Diurnal heterogeneity in silicic acid fluxes in shallow coastal sites: Causes and implications

In shallow coastal areas the amplitude and range of benthic silicic acid fluxes can have a significant influence on benthic–pelagic coupling and the functioning of the pelagic system. To explore the oscillation in fluxes over the diurnal cycle and in particular the influence of microphytobenthos (MPB), an experiment was carried out in a shallow subtidal site in the Bay of Brest (France). Benthic chambers were employed over a 48 h period to measure the variability in silicic acid and oxygen fluxes; MPB migration was investigated using a diving Pulse Amplitude Modulated (PAM) fluorometer and uptake rhythms of silicic acid by natural MPB populations were measured using the ³²Si isotope. It was discovered that silicic acid fluxes fluctuated greatly throughout the diurnal period resulting in an oscillation in the availability of this nutrient for phytoplankton communities. The uptake of silicic acid by the MPB was quantified for the first time and highlighted a 2-fold increase in the demand from night to afternoon periods. The combined silicic acid uptake and the concentration of cells at the sediment–water interface, forming a dense biofilm of MPB, were postulated to be the main processes reducing effluxes at midday. Our work highlighted the many processes which influence silicic acid effluxes in shallow coastal areas and the possible interaction between uptake and dissolution processes. The variations in benthic fluxes over the diurnal period were comparable to observations reported at the seasonal scale. Therefore, up-scaling hourly flux observations to daily and annual estimates should be undertaken with caution. Further we suggest that the main processes influencing flux oscillations over the diurnal period should be considered when planning sampling strategies and extrapolating to larger time scales.     

Towards a link between the energetic heterogeneities of the edge faces of smectites and their stability in the context of metallic corrosion

In the context of the potential confinement of high-level radioactive wastes (HLW) within the clay engineered barrier system (EBS) in deep geological formations, the evolution of the retention properties of smectite when interacting with Fe(0) needs to be assessed. If some potential natural analogues describing iron-clay reactivity are easily found, metallic iron-clay interactions are poorly described in studies regarding the Earth. Therefore, experimental investigations are needed. Several parameters influence Fe(0)-clay interactions, such as temperature, the interlayer composition of swelling clays, and the presence of octahedral Fe³⁺, etc. From a geometrical point of view, it is thought that clay destabilization is mainly controlled by phenomena starting at the edge faces of the particles. In the present work, the rates of the smectite-Fe(0) reaction at 80 °C were assessed by XRD, Mössbauer, and CEC analyses for three smectites. The investigations show marked differences in the degree of stability, which cannot be explained by the crystal-chemistry rules established in previous studies. Therefore, the Fe(0)-smectite interactions were studied in view of textural and energetic surface quantitative analyses. The studied smectites have equivalent nitrogen BET-specific surface areas, equivalent argon edge surface areas and slightly different basal surface areas. This similarity in particle shape indicates that the edge surface area cannot be accounted for when explaining the observed differences in reactivity. However, a correlation is obtained between smectite reactivity and the energetic heterogeneity of its edge faces. This is interpreted in terms of a multiplication of the number of sites on the edge faces, where the electron transfer between Fe(0) and the smectite structure can occur.     

Resolution issues in numerical models of oceanic and coastal circulation

The baroclinic and barotropic properties of ocean processes vary on many scales. These scales are determined by various factors such as the variations in coastline and bottom topography, the forcing meteorology, the latitudinal dependence of the Coriolis force, and the Rossby radius of deformation among others. In this paper we attempt to qualify and quantify scales of these processes, with particular attention to the horizontal resolution necessary to accurately reproduce physical processes in numerical ocean models. We also discuss approaches taken in nesting or down-scaling from global/basin-scale models to regional-scale or shelf-scale models. Finally we offer comments on how vertical resolution affects the representation of stratification in these numerical models.     

An incentive mechanism for reducing emissions from conversion of intact and non-intact forests

This paper presents a new accounting mechanism in the context of the UNFCCC issue on reducing emissions from deforestation in developing countries, including technical options for determining baselines of forest conversions. This proposal builds on the recent scientific achievements related to the estimation of tropical deforestation rates and to the assessment of ‘intact’ forest areas. The distinction between ‘intact’ and ‘non intact’ forests used here arises from experience with satellite-based deforestation measurements and allows accounting for carbon losses from forest degradation. The proposed accounting system would use forest area conversion rates as input data. An optimal technical solution to set baselines would be to use historical average figures during the time period from 1990 to 2005. The system introduces two different schemes to account for preserved carbon: one for countries with high forest conversion rates where the desired outcome would be a reduction in their rates, and another for countries with low rates. A ‘global’ baseline rate would be used to discriminate between these two country categories (high and low rates). For the hypothetical accounting period 2013–2017 and considering 72% of the total tropical forest domain for which data are available, the scenario of a 10% reduction of the high rates and of the preservation of low rates would result in approximately 1.6 billion tCO₂ of avoided emissions. The resulting benefits of this reduction would be shared between those high-rate countries which reduced deforestation and those low-rate countries which did not increase their deforestation over an agreed threshold (e.g., half of “global” baseline rate).     

The environmental setting of the harbor of the classical site of Oeniades on the Acheloos delta,Greece

Using a multidisciplinary approach, the Holocene geomorphological and palaeoenvironmental dynamics of the Acheloos delta were studied in order to understand how the ancient port of Oeniades, today situated 5 km from the sea, was connected to the sea in ancient times. A study of ancient maps, aerial photographs, and a SPOT image enabled us to reconstitute the successive changes in the flow of the Acheloos River and to conclude that, contrary to the traditional thesis of historians and archeologists, the harbor of Oeniades was completely independent from the river during Antiquity. Multidisciplinary studies (sedimentology, malacology, palynol‐ogy, and radiocarbon dating) were carried out on sediments from two boreholes (OEN1 and OEN2). Results show that the port of Oeniades communicated directly with an open bay that was created at the peak of the last post‐glacial transgression. The bay was gradually filled with sediments, allowing human occupation of the area to progress. © 2005 Wiley Periodicals, Inc.     

A Tortonian onset for the Algerian margin inversion: Evidence from low‐temperature thermochronology

In North Africa, the Algerian margin is made of basement blocks that drifted away from the European margin, namely the Kabylia, and docked to the African continental crust in the Early Miocene. This young margin is now inverted, as dated Miocene (17 Ma) granites outcrop alongshore, evidencing kilometre‐scale exhumation since their emplacement. Age of inversion is actually unknown, although Pliocene is often considered in the offshore domain. To decipher the exhumation history of the margin between 17 and 5 Ma, we performed a coupled apatite fission track (AFT) and (U–Th–Sm)/He (AHe) study in the Cap Bougaroun Miocene granite. AFT dates range between 7 ± 1 and 10 ± 1 Ma, and mean AHe dates between 8 ± 2 and 10 ± 1 Ma. These data evidence rapid and multi‐kilometre exhumation during Tortonian times. This event cannot be related to slab break‐off but instead to the onset of margin inversion that has since developed as an in‐sequence north‐verging deforming prism.     

Thermal Fronts Atlas of Canadian Coastal Waters

Oceanic fronts are often associated with enhanced biological activity. Depending on their generation mechanism, they are often linked to specific geographical areas. Here we use 25 years of high-resolution satellite sea surface temperature (SST) daily images to generate maps of SST fronts over Canadian coastal waters. Results show that fronts are ubiquitous features, but some fronts are more persistent than others. We confirmed the location of previously known major fronts, but some new persistent frontal areas were also detected as a result of the use of high-resolution (1.1?km) data and a methodology adapted to detect smaller-scale frontal features. Results also show that some of the frontal areas are associated with enhanced phytoplankton biomass or higher trophic level organisms (whales and birds) confirming the ecological importance of this physical process.     

The effect of slope aspect on the response of snowpack to climate warming in the Pyrenees

The aim of this study was to analyse the effect of slope aspect on the response of snowpack to climate warming in the Pyrenees. For this purpose, data available from five automatic weather stations were used to simulate the energy and mass balance of snowpack, assuming different magnitudes of an idealized climate warming (upward shifting of 1, 2 and 3 °C the temperature series). Snow energy and mass balance were simulated using the Cold Regions Hydrological Modelling platform (CRHM). CRHM was used to create a model that enabled correction of the all-wave incoming radiation fluxes from the observation sites for various slope aspects (N, NE, E, SE, S, SW,W,NW and flat areas), which enabled assessment of the differential impact of climate warming on snow processes on mountain slopes. The results showed that slope aspect was responsible for substantial variability in snow accumulation and the duration of the snowpack. Simulated variability markedly increased with warmer temperature conditions. Annual maximum snow accumulation (MSA) and annual snowpack duration (ASD) showed marked sensitivity to a warming of 1 °C. Thus, the sensitivity of the MSA in flat areas ranged from 11 to 17 % per degree C amongst the weather stations, and the ASD ranged from 11 to 20 days per degree C. There was a clear increase in the sensitivity of the snowpack to climate warming on those slopes that received intense solar radiation (S, SE and SW slopes) compared with those slopes where the incident radiation was more limited (N, NE and NW slopes). The sensitivity of the MSA and the ASD increased as the temperature increased, particularly on the most irradiated slopes. Large interannual variability was also observed. Thus, with more snow accumulation and longer duration the sensitivity of the snowpack to temperature decreased, especially on south-facing slopes.     

New insights on the trophic ecology of bathyal communities from the methane seep area off Concepción,Chile (~36° S)

Studies of the trophic structure in methane‐seep habitats provide insight into the ecological function of deep‐sea ecosystems. Methane seep biota on the Chilean margin likely represent a novel biogeographic province; however, little is known about the ecology of the seep fauna and particularly their trophic support. The present study, using natural abundance stable isotopes, reveals a complex trophic structure among heterotrophic consumers, with four trophic levels supported by a diversity of food sources at a methane seep area off Concepción, Chile (~36° S). Although methanotrophy, thiotrophy and phototrophy are all identified as carbon fixation mechanisms fueling the food web within this area, most of the analysed species (87.5%) incorporate carbon derived from photosynthesis and a smaller number (12%) use carbon derived from chemosynthesis. Methane‐derived carbon (MDC) incorporation was documented in 22 taxa, including sipunculids, gastropods, polychaetes and echinoderms. In addition, wide trophic niches were detected in suspension‐feeding and deposit‐feeding taxa, possibly associated with the use of organic matter in different stages of degradation (e.g. from fresh to refractory). Estimates of Bayesian standard ellipses area (SEA_B) reveal different isotopic niche breadth in the predator fishes, the Patagonian toothfish Dissostichus eleginoides and the combtooth dogfish Centroscyllium nigrum, suggesting generalist versus specialist feeding behaviors, respectively. Top predators in the ecosystem were the Patagonian toothfish D. eleginoides and the dusky cat shark, Bythaelurus canescens. The blue hake Antimora rostrata also provides a trophic link between the benthic and pelagic systems, with a diet based primarily on pelagic‐derived carrion. These findings can inform accurate ecosystem models, which are critical for effective management and conservation of methane seep and adjacent deep‐sea habitats in the Southeastern Pacific.