Water organisation at the solid–aqueous solution interfaceOrganisation de l'eau à l'interface solide–solution aqueuse

The aim of this review is to examine the present knowledge about water structure close to an interface or confined in porous spaces. First, the structure of liquid water is briefly described. Though its understanding remains incomplete, it appears that it is largely dominated by the hydrogen bond network and its dynamical evolution. The presence of any ‘foreign’ substance in water perturbs such a structure by changing at least locally the hydrogen bond network. For this reason, the presence of a solid interface significantly modifies the structure of the first adsorbed layers. Whatever the support, it is now clearly evidenced that structural perturbations are limited to distances lower than 10–15 Å from the interface. The nature, energetic heterogeneity and hydrophilicility/hydrophobicity of the solid surface influence the arrangement of water molecules. This surface organisation must definitely be considered when studying adsorption phenomena at the solid–aqueous solution interface. The relevance of such problems to geosciences is illustrated by a few situations in which water structure plays a prominent role. To cite this article: L.J. Michot et al., C. R. Geoscience 334 (2002) 611–631.     

Évolution temporelle et architecture interne d'un banc sableux estuarien : la Longe de Boyard (littoral atlantique,France)

The evolution and the internal architecture of an estuary type sand ridge has been studied with a set of bathymetric data recorded during the last two centuries and with a dense grid of recent very high resolution seismic profiles. Bathymetric data of the so-called, Longe de Boyard sand ridge, displays sand losts due to wave and tide erosion. Internal geometry, through seismic profile analysis, indicates two main phases of deposition recording both, a recent high energy environment and an older low energy one, respectively. Such an evolution is believed to record changes in sedimentation processes mainly related to the end of the Holocene transgression (8 000–5 000 yr BP). To cite this article: É. Chaumillon et al., C. R. Geoscience 334 (2002) 119–126.     

Earth dynamics and climate changes

The evolution of the Earth's climate over geological time is now relatively well known. Conversely, the causes and feedback mechanisms involved in these climatic changes are still not well determined. At geological timescales, two factors play a prevailing role: plate tectonics and the chemical composition of the atmosphere. Their climatic effects will be examined using palaeoclimatic indicators as well as results of climate models. I focus primarily on the influence of continental drift on warm and cold climatic episodes. The consequences of peculiar land sea distributions (amalgamation/dispersal of continental blocks) are discussed. Plate tectonics also drive sea level changes as well as mountain uplift. Marine transgressions during the Mid-Cretaceous favoured warmth within the interiors of continents, although their effect could be very different according to the season. Mountain uplift is also an important factor, which is able to alter climate at large spatial scales. Experiments relative to climatic sensitivity to the elevation of the Appalachians during the Late Permian are discussed. To affect the whole Earth, the chemical composition of the atmosphere appears to be a more efficient forcing factor. The carbon dioxide driven by the long-term carbon cycle has influenced the global climate. Geochemical modelling simulates more or less accurately the long-term evolution of pCO₂, which corresponds roughly to the icehouse/greenhouse climatic oscillations. However, the uncertainties on pCO₂ are still important because different parameters involved in the long-term carbon cycle (degassing rate, chemical weathering of silicates, burial of organic matter) are not well constrained throughout the past. The chemical composition of the atmosphere is also altered by the emissions of modern volcanic eruptions leading to weak global cooling. The influence of large flood basalt provinces on climate is not yet known well enough; this volcanism may have released huge amounts of SO₂ as well as CO₂. At last, the chemical composition of the atmosphere may have been altered by the release of methane in response to the dissociation of gas hydrates. This scenario has been proposed to explain the abrupt warming during the Late Palaeocene.     

Néotectonique affectant les dépôts marins tyrrhéniens du littoral sud-est tunisien : implications pour les variations du niveau marin

Pleistocene marine deposits of so-called Tyrrhenian age in southeastern Tunisia include two lithostratigraphic units of Last Interglacial (marine isotopic substage 5e). The lower unit culminates at about +3 m above the sea level; the upper unit with Strombus bubonius culminates at +5 m. Brittle deformations affected the upper unit. The analysis of fault-slip data sets reveals a post-Tyrrhenian N020°E trending compression, consistent with joint patterns. This event induced limited vertical movements, showing that at the northeastern edge of the Saharan Platform, the coastal area of the southern Tunisia remained relatively stable since at least the Last Interglacial.     

Milieux coralliens du Dogger près de Betioky (Madagascar) : la fin d'une exceptionCorallian meadows in the Dogger near Betioky (Madagascar): the end of an exception

Corallian outcrops of the Dogger in the Betioky area (Madagascar) have been previously interpreted as barrier reefs or atolls involved in a large carbonate platform. This statement appeared exceptional for these times. A field study demonstrates that, in fact, they are only sparse solitary or colonial corals, whose growth occurred with some difficulty. They developed in meadows strongly marked by terrigenous inputs, in a subsiding context, and during brief episodes favourable to the genesis of ooids. To cite this article: B. Lathuilière et al., C. R. Geoscience 334 (2002) 1169–1176.     

Multi-technique monitoring of ocean tide loading in northern France

We have organised afield study of ocean tide loading in the northwestern part of France, where tidal amplitudes are known to be among the highest in the world. GPS and gravimetric techniques have already proved their capability to measure such weak and high-frequency signals. In this study, these classical observations are complemented with less usual techniques, such as tiltmeter and Satellite Laser Ranging (SLR) measurements. We present here the preliminary results for a common period of observations spanning from 12–19 May 2004. Additional measurements from the French Transportable Laser Ranging Station (FTLRS) were available during September and October 2004. Observation residuals are computed as the difference between the observed and the predicted time signals. We obtain small RMS residuals for GPS measurements (2.5/3.1/4.5 mm for the eastward, northward and upward components), for absolute and relative gravimetry (9 nm/s² and 13 nm/s²) and for tiltmeters (0.05 μrad for EW component). We also fit the amplitude of the main M2 tidal constituent to FTLRS observations and we find a value of 3.731 cm, which is comparable to the theoretical value.     

Tracking past mining activity using trace metals,lead isotopes and compositional data analysis of a sediment core from Longemer Lake,Vosges Mountains,France

A 157-cm-long sediment core from Longemer Lake in the Vosges Mountains of France spans the past two millennia and was analyzed for trace metal content and lead isotope composition. Trace metal accumulation rates highlight three main input phases: Roman Times (cal. 100 BC–AD 400), the Middle Ages (cal. AD 1000–1500), and the twentieth century. Atmospheric contamination displays a pattern that is similar to that seen in peat bogs from the region, at least until the eighteenth century. Thereafter, the lake sediment record is more precise than peat records. Some regional mining activity, such as that in archaeologically identified eighteenth-century mining districts, was detected from the lead isotope composition of sediment samples. Compositional data analysis, using six trace metals (silver, arsenic, cadmium, copper, lead and zinc), enabled us to distinguish between background conditions, periods of mining, and of other anthropogenic trace metal emissions, such as the recent use of leaded gasoline.     

High-resolution modelling of a coastal harbour in the presence of strong tides and significant river runoff

Ocean Dynamics - In the context of Canada’s Ocean Protection Plan (OPP), improved coastal and near-shore modelling is needed to enhance marine safety and emergency response capacity in the...     

Reconstruction of the Sunspot Number Source Database and the 1947 Zurich Discontinuity

Solar Physics - The final version (V.19) of the total solar irradiance data from the SOlar Radiation and Climate Experiment (SORCE) Total Irradiance Monitor has been released. This version includes...