A conceptual approach for assessing the impact of climate change on groundwater and related surface waters in cold regions (Finland)

A literature review of the impacts of anticipated climate change on unconfined aquifers is presented, along with a conceptual framework for evaluating the complex responses of surface and subsurface hydrology to climate variables in cold regions. The framework offers a way to conceptualize how changes in one component of the system may impact another by delineating the relationships among climate drivers, hydrological responses, and groundwater responses in a straight-forward manner. The model is elaborated in the context of shallow unconfined aquifers in the boreal environment of Finland. In cold conditions, climate change is expected to reduce snow cover and soil frost and increase winter floods. The annual surface water level maximum will occur earlier in spring, and water levels will decrease in summer due to higher evapotranspiration rates. The maximum recharge and groundwater level are expected to occur earlier in the year. Lower groundwater levels are expected in summer due to higher evapotranspiration rates. The flow regimes between shallow unconfined aquifers and surface water may change, affecting water quantity and quality in the surface and groundwater systems.     

Suspended Matter,Chl-a,CDOM, Grain Sizes,and Optical Properties in the Arctic Fjord-Type Estuary,Kangerlussuaq, West Greenland During Summer

Optical constituents as suspended particulate matter (SPM), chlorophyll (Chl-a), colored dissolved organic matter (CDOM), and grain sizes were obtained on a transect in the arctic fjord-type estuary Kangerlussuaq (66°) in August 2007 along with optical properties. These comprised diffuse attenuation coefficient of downwelling PAR (K _d(PAR)), upwelling PAR (K _u(PAR)), particle beam attenuation coefficient (c _p), and irradiance reflectance R(−0, PAR). PAR is white light between 400 and 700 nm. The estuary receives melt water from the Greenland Inland Ice and stations covered a transect from the very high turbid melt water outlet to clear marine waters. Results showed a strong spatial variation with high values as for suspended matter concentrations, CDOM, diffuse attenuation coefficient K _d(PAR), particle beam attenuation coefficients (c _p), and reflectance R(−0, PAR) at the melt water outlet. Values of optical constituents and properties decreased with distance from the melt water outlet to a more or less constant level in central and outer part of the estuary. There was a strong correlation between inorganic suspended matter (SPMI) and diffuse attenuation coefficient K _d(PAR) (r ² = 0.92) and also for particle beam attenuation coefficient (c _p; r ² = 0.93). The obtained SPMI specific attenuation—K _d^*(PAR) = 0.13 m² g⁻¹ SPMI—and the SPMI specific particle beam attenuation—c _p^* = 0.72 m² g⁻¹—coefficients were about two times higher than average literature values. Irradiance reflectance R(−0, PAR) was comparatively high (0.09−0.20) and showed a high (r ² = 0.80) correlation with K _u(PAR). Scattering dominated relative to absorption—b(PAR)/a(PAR) = 12.3. Results strongly indicated that the high values in the optical properties were related to the very fine particle sizes (mean = 2–6 μm) of the suspended sediment. Data and results are discussed and compared to similar studies from both temperate and tropical estuaries.     

Strontium-Isotope Studies Of Chloride-Contaminated Groundwater,Denmark

Saline groundwater has three principal origins in Denmark: 1) Seawater infiltration into nearcoastal aquifers, 2) saline formation water in aquifers of marine sedimentary origin, and 3) intrusion of brines from deep saline formation waters and evaporitic deposits in the subsurface. Strontium-isotope studies of chloride-contaminated groundwater from a Quaternary sandy aquifer at Stautrup Waterworks, Denmark, indicate that the groundwater is heavily influenced by saline formation water from underlying Oligocene marine mica clay. Thus, strontium isotopic hydrochemical criteria were successfully used to identify the sources of saline groundwater.

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RESUMEN: La salinidad en las aguas subterráneas de Dinamarca tiene tres orígenes principales: 1) Infiltración de agua marina en acuíferos costeros, 2) agua de formación salina en acuíferos de origen sedimentario marino, y 3) intrusión de salmueras procedentes de aguas salinas de formaciones profundas y de depósitos evaporíticos subterráneos. Estudios isotópicos del estronico en las aguas subterráneas contaminadas or cloruros en un acuífero arenoso Cuaternario en Stautrup Waterworks, Dinamarca, indican que el agua está fuertement influenciada por el agua de formación salina correspondiente a una capa inferior de micas arcillosas oligocénicas. Por tanto, los criterios hidroquímicos isotópicos se pudieron utilizar satisfactoriamente para identificar las fuentes de salinidad de las aguas subterráneas.

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RéSUMé: La salinité des aux souterraines du Danemark possède trois origines principales: 1) l'intrusion d'eau de mer dans les aquifères littoraux, 2) les eaux connées des sédiments marins constituant l'aquifère, 3) la remontée dans les aquifères superficiels de saumures provenant d'eaux connées de sédiments et de formations évaporitiques profonds. L'étude des isotopes du strontium d'eaux souterraines chargées en chlorures d'un aquifère sableux du Quaternaire du champ captant de Stautrup (Danemark) montre que le chimisme des eaux souterraines est fortement marqué par les eaux connées des argiles micacées marines sous-jacentes de l'Oligocène. Des critères hydrochimiques des isotopes du strontium ont par conséquent permis d'identifier les sources de la salinité d'eaux souterraines.

     

Progress in the Study of Climatic Extremes in Northern and Central Europe

A study of the long-term changes of various climatic extremes was made jointly by a number of European countries. It was found that the changes in maximum and minimum temperatures follow, in broad terms, the corresponding well-documented mean temperature changes. Minimum temperatures, however, have increased slightly more than maximum temperatures, although both have increased. As a result, the study confirms that the diurnal temperature range has mostly decreased during the present century in Northern and Central Europe. Frost has become less frequent. Two extreme-related precipitation characteristics, the annual maximum daily precipitation and the number of days with precipitation 10 mm, show no major trends or changes in their interannual variability. An analysis of return periods indicated that in the Nordic countries there were high frequencies of extraordinary 1-day rainfalls both in the 1930s and since the 1980s. There have been no long-term changes in the number of high wind speeds in the German Bight. Occurrences of thunderstorms and hails show a decreasing tendency in the Czech Republic during the last 50 years. Finally, using proxy data sources, a 500-year temperature and precipitation event graph for the Swiss Mittelland is presented. It shows large interdecadal variations as well as the exceptionality of the latest decade 1986-1995.     

The distribution of trace metals in the western North Atlantic off Nova Scotia

The distributions of Fe, Mn, Zn, Cu, Ni, Cd and Co have been determined in a section across the Scotian Shelf into the Atlantic Slope water. Significant differences in concentration exist for most of the trace metals between the four water masses in the section. Depletions of trace metal concentration in the highly productive Atlantic Slope water relative to the underlying Central Atlantic water are thought to be due to biological activity.The distributions of Fe and Mn are strongly related to the distribution of suspended particulate matter. The concentrations of Fe and Mn, extracted from the suspended matter on the Scotian Shelf, are considerably higher than those in the non-detrital fraction of the underlying sediments. This suggests that post-depositional changes cause the loss of both elements from the non-detrital fraction of the particles. Whereas Mn shows major nearshore increases in concentration related to continental runoff, nearshore Fe concentrations are largely controlled by particulate matter distribution. Continental runoff does not appear to have much influence upon the distributions of the other trace metals.     

Trace element partitioning and melt structure: An experimental study at 1 atm pressure

Diopside-melt and forsterite-melt rare earth (REE) and Ni partition coefficients have been determined as a function of bulk compositions of the melt. Available Raman spectroscopic data have been used to determine the structures of the melts coexisting with diopside and forsterite. The compositional dependence of the partition coefficients is then related to the structural changes of the melt.The melts in all experiments have a ratio of nonbridging oxygens to tetrahedral cations ($\text{NBO}\text{T}$) between 1 and 0. The quenched melts consist of structural units that have, on the average, 2 (chain), 1 (sheet) and 0 (three-dimensional network) nonbridging oxygens per tetrahedral cation. The proportions of these structural units in the melts, as well as the overall $\text{NBO}\text{T}$, change as a function of the bulk composition of the melt.It has been found that Ce, Sm, Tm and Ni crystal-liquid partition coefficients ($\text{K}{}^{\mathrm{crystal?liq}}{}_{\mathrm{i}}\text{=}\text{C}{}^{\mathrm{crystal}}{}_{\mathrm{i}}\text{C}{}^{\mathrm{liq}}{}_{\mathrm{i}}$) decrease linearly with increasing $\text{NBO}\text{T}$. The values of the individual REE crystal-liquid trace element partition coefficients have different functional relations to $\text{NBO}\text{T}$, so that the degree of light REE enrichment of the melts would depend on their $\text{NBO}\text{T}$.The solution mechanisms of minor oxides such as CO₂, H₂O, TiO₂, P₂O₅ and Fe₂O₃ in silicate melts are known. These data have been recast as changes of $\text{NBO}\text{T}$ of the melts with regard to the type of oxide and its concentration in the melt. From such data the dependence of crystal-liquid partition coefficients on concentration and type of minor oxide in melt solution has been calculated.     

Titan-aegirine from early Tertiary ash layers in northern Denmark

Microprobe analyses on a xenocrystic suite of salites, aegirine-augites, aegirines, titan-aegirines and acmites from a lower Tertiary ash layer in northern Denmark are presented. The sodic pyroxenes show an unusual titan-enrichment and up to 42 mol.% of the component $\text{NaTi}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}{}^{\mathrm{4+}}\text{M}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}{}^{\mathrm{2+}}\text{Si}{}_3\text{O}{}_6\text{(}\text{M = Fe}{}^{\mathrm{2+}}\text{,}\text{Mn or Mg}\text{)}$, is estimated. Optical absorption measurements show no evidence for Ti³⁺. The titan-aegirines were formed during late to post-magmatic crystallization in a system with a high Ti⁴⁺/Fe²⁺ ratio and were followed by acmite showing enrichment in jadeite. Comparison with experimentally investigated titan-aegirine indicates crystallization far below the Mn₂O₃Mn₃O₄f₀₂ buffer.     

Geochemical aspects of permeability controlled partial melting and fractional crystallization

Magma accumulation in the mantle requires that the mantle be permeable. Experimental investigations show that the permeability threshold first will be attained after a certain degree of partial melting. The influence of the permeability threshold on the composition of partial melts is evaluated using the fayalite-forsterite system as an example. In addition the variation in trace element concentrations are calculated for different distribution coefficients. Primary magmas formed by accumulation when a minimal degree of partial melting is required for permeability display a remarkably small variation in composition up to 30% partial melting. It is suggested from REE abundances that primary tholeiitic magmas have been generated by permeability controlled partial melting. The compositions of the primary magmas generated by permeability controlled partial melting will not differ much from the compositions obtained by batch melting, but the degrees of partial melting will differ for similar compositions.