淮河流域地下水资源调查评价与利用研究

在查明淮河流域地下水各含水岩组的水文地质特征、水资源总量、开采现状及存在的环境地质问题的基础上,对该区域地下水资源开发利用潜力进行了详细的评价,并提出了相应的治理措施及促进地下水资源可持续利用的对策,为该区未来更长时期水资源的合理配置和以水资源的可持续利用支撑经济社会的可持续发展提供科学依据。     

吉林延边地区浅成热液金(铜)矿床的~(40)Ar/~(39)Ar激光探针测年与成矿时代讨论

延边地区是中国东北部陆缘浅成热液金铜矿床发育的地区之一,广泛发育着浅成热液金矿床、中温热液金(铜)矿床和中深成中高温热液富金铜矿床(类斑岩型);富金铜矿床的成矿时代发生在105～102 Ma,为了进一步确定浅成热液金矿床与中深成中高温热液富金铜矿床的成矿动力学背景,采用流体包裹体的~(40)Ar/~(39)Ar激光探针定年法,对该区典型浅成热液金矿床进行了精细的年代学测定,获得刺猬沟金矿床、五星山金矿床和杜荒岭金矿床的脉石矿物石英流体包裹体的~(40)Ar/~(39)Ar等时线年龄分别为(141±7)Ma、(123±7)Ma和(107±6)Ma,其中刺猬沟金矿床((141±7)Ma)和五星山金矿床((123±7)Ma)的脉石矿物石英流体包裹体含有过剩放射性成因~(40)Ar,而杜荒岭金矿床((107±6)Ma)的脉石矿物石英流体包裹体几乎不含或含极少量过剩放射性成因~(40)Ar。结合最新获得的相关地质体的精细年代学成果,认定该区浅成热液金矿床成矿作用均发生在早白垩世晚期,或发生在早白垩世晚期火山喷发、浅成岩浆就位之后,其形成环境与富金铜矿床一致,为古太平洋板块向亚洲大陆正北向俯冲转入Izanagi-Farallon板块西向俯冲的构造转换期。     

Cracking mechanisms during galena mineralization in a sandstone-hosted lead–zinc ore deposit: case study of the Jinding giant sulfide deposit, Yunnan, SW China

There are two types of lead–zinc ore bodies, i.e., sandstone-hosted ores (SHO) and limestone-hosted ores (LHO), in the Jinding giant sulfide deposit, Yunnan, SW China. Structural analysis suggests that thrust faults and dome structures are the major structural elements controlling lead–zinc mineralization. The two types of ore bodies are preserved in two thrust sheets in a three-layered structural profile in the framework of the Jinding dome structure. The SHO forms the cap of the dome and LHO bodies are concentrated beneath the SHO cap in the central part of the dome. Quartz, feldspar and calcite, and sphalerite, pyrite, and galena are the dominant mineral components in the sandstone-hosted lead–zinc ores. Quartz and feldspar occur as detrital clasts and are cemented by diagenetic calcite and epigenetic sulfides. The sulfide paragenetic sequence during SHO mineralization is from early pyrite to galena and late sphalerite. Galena occurs mostly in two types of cracks, i.e., crescent-style grain boundary cracks along quartz–pyrite, or rarely along pyrite–pyrite boundaries, and intragranular radial cracks in early pyrite grains surrounding quartz clasts. The radial cracks are more or less perpendicular to the quartz–pyrite grain boundaries and do not show any overall (whole rock) orientation pattern. Their distribution, morphological characteristics, and geometrical relationships with quartz and pyrite grains suggest the predominant role of grain-scale cracking. Thermal expansion cracking is one of the most important mechanisms for the generation of open spaces during galena mineralization. Cracking due to heating or cooling by infiltrating fluids resulted from upwelling fluid phases through fluid passes connecting the SHO and LHO bodies, provided significant spaces for crystallization of galena. The differences in coefficients of thermal expansion between pyrite and quartz led to a difference in volume changes between quartz grains and pyrite grains surrounding them and contributed to cracking of the pyrite grains when temperature changed. Combined thermal expansion and elastic mismatch due to heating and subsequent cooling resulted in the radial and crescent cracking in the pyrite grains and along the quartz–pyrite grain boundaries.     

Palynological records of Holocene monsoon change from the Gulf of Tonkin (Beibuwan), northwestern South China Sea

Palynological records in cores C4 and B106 from the Gulf of Tonkin reveal signals of paleo-monsoon and paleoenvironmental change during the late Pleistocene and Holocene. Before ∼ 13.4 cal kyr BP, the Gulf of Tonkin was exposed to the atmosphere and covered by grassland. Starting at ∼ 11.7 cal kyr BP, the Gulf of Tonkin was inundated by brackish water, indicated by the appearance of the brackish algae Cleistosphaeridium, Sentusidinium and Spiniferites, a decrease of herb content, and an increase of Pinus. After Hainan Island was completely separated from the Leizhou Peninsula by Qiongzhou Strait at ∼ 8.5 cal kyr BP, a continuous marine sedimentary environment was found. The current patterns were similar to those of the present, with a general trend of current homogenization reflected by gradually decreasing quantities of Quercus pollen and a narrowing gap between the palynological concentrations of the southern and northern parts of the region. The data suggest that three short periods of strengthened winter monsoons and currents were centered at ∼ 6.0 cal kyr BP, ∼ 2.7 cal kyr BP and ∼ 0.2 cal kyr BP and that two short periods of strengthened summer monsoons and currents were centered at ∼ 7.5 cal kyr BP and ∼ 3.4 cal kyr BP.     

Zircon U–Pb ages and tectonic implications of Paleozoic plutons in northern West Junggar,North Xinjiang,China

North Xinjiang, Northwest China, is made up of several Paleozoic orogens. From north to south these are the Chinese Altai, Junggar, and Tian Shan. It is characterized by widespread development of Late Carboniferous–Permian granitoids, which are commonly accepted as the products of post-collisional magmatism. Except for the Chinese Altai, East Junggar, and Tian Shan, little is known about the Devonian and older granitoids in the West Junggar, leading to an incomplete understanding of its Paleozoic tectonic history. New SHRIMP and LA-ICP-MS zircon U–Pb ages were determined for seventeen plutons in northern West Junggar and these ages confirm the presence of Late Silurian–Early Devonian plutons in the West Junggar. New age data, combined with those available from the literature, help us distinguish three groups of plutons in northern West Junggar. The first is represented by Late Silurian–Early Devonian (ca. 422 to 405 Ma) plutons in the EW-striking Xiemisitai and Saier Mountains, including A-type granite with aegirine–augite and arfvedsonite, and associated diorite, K-feldspar granite, and subvolcanic rocks. The second is composed of the Early Carboniferous (ca. 346 to 321 Ma) granodiorite, diorite, and monzonitic and K-feldspar granites, which mainly occur in the EW-extending Tarbgatay and Saur (also spelled as Sawuer in Chinese) Mountains. The third is mainly characterized by the latest Late Carboniferous–Middle Permian (ca. 304 to 263 Ma) granitoids in the Wuerkashier, Tarbgatay, and Saur Mountains.As a whole, the three epochs of plutons in northern West Junggar have different implications for tectonic evolution. The volcano-sedimentary strata in the Xiemisitai and Saier Mountains may not be Middle and Late Devonian as suggested previously because they are crosscut by the Late Silurian–Early Devonian plutons. Therefore, they are probably the eastern extension of the Early Paleozoic Boshchekul–Chingiz volcanic arc of East Kazakhstan in China. It is uncertain at present if these plutons might have been generated in either a subduction or post-collisional setting. The early Carboniferous plutons in the Tarbgatay and Saur Mountains may be part of the Late Paleozoic Zharma–Saur volcanic arc of the Kazakhstan block. They occur along the active margin of the Kazakhstan block, and their generation may be related to southward subduction of the Irtysh–Zaysan Ocean between Kazakhstan in the south and Altai in the north. The latest Late Carboniferous–Middle Permian plutons occur in the Zharma–Saur volcanic arc, Hebukesaier Depression, and the West Junggar accretionary complexes and significantly postdate the closure of the Irtysh–Zaysan Ocean in the Late Carboniferous because they are concurrent with the stitching plutons crosscutting the Irtysh–Zaysan suture zone. Hence the latest Late Carboniferous–Middle Permian plutons were generated in a post-collisional setting. The oldest stitching plutons in the Irtysh–Zaysan suture zone are coeval with those in northern West Junggar, together they place an upper age bound for the final amalgamation of the Altai and Kazakhstan blocks to be earlier than 307 Ma (before the Kaslmovian stage, Late Carboniferous). This is nearly coincident with widespread post-collisional granitoid plutons in North Xinjiang.     

超微量钐同位素的热表面电离质谱分析

采用双带测量方式,法拉第杯和离子计数器同时接收与跳峰接收相结合,建立了超微量钐同位素的热表面电离质谱的测量方法。优化了制样程序和质谱测量程序,研究了蒸发带电流对离子流强度的影响,考察了从纳克至微克不同样品用量的测量效果及其中Nd、Eu干扰核素的情况。对4 ng~2μg的天然丰度钐样品进行了同位素比值分析,相对标准偏差均小于1.1%。     

Investigation of the sulfur speciation during chalcopyrite leaching by moderate thermophile Sulfobacillus thermosulfidooxidans

The surface sulfur speciation of chalcopyrite leached by moderately thermophilic Sulfobacillus thermosulfidooxidans was investigated by employing scanning electron microscopy (SEM), X-ray diffraction (XRD) and sulfur K-edge X-ray absorption near edge structure spectroscopy (XANES), accompanying with the leaching behavior elucidation. Leaching experiment showed that there was an optimum range of the redox potential for chalcopyrite dissolution. Leaching products were found accumulating during the leaching process, which might be jarosite according to the XRD analysis. The sulfur K-edge spectra indicated that chalcocite might be the intermediate sulfur compound under a critical redox potential, which might explain the existence of optimum range of the redox potential and provide an evidence for the two-step leaching model of chalcopyrite at low Eh. In addition, the results of sulfur K-edge spectra showed jarosite would accumulate on mineral surface, which might be the main component of the passivation layer.     

Analysis of geocell-reinforced mattress with consideration of horizontal–vertical coupling

Geocell reinforcement has been increasingly applied to road embankment engineering. Deformation calculation is one of the major concerns during the design process. In this paper, the power-series method was employed to investigate the performance of a geocell-reinforced mattress under symmetric loads. The geocell-reinforced mattress was idealized as a beam on a Winkler foundation. In the analysis, the soil–foundation beam interface resistance, related to the horizontal deformation coupling with the vertical deformation, was considered. Semi-analytic solutions were developed to assess the deformations and internal forces of the foundation beam and verified against an existing finite element method [9]. The results of the proposed method were close to the results from the finite element method. Moreover, the effects of various factors, such as height of embankment, horizontal and vertical foundation coefficients, composite elastic modulus and height of geocell-reinforced mattress, on the foundation beam settlement and the tension force within the beam are discussed. It was found that the interface resistance related to the horizontal deformation of the beam has a reduction effect on the embankment settlement, and it is beneficial to reduce the embankment settlement by increasing the beam rigidity and strengthening the subgrade soil body.     

关于南天山碰撞造山时代的讨论

南天山是天山山脉的一支,是中亚型造山带的典型代表,它经历了复杂的增生—碰撞过程。关于古南天山洋最终闭合—碰撞造山(碰撞事件)发生的时间一直存在不同的认识,争论由来已久。综合分析南天山造山带的构造、地层、古生物、岩石、地球化学和同位素年代学等方面的资料,特别是对放射虫、蛇绿岩、蓝片岩、火山弧及前陆盆地沉积等地质事实的研究,我们认为,南天山碰撞造山作用起始于二叠纪末—三叠纪初。     

塔中古溶洞见证晚奥陶世抬升幅度

塔中隆起区上奥陶统良里塔格组灰岩与桑塔木组砂—粉砂岩之间为不整合接触,昭示着这两个组沉积期之间存在一次历时约百万年的区域性构造抬升事件。中古31井良里塔格组三段的4 125.6～4 133.9 m井段为垮塌型溶洞沉积,洞顶距良里塔格组二段顶部190.6 m,溶洞中角砾状充填物主要来自良里塔格组洞壁本身的礁相灰岩,且见数厘米厚的暗河流水沉积纹层,未发现源于其它时代的颗粒混杂其间。这一事实指证了溶洞的形成和充填时代均为良里塔格组沉积之后、桑塔木组覆盖之前的晚奥陶世凯迪中期。具溶蚀力的淡水潜流带的深度一般不低于周围的海平面,由此可推断出该井区这次抬升出海平面之上的高度,即使忽略良里塔格组顶部可能经地表剥蚀的良里塔格组一段,抬升出水面部分至少也应该有190 m,藉生态地层学恢复洞壁礁灰岩沉积时的海水深度约为30 m±,因此总抬升幅度至少能达到220 m。