A new compilation of N‐isotope and abundance data for metasedimentary rocks, and hyrdothermal micas that proxy for bulk crust, show systematic patterns. (1) δ15N values of kerogen in Precambrian cherts are more negative relative to siliciclastic counterparts, probably due to a mantle hydrothermal component. (2) There is a secular trend from average δ15N 15.3 ± 1.8‰ in Archean shales, through intermediate values in the Proterozoic, to Phanerozoic counterparts where δ15N averages +3.5‰. (3) Hydrothermal micas in metamorphic hydrothermal systems of Palaeozoic and Mesozoic age that proxy for crust have δ15N within the range of contemporaneous sedimentary rocks. (4) Hydrothermal micas track the secular trend of δ15N for kerogen from 2.7 Ga to the Phanerozoic. (5) Within Precambrian datasets δ15N does not increase with decreasing N content; accordingly, high δ15N values cannot stem either from metamorphism or form Rayleigh fractionation. (6) Previous studies show isotopic shifts during metamorphism are only +1 to +3‰ up to amphibolite facies. Values of 10–24‰ are attributed to a high δ15N Archean atmosphere, a residual signature of CI carbonaceous chondrites where δ15N is +30‰ to + 42‰. 相似文献
The application of the saddlepoint approximation to reliability analysis of dynamic systems is investigated. The failure event in reliability problems is formulated as the exceedance of a single performance variable over a prescribed threshold level. The saddlepoint approximation technique provides a choice to estimate the cumulative distribution function (CDF) of the performance variable. The failure probability is obtained as the value of the complement CDF at a specif ied threshold. The method requires computing the saddlepoint from a simple algebraic equation that depends on the cumulant generating function (CGF) of the performance variable. A method for calculating the saddlepoint using random samples of the performance variable is presented. The applicable region of the saddlepoint approximation is discussed in detail. A 10-story shear building model with white noise excitation illustrates the accuracy and effi ciency of the proposed methodology. 相似文献
Discrete element method has been widely adopted to simulate processes that are challenging to continuum-based approaches. However, its computational efficiency can be greatly compromised when large number of particles are required to model regions of less interest to researchers. Due to this, the application of DEM to boundary value problems has been limited. This paper introduces a three-dimensional discrete element–finite difference coupling method, in which the discrete–continuum interactions are modeled in local coordinate systems where the force and displacement compatibilities between the coupled subdomains are considered. The method is validated using a model dynamic compaction test on sand. The comparison between the numerical and physical test results shows that the coupling method can effectively simulate the dynamic compaction process. The responses of the DEM model show that dynamic stress propagation (compaction mechanism) and tamper penetration (bearing capacity mechanism) play very different roles in soil deformations. Under impact loading, the soil undergoes a transient weakening process induced by dynamic stress propagation, which makes the soil easier to densify under bearing capacity mechanism. The distribution of tamping energy between the two mechanisms can influence the compaction efficiency, and allocating higher compaction energy to bearing capacity mechanism could improve the efficiency of dynamic compaction.
Science China Earth Sciences - Helium gas is a scarce but important strategic resource, which is usually associated with natural gas. Presently, only one extra-large helium-rich gas field has been... 相似文献