Thermally induced wind patterns in the Sahelian city of Ouagadougou, Burkina Faso

The urban surface wind field in the dry-tropical city of Ouagadougou, Burkina Faso was studied based on data collected at one urban and one suburban station during early dry season. An intra-urban thermal breeze, creating almost opposite wind directions at the two sites, was found during nights with high atmospheric stability. The high atmospheric stability suggests a decoupling of the surface wind layer from the layer above, allowing the wind system to develop due to the strong intra-urban temperature gradients in the city. Frequent temporary breakdowns of the thermal wind system were noticed, generally generating a turn in wind direction towards that of the regional wind, thus indicating a re-coupling with a stronger wind flow in the wind layer above.     

Chemical fluid transport (CFT): A window into Earth and its development

Gas phase transport according to chemical fluid transport (CFT) in Earth's crust as well as in the solar nebula is characterized by very high transport efficiency. Systematic investigations of mobilization, transport and deposition of gaseous MeX (Me = metal, X = F or Cl) compounds by solid gas equilibrium reactions are suitable to explain numerous extensive accumulations of minerals and ores. More than 40 of the considered chemical elements form volatile MeX compounds. Some elements tend to form MeF compounds, whereas others are more likely to form MeCl compounds. Silicon reacts with HF to form SiF₄ and replaces other elements to form MeF compounds at low temperature ranges. Accumulations caused by SiF₄ transport explain the formation of numerous quartz varieties and silicate minerals in Earth's crust. Iron most likely reacts with HCl to form FeCl₂ as well as FeCl₃ and explain the formation of iron or iron compounds. Thermodynamically directed transport from cool to hot areas in connection with cyclic processes increases the transport efficiency of MeX-species. Such species are SiF₄, Al₂F₆, POF₃, Cu₃Cl₃, SnCl₄, BF₃, GeF₄, GeCl₄, Ga₂Cl₆, ZrF₄, NbF₅ and TiF₄. The transport gases SiF₄ and POF₃ often react with environmental compounds forming pneumatolytic and metasomatical mineral accumulations. CFT is the “motor” of pneumatolytic and metasomatical processes.     

Surface changes on crystalline stones due to salt crystallisation

This study assesses the changes on the surface of crystalline stones due to salt crystallisation. Efflorescence was forced to grow on the surface of granite and marbles through 60 cycles of salt crystallisation with sodium sulphate. Changes on surface roughness, gloss and colour were measured every 15 cycles and the specimens were examined with naked eye and SEM. Sodium sulphate produces damage which depends on mineral composition. Results show that granites experience a mechanical decay with an increase in roughness. Peaks of mica can be observed on the surface and cracks widen and grow deeper. Colour and gloss do not show any significant change, although gloss decreases with an increase in surface roughness. In marbles, the decay is mainly chemical. Surface roughness increases due to dissolution of the calcite. White marbles exhibit yellowing. Gloss decreases during the first cycles—as grain boundaries become more visible—but tends to regain almost its initial value as the number of cycles increases. In this case, gloss does not show any relation with surface roughness.     

Performance of buildings with masonry infill walls during the 2011 Lorca earthquake

On Wednesday 11th May 2011 at 6:47 pm (local time) a magnitude 5.1 Mw earthquake occurred 6 km northeast of Lorca with a depth of around 5 km. As a consequence of the shallow depth and the small epicentral distance, important damage was produced in several masonry constructions and even led to the collapse of one of them. Pieces of the facades of several buildings fell down onto the sidewalk, being one of the reasons for the killing of a total of 9 people. The objective of this paper is to describe and analyze the failure patterns observed in reinforced concrete frame buildings with masonry infill walls ranging from 3 to 8 floors in height. Structural as well as non-structural masonry walls suffered important damage that led to redistributions of forces causing in some cases the failure of columns. The importance of the interaction between the structural frames and the infill panels is analyzed by means of non-linear Finite Element Models. The resulting load levels are compared with the member capacities and the changes of the mechanical properties during the seismic event are described and discussed. In the light of the results obtained the observed failure patterns are explained. Some comments are stated concerning the adequacy of the numerical models that are usually used during the design phase for the seismic analysis.     

Influence of high-pressure processing on the structure and memory effect of synthetic layered double hydroxides

We investigate the structural evolution of synthetic layered double hydroxides (LDH) samples, processed at room temperature and high-pressure (up to 7.7 GPa) in a toroidal chamber with two pressure-transmitting media, lead and graphite, using X-ray diffraction, thermogravimetry and N₂-adsorption isotherms techniques. The X-ray patterns of compacted samples show a decrease in the peak intensities. For both pressure-transmitting media, our samples revealed a reduction of the basal d-spacing for the (003) plane when processed at 7.7 GPa. The expected high-pressure-induced amorphization was not observed. Surprisingly, we find high-pressure processing to have a strong influence on the memory effect of the LDH, due essentially to the reduction of the surface area and pore closing. Even when immersed in water, our samples did not recover the LDH structure, when either calcined at 450°C and compacted at 7.7 GPa, or calcined at 700°C and immediately compacted at 2.5 and 7.7 GPa.     

Hilda asteroids among Jupiter family comets

Hilda asteroids and comets are similar from the compositional point of view. The D-taxonomic class prevailing among Hildas has all the characteristics found in cometary spectra. Jupiter Family Comets (JFCs) coming from the trans-neptunian region are under the gravitational control of Jupiter, making them a dynamically unstable population with a mean dynamical lifetime of 10⁴ to ¹⁰⁵ years. In contrast, Hilda asteroids residing in the 3:2 mean motion resonance with Jupiter are a very stable population. But once they escape from the resonance, they are dynamically controlled by Jupiter, and in this sense their behavior resembles that of JFC. We performed a numerical simulation to analyze the dynamical evolution that Hildas follow after escaping from the resonance, and their contribution to the JFC population. We found that 8% of the particles leaving the resonance end up impacting Jupiter. 98.7% of the escaped Hildas live at least 1000 years as a JFC, with a mean lifetime of 1.4×¹⁰⁶ years. In particular, escaped Hildas stay mainly in the region of perihelion distances greater than 2.5 AU. On the other hand, the number of escaped Hildas reaching the inner Solar System (q<2.5 AU) is negligible. So, there are almost no Hilda asteroids among the NEO population. We also analyzed the possibility that the Shoemaker-Levy 9 were an escaped Hilda asteroid. In this case, it would be possible to give stronger constraints to its pre-capture orbital elements.