矿物流体包裹体中的羧酸

矿物流体包裹体中的羧酸曾贻善刘家齐（北京大学地质系，北京１００８７１）（地矿部宜昌地质矿产研究所，宜昌４４３００３）关键词矿物包裹体浸取液羧酸离子色谱分析分子中含有羧基官能团（—ＣＯＯＨ）的物质称为羧酸。Ｆｅｉｎ［１］和Ｓｈｏｃｋ［２］曾概述羧酸在自...     

Discriminating characters of ore-forming intrusions in the super-large Chalukou porphyry Mo deposit,NE China

The Chalukou porphyry Mo deposit, located in the Great Hinggan Range, is the largest Mo deposit in northeast China, although the age and genesis of the associated magmatic intrusions remain debated.Here we report zircon U-Pb ages and trace elements, whole rock geochemistry and Sre Nd isotope data with a view to understand the relationship between the magmatism and molybdenum mineralization.Zircon U-Pb analysis yield an age of 475 Ma for rhyolite in the older strata, 168 Ma for the premineralization monzogranite, and 154 Ma for the syn-mineralization granite porphyry. The granite porphyry and quartz porphyry are considered as the ore-forming intrusions. These rocks are peraluminous, alkali-calcic, and belong to high-K to shoshonitic series with a strong depletion of Eu. They also display characteristics of I-type granites. The rocks exhibit wide variations of(87 Sr/86 Sr)iin the range of 0.705426 -0.707363, and ε_(Nd)(t) of -3.7 to 0.93. Zircon REE distribution patterns show characteristics between crust and the mantle, implying magma genesis through crust-mantle interaction. The Fe_2O_3/FeO values(average 1) for the whole rock and EuN/Eu*Nvalues(average 0.45), Ce~(4+)/Ce~(3+) values(average 301)for zircon grains from the granite porphyry are higher than those from other lithologies. These features suggest that the ore-forming intrusions(syn-mineralization porphyry) had higher oxygen fugacity conditions than those of the pre-mineralization and post-mineralization rocks. The Chalukou Mo deposit formed in relation to the southward subduction of the Mongol-Okhotsk Ocean. Our study suggests that the subduction-related setting, crust-mantle interaction, and the large-scale magmatic intrusion were favorable factors to generate the super-large Mo deposits in this area.     

基于边坡渐进破坏特征对传统极限平衡法几点假设的合理分析

边坡的渐进破坏特征一直以来是边坡计算仿真中的一个难点。实际边坡的破坏很少是一个整体达到极限状态,突然滑动的过程,往往是逐步发展由局部破坏到最终整体失稳,即临界状态小扰动导致的链式多米洛骨牌式失稳。利用颗粒流软件,设计了0.1 m粒径高10 m土坡的数值模型,粒间黏聚力为36 kPa,摩擦系数为0.36。初始模型在重力作用下不会发生破坏,通过单独折减粒间黏聚力到18 kPa使得边坡破坏,监测竖向颗粒组group的变化获取每20 000个时间步的边坡破坏形态,实现200 000个时间步内边坡的渐进破坏过程。边坡总是从局部开始破坏,坡体物质的运移造成次一级破坏,形成最终的近似弧形的滑动面,说明滑体不是整体下滑,不是刚体,不是整体达到极限状态;坡体内应力的变化也不是单调的,有涨有落,均区别于当前极限平衡法中有限条块的刚体假设;滑动面上同时达到极限状态假设,问题本身是静不定的,通过给出条间力的传递方式使之静定可解;整体分析不能考虑破坏的局部化和渐进特征。这说明边坡计算方法的未来在于能反映动力问题和材料破坏特征的离散元方法。     

Decrepitation Thermometry and Compositions of Fluid Inclusions of the Damoqujia Gold Deposit,Jiaodong Gold Province,China:Implications for Metallogeny and Exploration

The recently discovered Damoqujia (大磨曲家) gold deposit is a large shear zone-hosted gold deposit of disseminated sulphides located in the north of the Zhaoping (招平) fault zone, Jiaodong (胶东) gold province, China. In order to distinguish the temperature range of cluster inclusions from different mineralization stages and measure their compositions, 16 fluid inclusions and 5 isotopic geochemistry samples were collected for this study. Corresponding to different mineralization stages, the multirange peaks of quartz decrepitation temperature (250-270, 310-360 and 380-430℃(2) indicate that the activity of ore-forming fluids is characterized by multistage. The ore-forming fluids were predominantly of high-temperature fluid system (HTFS) by CO2-rich, and SO2-4-K type magmatic fluid during the early stage of mineralization and were subsequently affected by low-temperature fluid system (LTFS) of CH4-rich, and Cl--Na /Ca2 type meteoric fluid during the late stage of mineralization. Gold is transferred by Au-HS- complex in the HTFS, and Au-Cl- complex can be more important in the LTFS. The transition of fluids from deeper to shallow environments results in mixing between the HTFS and LTFS, which might be one of the most key reasons for gold precipitation and large-scale mineralization. The ore-forming fluids are characterized by high-temperature, strong-activity, and superimposed mineralization, so that there is a great probability of forming large and rich ore deposit in the Damoqujia gold deposit. The main bodies are preserved and extend toward deeper parts, thereby suggesting a great potential in future.     

大别山碧溪岭地区超高压变质岩构造分析

大比例尺 (1∶10 0 0 0 )构造制图及构造分析表明 ,碧溪岭地区超高压变质岩石含有丰富的构造演化历史记录。同碰撞或挤压组构只保留于榴辉岩及其它超高压变质岩透镜体内部 ,表现为高角度网络状超高压剪切带与弱应变透镜体域规律组合格式。前者由面理或糜棱岩化榴辉岩组成 ,后者由块状榴辉岩及石榴橄榄岩组成。碰撞期后伸展构造表现为区域性的假单斜状 ,内部呈低缓角度的网络状强应变带及所环绕的透镜状弱应变域组合格式 ,强应变带的岩石为由榴辉岩退变成的角闪岩相高压片麻岩及部分熔融形成的含榴花岗岩 ,透镜状弱应变域的岩石为弱角闪相改造的榴辉岩及石榴橄榄岩。不同尺度上同碰撞或挤压组构及碰撞期后伸展组构所显示的这种残斑基质流变学结构样式 ,虽然与先期原岩成分、结构、流变学的不均一性有关 ,但主要是多期递进应变分解作用的结果 ,支持榴辉岩“原地”成因模式。依据构造学证据和可利用的岩石学及同位素年代学资料 ,分析了超高压变质岩石的形成及折返过程 ,指出碧溪岭地区超高压变质岩石是在 2 45～ 2 10Ma形成的 ,碰撞期后伸展作用主要发生在 2 0 0～ 170Ma。在超高压变质岩石向地壳表层折返过程中 ,张扭作用可能有重要功能 ,不支持碧溪岭地区遭受过多期超高压变质作用的推论。     

乳化植物油强化土著微生物修复中高浓度Cr(Ⅵ)污染地下水

以天然细砂为微生物来源,模拟研究了乳化植物油强化原位生物修复中高浓度Cr（Ⅵ）污染地下水的可行性,考察了修复效果及修复过程中地下水质变化及产物的稳定性。结果表明,反应77 d后,Cr（Ⅵ）质量浓度分别从20.0、30.0、50.0、80.0、110.0 mg/L降低到0.0、5.8、19.0、43.6、65.8 mg/L,去除率分别为100.0%、80.7%、61.9%、45.5%、40.2%。反应后介质中Cr形态分析表明,其主要以能在自然条件下稳定存在的铁锰结合态和有机结合态形式存在。此外,随反应进行,实验体系逐渐呈弱酸性环境,pH为5.80~6.70。当Cr被完全还原后,体系会发生异化铁还原,Fe（Ⅱ）质量浓度逐渐升高,最高可达117.0 mg/L,最终形成二价铁矿物。综上所述,天然细砂介质中的土著微生物能够利用乳化植物油强化并还原地下水中的中、高浓度Cr（Ⅵ）,且产物能够在自然状态下稳定存在,修复过程对地下环境的影响较小。     

塔西南坳陷甫沙构造带正反转构造及其石油地质意义

塔西南坳陷甫沙构造带褶皱冲断强烈,古近系膏泥岩下层构造变形复杂,具有正反转构造变形特征。侏罗纪—白垩纪区域伸展环境发育大量正断层,后期在喜马拉雅运动中受挤压反转。南部发育高角度基底卷入正反转断层,中部发育叠瓦式逆冲断层,北部边缘变形微弱。相应地将甫沙构造带划分为反转断隆背斜带、楔状叠瓦构造带和逆冲前缘构造带;反转程度南强北弱、西强东弱。对区域构造变形环境的分析表明,西昆仑山隆升引发水平挤压叠加垂直向上的剪切作用,使先存高角度正断层容易被迁就利用进而发生正反转。对正反转相关构造圈闭评价认为:反转断隆背斜带发育的圈闭规模大,幅度低,埋藏浅,落实程度高,但上覆膏泥岩层薄,被断层破坏强烈,油气散失严重;楔状叠瓦构造带发育的圈闭规模小,幅度大,埋藏深,落实程度低,上覆膏泥岩层厚,有利于油气保存;逆冲前缘构造带发育低幅度隆起和地层岩性圈闭。     

Sedimentary Facies Architectures of Third-Order Sequences from Early to Middle Triassic in Nanpanjiang Basin

There are complex and regular changes on sedimentary facies from the Early to the Middle Triassic in the Nanpanjiang basin. After the obvious drowned event of carbonate platforms in the transitional period between Permian and Triassic, carbonate platforms have evolved into the ramp type from the rimmed-shelf type. The differentiation of sedimentary facies becomes dearer in space, which are marked by the changes from an attached platform to a turbidity basin and several isolated platforms in the basin. The striking characteristics are the development of oolitic banks on isolated platforms in Nanning and Jingxi and the reef- and bank-limestones in the margin of the attached platform in the Early Triassic. Despite the difference of the time-span and the architectnre of fades succession of third-order sedimentary sequences, the process of the third-order relative sea-level changes reflected by the sedimentary facies succession of the third-order sequences is generally synchronous. Therefore, six third-order sequences could be discerned in the strata from the Early to the Middle Triassic in the Nanpanjiang basin. Using two types of facies changing surfaces and two types of diachronisms in stratigraphic records as the key elements, the sedimentary facies architectures of the third-order sequences that represent sequence stratigraphic frameworks from the Early to the Middle Triassic in the Nanpanjiang basin could be constructed.     

华夏古陆活动大陆边缘的探讨

本文阐述了华南中元古代晚期活动陆缘特征。根据带内前寒武纪地层分布、古地磁、侵入作用、构造变形、深部构造、中元古代晚期沉积作用及火山岩岩石化学特征,证明活动陆缘是南华洋壳向南部古大陆俯冲的产物。武陵运动是华南最重要的运动,华夏古陆与扬子地块碰撞,形成统一的“华南古大陆”。     

Impact of Montmorillonite and Calcite on Release and Adsorption of Cyanobacterial Fatty Acids at Ambient Temperature

Minerals might act as important sorbents of sedimentary organic matter and reduce biodegradation, which favors the formation of hydrocarbon source rocks in the earth's history. Since most organic matter is degraded during the sinking process, at ambient temperature, it is important to investigate the adsorption capacity of different minerals during this process, to assess the organic loss from primary productivity to sedimentary organic matter. In this study, montmorillonite and calcite have been selected to study the impact of different minerals on the release, adsorption, and deposition of cyanobacterial (Synechococcus elonpata) fatty acids (FAs) at ambient temperature. Gas chromatography (GC), gas chromatography-mass spectrometry (GC-MS) have been utilized to detect the variation in fatty acids. Primary results suggest that minerals have a different impact on dissolved organic matter. Montmorillonite can specifically enhance the release of fatty acids from cyanobacterial cells by lowering the pH values of the solution. The adsorption of the dissolved organic matter by montmorillonite will also be enhanced under a lower pH value. Conjunction of fatty acids with montmorillonite to form a complex will favor the sinking and preservation of these organics. Selective adsorption is observed among fatty acids with different carbon numbers. In contrast, calcite does not show any impact on the release and adsorption of organic matter even though it is reportedly capable of acting as a catalyst during the transformation of organic matter at high temperature. The primary data bridge a link between primary productivity and sedimentary organic matter, suggesting the relative importance of claystones in the formation of hydrocarbon source rocks in the earth's history.