Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.     

中国1∶100万景观生态制图设计

中国1∶100万景观生态图系借鉴国内外传统景观制图方法和制图规范,在遥感、地理信息系统先进技术的支持下,设计研制其制图方法、制图内容、样图和技术流程,同时提出初步的景观分类系统,为今后编制中国1∶100万景观生态图奠定基础。     

ANALYSIS OF DRIVING FORCES ON THE CHANGE OF HISTORICAL FARMLAND USE IN SHANDONG PROVINCE DURING THE QING DYNASTY (1644-1911)

1INTRODUCTIONTheIGBP-IHDP(InternationalGeosphere-BiosphereProgramme,andInternationalHumanDimensionPro-gramme)jointproject—LUCC(landuse/coverchange)isaninterdisciplinaryprogramdesignedtoimprovetheunderstandingofthedynamicsofland-useandland-coverchangeasinputstoandconsequencesofglobalenvironmentalchangeandsustainabledevelopment(CHARLOTTE,2002).Inparticularthedifferentbio-geochemicalmodeling(e.g.theglobalcarboncycle)ac-tivitiesandcomparativestudies,suchasthoseconduct-edbyIGBP-G…     

新近对耀变体(Blazar)的X射线观测

本文综述了ASCA ,RXTE ,BeppoSAX和XMM -NEWTON对TeV耀变体 (Blazar)X射线研究的最新进展。主要集中在X射线资料的时间和光谱分析的最重要的方面 ,包括功率谱密度 ,结构函数 ,带间时间延迟 ,同步峰值能量的漂移和谱演化。对这些新结果的物理意义也进行了简要讨论。     

EMERGY ANALYSIS OF GRAIN PRODUCTION SYSTEM IN JIANGSU AND SHAANXI PROVINCE

1INTRODUCTIONGrain production has always been top-priority issue con-cerned by government and people (MA etal., 2002). Af-ter China put household contract responsibility system in force, its domestic issue of grain was basically settled in the mid 1980s (MA and XU, 1999). However, in the days when idea of sustainable development is broadly accepted, efficiency and sustainability of grain produc-tion are now in question, which have prompted interest in reviewing grain production patterns…     

概率赋范空间的S-凸和K-凸

文献[1][2]认为M－PN空间是局部凸的。通过定理说明这个结论对t-模T（a,b)≥min(a,b)时成立。又通过反例表明，当t-模型T（a,b)=max(a b-1,0）时无论邻域Nθ（ε，λ）概率有界还是概率半有界结论均不成立。还讨论了Takahashi凸性并对S－凸和K－凸作了比较。     

流动VLBI站氢原子钟的研制与性能测试

氢脉泽是射电天文所必需的频率标准.文中对为流动vLBI站研制的新一代氢脉泽的物理结构特点进行了讨论，包括对腔泡结构、磁屏蔽、原子束光学系统等.同时性能测试表明在80秒到1天之间频率稳定度优于1×10     

海量多波段星表数据的交叉证认的实现

许多天文学家需要星表来选源、证认和研究。目前国外有一些大的数据中心提供了星表查询、多源查询(即小样本交叉证认)、可视化等功能。但是随着大数据量及全波段天文时代的到来,这些服务已经越来越不能满足天文学家的需求。在详细分析了国外数据中心的服务后,提出了新的问题,并给出一套解决方案。着重讨论了任意两个星表的交叉证认和大数据量星表的交叉证认的实现,以及交叉证认结果的分类和参数的自由选择等方面的课题。     

SHORT COMMUNICATION TARGET FACTOR ANALYSIS:UV SPECTROPHOTOMETRY FOR THE SIMULTANEOUS DETERMINATION OF SIX AMINO ACIDS

The UV spectra of mixture solutions consisting of tyrosine,tryptophane,phenylalanine,cystine,histidineand 3,4-dihydroxyl phenylalanine have been measured.The numbers,identities and concentrations of theamino acids in the mixtures have been determined successfully using target factor analysis.The effectsof the wavelength range and the selected sampling interval on the results are discussed.Twenty-fivesynthetic mixture samples have been analysed successfully.The average recoveries are 98·9 for Tyr,96·5for Trp,105·6 for Phe,98·1 for Cys,98·9 for His and 106·4 for Di-phe.The results obtained are ingood agreement with those obtained by the Kalman filter method.     

5个新发现的X选BL Lac天体

利用ＲＯＳＡＴＶＬＡ方法筛选，从ＲＯＳＡＴＸ射线源中选出了一批新的ＢＬＬａｃ天体和类星体的候选体．１９９６年１２月８日至１７日，利用北京天文台２．１６ｍ望远镜和新从美国引进的ＯＭＲ摄谱仪，对这批新候选体进行了光谱认证．经ＳＵＮ工作站处理，又发现了５个新的Ｘ选ＢＬＬａｃ天体．此外，还对去年作者在ＯＭＲ引进之前发现的ＢＬＬａｃ天体进行了检验，结果发现，去年发现的７个ＢＬＬａｃ天体中，２３２２＋３４３的ＣａＩＩＨ＆Ｋ“Ｂｒｅａｋｓｔｒｅｎｇｔｈ”为２６．９％，稍大于判据２５％，因此，２３２２＋３４３到底是ＢＬＬａｃ天体还是射电星系还有待于进一步测光及偏振观测的验证．