaciation and almost the entire absence of other surface processes. Typical glacial erosional features are combined by a variety of depressions which are the result of a karstic drainage of sub‐glacial waters. The majority of glacial deposits occur as extensive lateral‐terminal moraine complexes, which are often dissected by smaller breach‐lobe moraines on the external side of the ridge. Those moraine complexes are likely to be a product of several glacial events, which is supported by complex depositional structures. According to the type of glacial depositional features, the glaciers in the study areas were likely to have characteristics of moraine‐dammed glaciers. Due to vertical drainage ice‐marginal fluvial processes were unable to evacuate sediment. Fluvial transport between glacial and pro‐glacial systems in karst areas is inefficient. Nevertheless, some sediment from the glacier margin is washed away by the pro‐glacial streams, filling the karst depressions and forming piedmont‐type poljes. Copyright © 2015 John Wiley & Sons, Ltd.     

The SHARE European Earthquake Catalogue (SHEEC) 1000–1899

In the frame of the European Commission project “Seismic Hazard Harmonization in Europe” (SHARE), aiming at harmonizing seismic hazard at a European scale, the compilation of a homogeneous, European parametric earthquake catalogue was planned. The goal was to be achieved by considering the most updated historical dataset and assessing homogenous magnitudes, with support from several institutions. This paper describes the SHARE European Earthquake Catalogue (SHEEC), which covers the time window 1000–1899. It strongly relies on the experience of the European Commission project “Network of Research Infrastructures for European Seismology” (NERIES), a module of which was dedicated to create the European “Archive of Historical Earthquake Data” (AHEAD) and to establish methodologies to homogenously derive earthquake parameters from macroseismic data. AHEAD has supplied the final earthquake list, obtained after sorting duplications out and eliminating many fake events; in addition, it supplied the most updated historical dataset. Macroseismic data points (MDPs) provided by AHEAD have been processed with updated, repeatable procedures, regionally calibrated against a set of recent, instrumental earthquakes, to obtain earthquake parameters. From the same data, a set of epicentral intensity-to-magnitude relations has been derived, with the aim of providing another set of homogeneous Mw estimates. Then, a strategy focussed on maximizing the homogeneity of the final epicentral location and Mw, has been adopted. Special care has been devoted also to supply location and Mw uncertainty. The paper focuses on the procedure adopted for the compilation of SHEEC and briefly comments on the achieved results.