Dissolution mechanisms of water in depolymerized silicate melts: Constraints from H and Si NMR spectroscopy and ab initio calculations

Dissolution of water in magmas significantly affects phase relations and physical properties. To shed new light on the this issue, we have applied ¹H and ²⁹Si nuclear magnetic resonance (NMR) spectroscopic techniques to hydrous silicate glasses (quenched melts) in the CaO-MgO-SiO₂ (CMS), Na₂O-SiO₂, Na₂O-CaO-SiO₂ and Li₂O-SiO₂ systems. We have also carried out ab initio molecular orbital calculations on representative clusters to gain insight into the experimental results.The most prominent result is the identification of a major peak at ∼1.1 to 1.7 ppm in the ¹H MAS NMR spectra for all the hydrous CMS glasses. On the basis of experimental NMR data for crystalline phases and ab initio calculation results, this peak can be unambiguously attributed to (Ca,Mg)OH groups. Such OH groups, like free oxygens, are only linked to metal cations, but not part of the silicate network, and are thus referred to as free hydroxyls in the paper. This represents the first direct evidence for a substantial proportion (∼13∼29%) of the dissolved water as free hydroxyl groups in quenched hydrous silicate melts. We have found that free hydroxyls are favored by (1) more depolymerized melts and (2) network-modifying cations of higher field strength (Z/R²: Z: charge, R: cation-oxygen bond length) in the order Mg > Ca > Na. Their formation is expected to cause an increase in the melt polymerization, contrary to the effect of SiOH formation. The ²⁹Si MAS NMR results are consistent with such an interpretation. This water dissolution mechanism could be particularly important for ultramafic and mafic magmas.The ¹H MAS NMR spectra for glasses of all the studied compositions contain peaks in the 4 to 17 ppm region, attributable to SiOH of a range of strength of hydrogen bonding and molecular H₂O. The relative population of SiOH with strong hydrogen bonding grows with decreasing field strength of the network-modifying cations. Ab initio calculations confirmed that this trend largely reflects hydrogen bonding with nonbridging oxygens.     

Soil respiration in tropical seasonal rain forest in Xishuangbanna, SW China

With the static opaque chamber and gas chromatography technique, from January 2003 to January 2004 soil respiration was investigated in a tropical seasonal rain forest in Xishuangbanna, SW China. In this study three treatments were applied, each with three replicates: A (bare soil), B (soil+litter), and C (soil+litter+seedling). The results showed that soil respiration varied seasonally, low from December 2003 to February 2004, and high from June to July 2004. The annual average values of CO2 efflux from soil respiration differed among the treatments at 1% level, with the rank of C (14642 mgCO2· m-2. h-1)＞B (12807 mgCO2· m-2. h-1)＞A (9532 mgCO2· m-2. h-1). Diurnal variation in soil respiration was not apparent due to little diurnal temperate change in Xishuangbanna. There was a parabola relationship between soil respiration and soil moisture at 1% level. Soil respiration rates were higher when soil moisture ranged from 35% to 45%. There was an exponential relationship between soil respiration and soil temperature (at a depth of 5cm in mineral soil) at 1% level. The calculated Q1o values in this study,ranging from 2.03 to 2.36, were very near to those of tropical soil reported. The CO2 efflux in 2003was 5.34 kgCO2· m-2. a-1 from soil plus litter plus seedling, of them 3.48 kgCO2· m-2. a-1 from soil (accounting for 62.5%), 1.19 kgCO2· m-2. a-1 from litter (22.3%) and 0.67 kgCO2·m-2. a-1 from seedling (12.5%).     

2022年泸定Ms6.8级地震发震构造与鲜水河断裂带强震迁移规律

2022年9月5日12时52分在四川甘孜州泸定县发生Ms6.8级地震,震源深度16 km。这是继2014年康定地震后,发生在鲜水河断裂带上的又一次强震。笔者等通过已有文献资料,结合鲜水河断裂带南段野外地质调查,统计了滑动速率及历史地震资料,并总结了近代鲜水河断裂带强震迁移规律,对认识鲜水河断裂带活动特征及未来地震危险性具有重要意义。主要得出以下几点认识：①鲜水河断裂带各段滑动速率差异较大,以乾宁为界,从NW至SE段整体上呈现出“先减速后加速”的滑动特点;②泸定地震发震构造磨西断裂,为一次左旋走滑事件;③川滇地区近代历史强震活跃期具有“跳跃性”迁移的特点。自1981年道孚地震后,鲜水河断裂带断进入相对平静期,持续了33 a。自2014年康定地震发生,鲜水河断裂带再次进入地震活跃期;④鲜水河断裂带的强震破裂并非单次地震的“贯通型”模式,而是多次地震的渐进式。断层间相互作用尤其是大地震的发生对断裂带强震复发间隔具有重大影响,相同断裂带的强震也会对后续地震的发生概率产生变化。     

辽宁省精细化暴雨洪涝灾害风险评估与预评估

基于辽宁省61个国家气象站1961—2020年和998个区域自动气象观测站建站至2020年逐小时、逐日降水资料,分析了辽宁省暴雨洪涝灾害主要致灾因子,计算了暴雨洪涝孕灾环境指标,完成了辽宁省暴雨洪涝灾害危险性评估。结果表明：暴雨洪涝高危险性地区主要位于丹东;暴雨洪涝灾害人口高风险区主要位于沈阳和大连市区;经济高风险区主要位于大连和盘锦市区;水稻、玉米高风险区主要位于锦州、盘锦和丹东。利用辽宁省无缝隙智能网格预报数据对2022年7月28—29日的暴雨过程灾害风险进行了预评估,发现暴雨灾害危险性高值区域主要分布在朝阳、葫芦岛以及辽宁中部。暴雨灾害可能造成的人口、经济高风险区域主要位于辽宁西部和中部地区;暴雨灾害可能造成的水稻和玉米高风险区主要位于沈阳、铁岭和朝阳北部等地区。预计高风险区主要影响人口约为449万人,经济损失约为1432万元,受影响的水稻面积约为1.028万公顷、玉米面积约为1.798万公顷。通过灾后效果检验,发现预评估模型效果良好,可在实际的暴雨洪涝灾害风险评估业务中使用。     

Influence of Near Real-Time Green Vegetation Fraction Data on Numerical Weather Prediction by WRF over North China

The green vegetation fraction(GVF) can greatly influence the partitioning of surface sensible and latent heat fluxes in numerical weather prediction(NWP) models. However, the multiyear averaged monthly GVF climatology—the most commonly used representation of the vegetation state in models—cannot capture the real-time vegetation state well. In this study, a near real-time(NRT) GVF dataset generated from an 8-day composite of the normalized difference vegetation index is compared with the 10-yr averaged monthly GVF provided by the WRF model. The annual variability of the GVF over North China is examined in detail. Many differences between the two GVF datasets are found over dryland, grassland, and cropland/grassland mosaic areas. Two experiments using different GVF datasets are performed to assess the impacts of GVF on forecasts of screen-level temperature and humidity. The results show that using NRT GVF can lead to a widespread reduction of 2-m temperature forecast errors from April to October.Evaluation against in-situ observations shows that the positive impact on 2-m temperature forecasts in the morning is more distinct than that in the afternoon. Our study demonstrates that NRT GVF can provide a more realistic representation of the vegetation state, which in turn helps to improve short-range forecasts in arid and semiarid regions of North China. Moreover, our study shows that the negative effect of using NRT GVF is closely related to the initial soil moisture.     

新疆地区表土孢粉空间分布规律研究

中国新疆地区表土花粉研究结果展示了干旱区主要孢粉的空间分布规律,大部分表土花粉属种的地理空间分布与含量与相应植物的分布区域基本一致,藜科、蒿属、麻黄属及木本植物云杉属、桦木属等花粉普遍呈超代表性,柽柳属花粉呈低代表性。干旱区主要草灌木表土花粉数据的聚类分析结果可以基本反映本区植物群落的主要生态组合类型。主成分分析进一步表明该区草本和灌木花粉分布主要受水文和湿度等因素控制。     

CMIP5模式对东太平洋ITCZ偶极子模态模拟能力的评估

本研究利用第五次国际间耦合模式比较计划(Coupled Model Intercomparison Project phase 5, CMIP5)中的24个模式的工业革命前控制试验(Pre-industrial Control, picontrol)模拟结果, 结合观测资料, 评估了24个CMIP5 模式对东太平洋热带辐合带偶极子(Eastern Pacific ITCZ dipole, EPID)降水模态的模拟能力, 并建立了其与模式对热带太平洋气候态模拟之间的联系。结果表明: 1) 绝大多数模式在北半球春季(2—4月)对EPID模态模拟能力较差, 主要原因在于CMIP5模式对热带辐合带(Intertropical Convergence Zone, ITCZ)的模拟偏差, 其中模拟效果较差的模式在2—4月的气候态降水分布在赤道以南, 且降水普遍偏强; 2) 对各模式的EPID模态选取的季节按照技巧评分最高进行调整后, 大部分模式能较好地模拟出EPID模态的空间分布特点, 技巧评分在0.6以上, 其中模拟效果好的模式(技巧评分大于0.7)中EPID模态出现的月份同时在中东太平洋气候态表现出“双ITCZ”特征, 且多模式集合结果的模拟误差小于绝大多数模式。     

HALOE资料揭示的热带平流层CH4时空变化特征

中层大气微量成分的分布和变化是中层大气研究的重要问题之一,但是长期以来中层大气的资料非常少。卤素掩星试验（HALOE）对中层大气多种微量气体进行观测,形成中层大气多种微量元素的空间分布和时间演变资料组,这是对中层大气微量气体含量资料的极大补充。作者利用1992～2003年HALOE资料分析热带地区（20°S～20°N）平均的CH4的垂直分布和时间演变特征。结果表明:热带平流层CH4混合比在平流层下层有较充分的混合;热带平流层CH4混合比的季节变化明显,在平流层中上层以年循环为主,而在平流层下部以半年变化为主;热带平流层CH4混合比的年际变化主要有准2年和准5年振荡。       

The Impact of Climatic and Environmental Factors on n-Alkanes Indices in Southwestern Tibetan Plateau

n-Alkanes are widely used in paleoenvironmental reconstructions.However,our understanding of changes in the distribution of n-alkanes with climatic and environmental factors remains unclear in arid/semi-arid regions.We sampled 26 surface sediments from three climatic zones across the southwestern Tibetan Plateau to evaluate the sensitivity of chain length distributions of n-alkanes to climatic and environmental parameters.Our observations demonstrate that average chain length (ACL), proportion of aquatic macrophyte (Paq),carbon preference index (CPI) and ratio of the contents of nC27 and nC31 (nC27/nC31) are all sensitive to hydroclimatic conditions.In contrast to commonly-adopted assumptions,the correlations between these indices and hydrological parameters are not always good,which indicates that the interpretation of n-alkane indices is special on the southwestern Tibetan Plateau.These might be related to the vegetation characteristics and seasonality of biological activity,and need to be considered in paleoclimatic reconstruction.The impact of seasonal precipitation on n-alkanes indices was also evaluated.     

西藏甲玛-卡军果推-滑覆构造系特征

通过矿区填图和路线调查,结合室内研究,指出:①甲玛-卡军果推-滑覆构造系由印度-欧亚板块碰撞引发,具有递进变形、自盆地中心向边部推覆、新盖老等特点,强变形于50Ma±。②推覆体下盘为叶巴组构造岩系;推覆体由上侏罗统和下白垩统碳酸盐-碎屑沉积岩系构成,主体为轴面北倾的复式褶皱,自南而北分为前部带、中部带和后部带。滑覆构造系推覆形成的复背斜轴部高位岩块失稳向北滑覆形成,自南而北分为后部带、中部带和前部带。③导致矿区蚀变的主要岩浆活动发生于推覆强变形后的松弛期,上侵受近南北向基底断裂和推覆断裂联合控制,就位受控于前部带推-滑覆褶断系,其后发生多次构造-岩浆-成矿液叠加,造就甲玛铜多金属矿床。