Determining Pressure with Daughter Minerals in Fluid Inclusion by Raman Spectroscopy: Sphalerite as an Example

Abstract: Raman frequency of some materials, including minerals, molecules and ions, shifts systematically with changing pressure and temperature. This property is often used as a pressure gauge in high pressure experiments with the hydrothermal diamond anvil cell (HDAC). Since the system of fluid inclusion is similar to that of HDAC, it can also be used to determine the internal pressure of fluid inclusions. Sphalerite is a common daughter mineral. In this study, the frequency shift of the 350 cm?1 peak of sphalerite has been studied from 296 to 523 K and from 0.07 to 2.00 GPa using the HDAC. The global slope of the isotherms (?n350/?p)T is 0.0048 in the studied pressure range. No significant variation of the slopes with temperature has been observed. The correlation between the frequency shift of the 350 cm?1 peak of sphalerite and pressure and temperature is constrained as P=208.33(?np)350+3.13T?943.75. This relationship may be used to estimate the internal pressure of the sphalerite-bearing fluid inclusions.     

考虑时变影响的拱坝坝肩空间变形场预测

坝肩变形是拱坝坝肩稳定状态的综合反映,在运行期呈小变形变化,监测点测值在空间上具有连续性,同时影响拱坝坝肩变形的各种因素具有时变性。通过融合统计回归和多层递阶方法的特点,建立了反映变形场空间和时变特性的空间时变分析模型。实例分析表明,该模型实用有效,预测精度高。考虑时变影响可以提高拱坝坝肩空间变形场的预测能力,对监控拱坝坝肩的实际工作状况有重要意义。     

地下水污染调查多级监测井建造及取样技术

多级地下水监测井能够在一个井内监测多个深度段水质和污染状况,在场地污染调查污染羽三维描述中起着不可替代的作用。一口多级地下水监测井可等同多口单管监测井,节约施工成本和维护费用。本文在实地典型污染场地调查的基础上,对多级监测井建造及其取样技术进行了研究,为以后的工作奠定了基础。     

西藏纳当地区永珠组构造变形特征

西藏纳当地区石炭系永珠组主要为浅变质的砂板岩组合,断层和褶皱非常发育的特征。依据岩石和构造特征可以把区内永珠组分成上、中、下三段。永珠组形成于拉张的被动大陆边缘向裂谷转换的次深海环境,并于中晚二叠世至晚三叠世期间经历了三个构造演化阶段。     

中国图们江河口湖沼沉积中植硅体古气候变化特征

通过对中国图们江河口湖沼沉积剖面的植硅体组合的分析,划分出该剖面自17.1～2.247 kaB.P.期间的6个植硅体组合带,分别对应冷干-凉湿-冷干-凉湿-温暖-温湿的气候阶段.将分析结果与本剖面Na、K、Ba、Cu、Pb、Fe、Mn分析相对比,发现植硅体对气候湿润程度的反映不如Na、K、Fe敏感,但是比其它指标,如泥炭地发育程度对湿润度的反映,要灵敏得多.区域对比发现,本剖面的植硅体古气候过程存在着区域上的良好响应,对全球变化与区域响应研究起着积极作用.     

东昆仑大干沟火山岩SHRIMP锆石U-Pb测年及其地质意义

东昆仑大干沟以北地区造山后形成的牦牛山组磨拉石建造不整合覆盖于前泥盆系之上,其形成时代对限定柴达木盆地加里东造山作用的结束时间及晚古生代裂解作用的开始时间具有重要意义。应用单颗粒锆石离子探针质谱仪(SHRIMP)方法,对牦牛山组上部火山岩段的样品进行精确的锆石U-Pb测年。结果表明,牦牛山组上段火山岩样品DG01和DG02中的岩浆锆石206Pb/238U平均年龄分别为403.6±5.1Ma和409±3.4Ma。综合前人研究认为,造山后牦牛山组伸展型磨拉石的形成时代为晚志留世-早泥盆世,限定了晚古生代裂解的开始时间,也意味着早古生代加里东造山运动在晚志留世-早泥盆世之前已经结束。     

A Preliminary Research on the Development of the Hard X-ray Imaging Telescope

The hard X-ray imaging telescope based on the Fourier transform imaging technique is introduced. The double-layer parallel gratings are used to make the modulation and coding on the light emerging from a celestial X-ray source, the modulated light is acquired, to make the optoelectronic conversion by scintillation crystal detectors, and ?nally read out by the electronic system. The modulation collimator X-ray telescopes can be divided into two types: the spatial modulation and temporal modulation. The temporal modulation system requires the scanning motion of the detector system, but the spatial modulation system requires no motion. The technology of grating fabrication is investigated, and the basic structure design of the collimators is given. The principal compo- nents of the prototype hard X-ray imaging telescope of spatial modulation type are successfully developed, including the 8 CsI crystal detector modules (contain- ing photomultipliers or PMTs), 8-channel shaping ampli?ers (two of them are prepared for experiments), and the data acquisition system. And the preliminary test results of the electronic system are also given.     

水和土壤环境非水溶相污染物的表面活性剂增效修复机制

分析了表面活性剂和非水溶相有机污染物在水和土壤环境中的相互作用,以及表面活性的特性,解释了表面活性剂增效修复水和土壤环境中非水溶相污染物的机制。表面活性剂溶液通过增溶作用和增流作用,驱除地下水含水层中的非水相液体以及吸附于土壤颗粒物上的污染物,提高地下水和土壤中憎水性有机污染物的现场修复速率。增效修复效果依赖于临界胶束浓度(CMC)、污染物和表面活性剂的吸附特性、污染物的溶解性和土壤类型等。表面活性剂能增加化合物的溶解度,降低与水的界面张力,并形成乳液。     

地形地貌发育时间与古地形反演

地形地貌是构造过程与地表过程等相互竞争的结果,古地形重建与地貌演化研究将有助于理解这些过程及其相互作用关系。传统的地形地貌演化研究多基于14C、释光、磁性地层等定年手段,定性或半定量地分析构造活动与地表侵蚀对地形地貌发育的影响。随着相关技术手段的发展,低温热年代学方法已不仅仅局限于构造地质学领域的造山带构造-热演化历史研究,目前已用于重建地形地貌演化历史。基于这一背景,在概述低温热年代学基本原理的基础上,结合自己的研究,主要介绍了该方法在地形地貌发育时间、古地形反演等方面的研究进展以及研究中需要注意的一些问题。文章最后指出,寻求具有更低封闭温度的低温热年代学测年体系是这方面研究的努力方向。