Electron microscopy of clinoenstatite from a boninite and a chondrite

Clinoenstatite crystals from a boninite and the Yamato-74191 chondrite have been studied with an analytical electron microscope. (100) twins and cracks perpendicular and parallel to the c axis are characteristic of their submicroscopic textures. The frequency in appearance along the c axis and widths of the cracks have been explained by the dimensional change of the c axis in the direct transformation of protoenstatite to clinoenstatite and by the cooling rate around the transformation temperature. The cracks in the crystals from the boninite are filled with fibrous crystals of talc, while those from the chondrite are open or filled with glass in which fine crystals of plagioclase are common.     

Geochronology of the khondalite belt of Trivandrum Block, Southern India: Electron probe ages and implications for Gondwana tectonics

In a comprehensive U–Pb electron microprobe study of zircon and monazite from the khondalite belt of Trivandrum Block in southern Kerala, we present age data on five key metapelite locations (Nedumpara, Oottukuzhi, Kulappara, Poolanthara and Paranthal). The rocks here, characterized by the assemblage of garnet–sillimanite–spinel–cordierite–biotite–K–feldsapr–plagiocalse–quartz–graphite, have been subjected to granulite facies metamorphism under extreme thermal conditions as indicated by the stability of spinel + quartz and the presence of mesoperthites that equilibrated at ultrahigh-temperature (ca. 1000 °C) conditions. The oldest spot age of 3534 Ma comes from the core of a detrital zircon at Nedumpara and is by far the oldest age reported from this supracrustal belt. Regression of age data from several spot analyses in single zircons shows “isochrons” ranging from 3193 ± 72 to 2148 ± 94 Ma, indicating heterogeneous population of zircons derived from multiple provenance. However, majority of zircons from the various localities shows Neoproterozoic apparent ages with sharply defined peaks in individual localities, ranging between 644–746 Ma. The youngest zircon age of 483 Ma was obtained from the outermost rim of a grain that incorporates a relict core displaying ages in the range of 2061–2543 Ma.The cores of monazites also show apparent older ages of Palaeo-Mesoproterozoic range, which are mantled by late Neoproterozoic/Cambrian rims. The oldest monazite core has an apparent age of 2057 Ma. Extensive growth of new monazite during latest Neoproterozoic to Cambrian–Ordovician times is also displayed by grain cores with apparent ages up to 622 Ma. The homogeneous core of a sub-rounded monazite grain yielded a maximum age of 569 Ma, markedly younger than the 610 Ma age reported in a previous study from homogenous and rounded zircon core from a metapelite in Trivandrum Block. These younger ages from abraded grains that have undergone fluvial transport are interpreted to indicate that deposition within the khondalite belt was as young as, or later than, this range. Probability density plots indicate that majority of the monazite grain population belong to Late Proterozoic/Cambrian age (ca. 560–520 Ma) with major peaks defining sharp spikes in individual localities.The age data presented in this study indicate that the metasediments of the Trivandrum Block sourced from Archaean and Paleo-Mesoproterozoic crustal fragments that were probably assembled in older supercontinents like Ur and Columbia. The largest age population of zircons belong to the Neoproterozoic, and are obviously related to orogenies during the pre-assembly phase of Gondwana, possibly from terrains belonging to the East African Orogen. Several prominent age spikes within the broad late Neoproterozoic–Cambrian age range displayed by monazites denote the dynamic conditions and extreme thermal perturbations attending the birth of Gondwana. Our study further establishes the coherent link between India and Madagascar within the East Gondwana ensemble prior to the final assembly of the Gondwana supercontinent.     

Irradiation of NH3CH4 mixtures as a model of photochemical processes in the Jovian planets and Titan

Photolysis of NH₃ in the presence of CH₄ with a 185-nm light source results in the generation of hot hydrogen atoms that abstract hydrogen from the CH₄ to produce CH₃·. Subsequent reactions of CH₃· and NH₂· give hydrocarbons, CH₃NH₂, and HCN. The extent of reaction of CH₄ was measured by the ratio of the moles of CH₄ reacted per mole of NH₃ decomposed ($\text{Δ}\text{CH}{}_4\text{Δ}\text{NH}{}_3$). This ratio increases with diminishing NH₃ pressure at constant CH₄ pressure but it remains constant if $\text{CH}{}_4\text{NH}{}_3\text{?3}$. The $\text{Δ}\text{CH}{}_4\text{Δ}\text{NH}{}_3$ ratio is independent of temperature in the range 156–298° K, suggesting that hot hydrogen atoms were responsible for the reaction of CH₄. This postulate was confirmed by the observation that this reaction was quenched when H₂ or SF₆ was added to the reaction mixture.     

Characteristics of Sea Surface Circulation and Eddy Field in the South China Sea Revealed by Satellite Altimetric Data

Temporal and spatial variations of sea surface circulation in the South China Sea were revealed with use of altimetric data provided by TOPEX/POSEIDON from December 1992 to October 1997. The estimated distribution of sea surface dynamic heights from altimetric data coincide well with the results of observation by Soong et al. (1995) and Chu et al. (1998). The RMS variability of sea surface dynamic height, which is obtained after tidal correction based on Yanagi et al. (1997), is high in the central part of the South China Sea, the Gulf of Tongking, the Sunda Shelf and the Gulf of Thailand. The high RMS variability in the Gulf of Tongking, the Sunda Shelf and the Gulf of Thailand is due to set up and set down of sea water by the East Asian monsoon, which is northeasterly during winter and southwesterly during summer. Also, the high RMS variability in the central part of the South China Sea is due to the variations of basin-wide circulation. The circulations are dominant in the central part of the South China Sea during summer and winter, an anticyclonic circulation during summer and a cyclonic circulation during winter. It is suggested that these circulations are controlled by the East Asian monsoon. Hence, there is an interannual variability of the basin-wide circulation associated with the variation of the East Asian monsoon.     

Movement of the Kuroshio axis to the northeast shelf of Taiwan during typhoon events

We investigated the movement of the Kuroshio axis on the northeast shelf of Taiwan associated with the passage of typhoons, using sea surface current data observed by the ocean radar system on Yonaguni and Ishigaki islands. First, we examined daily Kuroshio axis variation on the northeast shelf of Taiwan during typhoon events. The ocean radar data showed that the Kuroshio axis moved onto the shelf after passages of typhoons. The Kuroshio moved onto the shelf and stayed there after the passage of Typhoon Hai-Tang; while the Kuroshio maintained this pattern, southerly wind blew continuously for 4 days. The mean current speed northeast of Taiwan after the typhoon's passage increased by 18 cm s⁻¹. In addition, the sea level difference between two satellite altimetry tracks east of Taiwan increased by 14.4 cm. These results suggest that coastal upwelling east of Taiwan caused by the southerly wind generated an east–west sea level difference that, in turn, generated a northward geostrophic current. This current could have enhanced the Kuroshio east of Taiwan, and pushed it onto the shelf.     

Dynamics of distinct intraseasonal oscillation in summer monsoon rainfall over the Meghalaya–Bangladesh–western Myanmar region: covariability between the tropics and mid-latitudes

Detailed spatiotemporal structures for the submonthly-scale (7–25 days) intraseasonal oscillation (ISO) in summer monsoon rainfall and atmospheric circulation were investigated in South Asia using high-quality rainfall and reanalysis datasets. The Meghalaya–Bangladesh–coast of the western Myanmar (MBWM) region is the predominant area of submonthly-scale ISO in the Asian monsoon regions. The distinct rainfall ISO is caused by a remarkable alternation of low-level zonal wind between westerly and easterly flows around the Gangetic Plain on the same timescales. In the active ISO phase of the MBWM, a strong low-level westerly/southwesterly flows around the plain and a center of cyclonic vorticity appears over Bangladesh. Hence, a local southerly flows toward the Meghalaya Plateau and there is strong southwesterly flow towards the coast along southeastern Bangladesh and western Myanmar, resulting in an increase in orographic rainfall. Rainfall also increases over the lowland area of the MBWM due to the low-level convergence in the boundary layer under the strong cyclonic circulation. The submonthly-scale low-level wind fluctuation around the MBWM is caused by a westward moving n = 1 equatorial Rossby (ER) wave. When the anticyclonic (cyclonic) anomaly related to the ER wave approaches the Bay of Bengal from the western Pacific, humid westerly/southwesterly (easterly/southeasterly) flows enhance around the Gangetic Plain on the northern fringe of the anticyclone (cyclone) and in turn promote (reduce) rainfall in the MBWM. Simultaneously, robust circulation signals are observed over the mid-latitudes. In the active phase, cyclonic anomalies appear over and around the TP, having barotropic vertical structure and also contributing to the enhancement of low-level westerly flow around the Gangetic Plain. In the upper troposphere, an anticyclonic anomaly is also observed upstream of the cyclonic anomaly over the TP, having wavetrain structure. The mid-latitude circulation around the TP likely helps to induce the distinct ISO there in conjunction with the equatorial waves. Thus, the distinct ISO in the MBWM is strongly enhanced locally (~500 km) by the terrain features, although the atmospheric circulation causing the ISO has a horizontal scale of ~6,000 km or more, extending across the whole Asian monsoon system from the tropics to mid-latitudes.     

The superstructure of plagioclase feldspars

A modulation function representing the position and density of (Na, Ca) atoms in the superstructure of the e-plagioclase has been derived from the average structures of different plagioclase and a general modulation theory. Based on this function the superstructure of bytownite (An₇₃) has been studied with the single crystal X-ray method. The cell dimensions by Megaw's axes are a=7.946(3)A, b=67.09(2)A, c=12.236(4)A, α=39.03(1)°, β=45.63(1)° and γ=59.63(1)°. Z=18(Na, Ca) Al(Al, Si)Si₂O₈. The initial phase factor of the modulation function for bytownite has been obtained from the intensity data of the satellite reflections. This modulation function indicates a coherent small-scale alternation of the Na-rich and Ca-rich bands in the superstructure. This superstructure has been refined by applying the albite and anorthite structures to the Na-rich and Ca-rich bands, respectively. The change of the superstructure of the e-plagioclase due to the compositional change has been described based on the movements of the satellites in reciprocal space. The direction of the coherent small-scale intergrowth of the anorthite-like and albite-like bands is perpendicular to the t vector. The thickness of the intergrowth is 1/|t|. Both direction and thickness change regularly from An₇₅ to An₂₅.     

Eutrophication and hypoxia in the upper Gulf of Thailand

In this study, we investigated the mechanism of eutrophication and hypoxia in the upper Gulf of Thailand from August 2014 to June 2015 based on field observation data, box model analysis, and the unscaled trophic status index (UNTRIX). Fresh water residence time derived from a simple box model was long (38.61 days) during the transition period between the southwest to northeast monsoon in September 2014. In contrast, fresh water residence time was short (2.63 days) during the late northeast monsoon in February 2015. Long residence time was related to the development of widespread strong hypoxia in near-bottom waters in over half of the gulf during the transition between the southwest and the northeast monsoon, when river discharge was also very large. UNTRIX is used to assess water trophic levels, and is based on water qualities including concentrations of chlorophyll-a (Chl-a), dissolved oxygen (DO), dissolved inorganic nitrogen (DIN), and dissolved inorganic phosphorus (DIP). Hypertrophic and eutrophic conditions were observed at river mouths; their seasonal eutrophication was related to river discharge and circulation. Nutrients were mainly increased by river discharge. Water column stratification and long residence time were required for the development of severe hypoxia in the study area.

     

Hypoxia in the Upper Gulf of Thailand: Hydrographic observations and modeling

We conducted hydrographic observations throughout the year to investigate seasonal variations of the hypoxic water mass distribution in the Upper Gulf of Thailand (UGoT). Hypoxic water masses were observed from June to November, with half of the UGoT occupied by hypoxic water in September. A hypoxic water mass appeared in the northeastern part of the UGoT in June and August, and moved westward over time. Low-salinity surface water moved from east to west as the rotational direction of surface circulation shifted with the reversal of monsoon winds. Westward movement of low-salinity water causes strong stratification in the northwestern part of the UGoT, leading to severe hypoxia. Numerical experiments showed high dissolved oxygen consumption rates around and offshore of river mouths, where hypoxic water is generated. This finding suggests that hypoxic water masses are transported to the south by physical processes. We examined how flooding affects hypoxic water mass formation. The volume of hypoxia in a flood year was approximately 2.5 times greater than in a normal year. In addition, hypoxia occurred in the dry season and extensive hypoxia was observed in the year after flooding. These results suggest that the hypoxic water mass persists for a long time after flooding.

     

Spatial and Temporal Variation of a Cyclonic Eddy Detected Downstream of the Tsushima Islands in November 2007

Horizontal, vertical and temporal distribution of a cyclonic (counterclockwise) eddy, where biological productivity is high, downstream of the Tsushima Islands in the eastern channel of the Tsushima Straits in November 2007 was revealed using conductivity–temperature–depth and acoustic Doppler current profiler data. The eddy had a horizontal scale of approximately 40–60 km, and the accompanying baroclinic current was more than 15 cm s⁻¹ at the edge of the eddy. The island-induced cyclonic eddy moved east-northeastward at about 10 km day⁻¹ (∼10 cm s⁻¹) along the Tsushima Warm Current and was intensified by the barotropic instability in the current shear. The cyclonic eddy with high surface chlorophyll a concentrations intensified in the vicinity of the Tsushima Islands and was advected by the Tsushima Warm Current towards the southwestern Japan Sea.