n-Alkan-2-one distributions in a northeastern China peat core spanning the last 16 kyr

Most research on long chain methyl ketones has focused on their origins and distributions. Their application in paleoclimate studies is less common than that of other n-alkyl lipids. The goal of this research was to explore this potential by studying n-alkan-2-ones from the Hani peat sequence in northeastern China. They were identified using gas chromatography-mass spectrometry (GC-MS) and showed a distribution ranging from C₁₉ to C₃₁ with a strong odd/even predominance. This type of distribution is considered to derive from Sphagum and microbial oxidation of n-alkanes. Comparison with climate sensitive indicators and macrofossil analysis shows that microbial oxidation of n-alkanes derived from higher plants was enhanced during the warm early Holocene period. This led us to develop three n-alkan-2-one proxies - C₂₇/ΣC_23-31 (C₂₇/HMW-KET), carbon preference index (CPI_H-KET) and average chain length (ACL_(27-31)-KET) - as possible indicators of paleoclimate in the peat-forming environment. These proxies, in combination with C₂₇n-alkane δD values and peat cellulose δ¹⁸O records, might allow examination of paleo-ecosystem behavior during climatic evolution in northeastern China over the past 16,000 yr.     

冀东下营坊地区晚古生代富碱侵入岩锆石U-Pb年代学、岩石地球化学及其地质意义

富碱侵入岩具有重要的地质和矿产意义,倍受学者关注。冀东地区晚古生代钙碱性岩浆岩十分发育,而碱性岩少见,笔者首次在冀东下营坊地区识别出一批与金(铜铅锌银)多金属矿化有关的晚古生代中晚期的富碱侵入岩体。通过锆石LA-ICP-MS U-Pb测年,获得下营坊地区三处富碱侵入岩的侵位年龄分别为300.0±1.5Ma、299.3±2.1Ma、300.0±2.0Ma,侵位时间显示这些岩浆岩均为晚石炭世末—早二叠世的产物。岩石地球化学特征显示富碱(K2O+Na2O8%),稀土元素含量较高,并强烈富集轻稀土,指示其具有富碱侵入岩的基本特征。下营坊富碱侵入岩富集大离子亲石元素,高La/Yb比,较高的La/Sm比值且变化范围大(5),低Y,Eu异常不明显等特点,表明其源区可能与富集地幔有关,并可能受到俯冲板片脱水所释放流(熔)体的影响,在岩浆的侵位过程中可能受到地壳物质的混染。由成岩时代结合区域构造演化历史推断,该地区富碱侵入岩很可能与古生代期间古亚洲洋板块向华北板块俯冲有关,并形成于由俯冲板块后撤的伸展环境。     

川西北甘溪地区吉维特阶核形石特征、成因及地质意义

川西北龙门山前甘溪地区吉维特阶发育一套厚2~3m灰-深灰色微生物岩,由直径0.1~4.0cm的核形石组成,其核心皆由早期葛万藻及其他生物碎屑组成,包壳由具同心圈层结构的亮色和暗色含葛万藻的纹层组成,并可分为球状、帽状和变形状3类核形石微生物岩,垂向上可分4个旋回,从底到顶核形石密度和粒径总体变密、变大,平面上呈不均匀发育。核形石样品具不同程度的δ~(13)C、δ~(18)O值负偏移和~(87)Sr/~(86)Sr正偏移特征,表明核形石微生物岩层遭受过古表生期大气淡水的影响,其中亮色纹层与球状核形石微生物岩受大气淡水影响最为强烈,核形石是在葛万藻发育、水流扰动及大气淡水参与的环境下,葛万藻包覆于生屑的外缘而成,藻类越发育、水体能量越高、沉积环境越稳定,形成的核形石粒径越大、丰度越高。核形石微生物岩在纵、横向分布特征,表明在全球中泥盆统艾菲尔期—吉维特期海平面上升背景下,龙门山地区吉维特金宝石组末期表现为至少6期次脉动式且逐渐强烈的构造抬升作用,造成该地区金宝石组末期海平面大幅下降而暴露于地表遭受大气淡水的淋滤作用。     

首都地质资源环境承载能力监测预警信息平台建设思路

为适应大数据的新背景和首都未来发展形势的新需求,同时避免"信息孤岛"、"重复建设"等现象的发生。本次以首都地质资源环境承载能力监测预警平台为例,提出以多维地理信息系统、智慧地图、互联网大数据分析等信息化技术为基础的平台建设思路,阐述了平台的总体架构及云计算技术,多源异构空间数据集成技术,大数据存储处理技术等关键技术问题,同时对平台将实现的功能应用和服务对象进行了分析和说明。     

Dehydration and melting during continental collision: Constraints from element and isotope geochemistry of low-T/UHP granitic gneiss in the Dabie orogen

A combined study of petrography, whole-rock major and trace elements as well as Rb?Sr and Sm?Nd isotopes, and mineral oxygen isotopes was carried out for two groups of low-T/UHP granitic gneiss in the Dabie orogen. The results demonstrate that metamorphic dehydration and partial melting occurred during exhumation of deeply subducted continent. Zircon δ¹⁸O values of ? 2.8 to + 4.7‰ for the gneiss are all lower than normal mantle values of 5.3 ± 0.3‰, consistent with ¹⁸O depletion of protolith due to high-T meteoric-hydrothermal alteration at mid-Neoproterozoic. Most samples have extremely low ⁸⁷Sr/⁸⁶Sr ratios at t₁ = 780 Ma, but very high ⁸⁷Sr/⁸⁶Sr ratios at t₂ = 230 Ma. This suggests intensive fluid disturbance due to the hydrothermal alteration of protoliths during Neoproterozoic magma emplacement and the metamorphic dehydration during Triassic continental collision. Rb–Sr isotopes, Th/Ta vs. La/Ta and Th/Hf vs. La/Nb relationships suggest that Group I gneiss experienced lower degrees of hydrothermal alteration, but higher degrees of dehydration, than Group II gneiss. The two groups of gneiss have similar patterns of REE and trace element partition. Group I gneiss displays good correlations between Nb and LREEs but no correlations between Nb and LILEs (Rb, Ba, Pb, Th and U), indicating differential mobilities of LILEs during the dehydration. Thus the correlation between Nb and LREEs is inherited from protolith rather than caused by metamorphic modification. Relative to Group I gneiss, Group II gneiss has stronger negative Eu anomaly, lower contents of Sr and Ba but higher contents of Rb, Th and U. In particular, Nb correlates with LILEs (e.g., Rb, Sr, Ba, Th and U), but not with LREEs (La and Ce). This may indicate decoupling between the dehydration and LILEs transport during continental collision. Furthermore, dehydration melting may have occurred due to breakdown of muscovite during “hot” exhumation. Group II gneiss has extremely low contents of FeO + MgO + TiO₂ (1.04 to 2.08 wt.%), high SiO₂ contents of 75.33 to 78.23 wt%, and high total alkali (Na₂O + K₂O) contents (7.52 to 8.92 wt.%), comparable with compositions predicted from partial melting of felsic rocks by experimental studies. Almost no UHP metamorphic minerals survived; felsic veins of fine-grain minerals occurs locally between coarse-grain minerals, resulting in a kind of metatexite migmatites due to dehydration melting without considerable escape of felsic melts from the host gneiss. In contrast, Group I gneiss only shows metamorphic dehydration. Therefore, the two groups of gneiss show contrasting behaviors of fluid–rock interaction during the continental collision.     

闽西南地区块状硫化物矿床的喷流-沉积成矿作用

通过对闽西南地区石炭纪—早二叠世主要块状硫化物矿床的区域成矿背景、贮矿层位特征以及矿石矿物成分、结构构造,硫同位素地球化学特征、成矿温度等分析研究,指出该地区石炭纪—早二叠世块状硫化物矿床的形成多与海底火山活动有关,贮矿层中伴有典型的喷流沉积岩—硅质岩,并提出闽西南地区块状硫化物矿床存在海底喷流-沉积成矿作用的新认识。     

邯邢煤田岩浆侵入及对煤层煤质的影响

根据邯邢煤田岩浆侵入特点,分析岩浆侵入煤系层位与分布规律,岩浆侵入体的产状及岩性特征。邯邢煤田岩浆岩的侵入,不仅破坏了该区煤层的连续性和完整性,减少了煤炭的可采储量,并使煤层的物理性质、化学成分和工艺性能也发生了显著变化,致使煤质变差,煤炭工业价值降低。     

李口集区块煤储层地质条件及煤层气采收率

基于煤田勘探资料和矿井实际观测结果,结合测试分析和数值计算,对平顶山矿区李口集区块煤储层地质条件进行了研究。结果表明：区块内主煤层的煤体结构破坏严重,小型裂隙发育但连通性较差,含气量中等且属于低压煤储层,煤层气采收率偏低,地面原位开采的难度较大。为此,建议该区块的煤层气开发以矿井抽采为主,并在煤矿采动带和采空区辅以合理的地面抽采工程。     

基于MSC MARC的三维构造应力场数值模拟与裂缝预测——以宝浪油田宝北区块为例

MSC MARC的高度非线性有限元分析能力与强大的二次开发接口为复杂三维地质数值模型的建立与三维构造应力模拟与非线性分析提供了有力工具; 并可以通过二次开放子程序建立复杂的岩石本构与破裂准则。本文基于MSC MARC建立了新疆焉耆盆地宝浪油田宝北区块背斜构造三维有限元模型并进行了构造应力模拟分析和裂缝预测。裂缝预测结果与实际动态资料十分吻合。      

花岗岩构造研究及花岗岩构造动力学刍议

花岗岩可以视为一种很好的构造标志体,犹如褶皱、断裂一样。从花岗岩浆的形成、融体分离、岩浆上升到岩体定位以及变形改造的全过程都蕴含着丰富的构造动力学信息。研究花岗岩浆上升、迁移和定位可以探讨构造块体抬升及区域构造动力学。岩体生长方式与构造块体的运动学、动力学有密切的关系,极性生长揭示了上、下构造块体或岩石圈之间的相对的近水平方向剪切运移。变形花岗岩体是一种区域尺度的应变标志体,可以进行岩石有限应变测量和流变学参数估算,为分析区域构造变形特征提供应变参数。以对不同期次、不同变形程度花岗岩体为间接标志体,通过锆石定年可以限定变形的时间,特别是有可能确定早期变形的时间。岩体定位深度的系统研究有利于了解构造块体的抬升和深部构造作用。花岗岩构造与花岗岩成因类型特别是其演变研究的结合是判别构造块体动力学背景以及其转换的有效途径。通过这几方面的系统研究和有机结合,可以提供丰富的构造动力学信息,是否可能发展成较系统的花岗岩构造动力学值得探讨。