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Hydrogen Isotopes of Glassy and Phyllosilicate Spherules in Al Rais (CR) and Orgueil (CI) Chondrites

The hydroxyl in phyllosilicate minerals is the most common occurrence of water in primitive meteorites. Direct hydrogen isotopic analysis of this water component using an ion microprobe has been made in some glassy or phyllosilicate spherules from the Al Rais (CR) and Orgueil (CI) chondrites. The spherules from Al Rais show large deuterium excesses (δD = +200 -+800‰) relative to terrestrial standards, whereas deuterium-enrichments in the spherules from Orgueil are much smaller (δD = +40 - +130‰). The phyllosilicate spherules are products of     

近年来我国GNSS电离层延迟精确建模及修正研究进展

空间电离层是影响全球卫星导航系统(GNSS)应用服务性能最棘手的误差源之一。近几十年来,随着地基/空基GNSS数据的日益丰富,国内外学者发展并提出了多种重要技术措施修正、削弱电离层延迟对各类GNSS用户导航定位的影响,取得了重要进展和成果。本文在系统总结GNSS空间电离层延迟影响修正研究成果的基础上,从电离层延迟信息精确提取、建模及误差分析、实时改正方法等几个方面,重点介绍了近年来我国在这一领域的主要研究进展情况。     

巨大撞击对地球演化的系统灾变效应

综述了巨大地外物体撞击事件对地球产生的一系列剧烈灾变效应，包括撞击事件诱发或产生的各类地质作用变化、古气候波动、古生物灭绝和古地磁倒转等。同时指出，全面深入地研究巨大撞击的灾变效应对认识地球演化和发展具有重要意义。     

Oxygen isotopic compositions of chondrules: Implications for evolution of oxygen isotopic reservoirs in the inner solar nebula

We review the oxygen isotopic compositions of minerals in chondrules and compound objects composed of a chondrule and a refractory inclusion, and bulk oxygen isotopic compositions of chondrules in unequilibrated ordinary, carbonaceous, enstatite, and Kakangari-like chondrites, focusing on data acquired using secondary ion mass-spectrometry and laser fluorination coupled with mass-spectrometry over the last decade. Most ferromagnesian chondrules from primitive (unmetamorphosed) chondrites are isotopically uniform (within 3–4‰ in Δ¹⁷O) and depleted in ¹⁶O (Δ¹⁷O>−7‰) relative to amoeboid olivine aggregates (AOAs) and most calcium–aluminum-rich inclusions (CAIs) (Δ¹⁷O<−20‰), suggesting that these classes of objects formed in isotopically distinct gaseous reservoirs, ¹⁶O-poor and ¹⁶O-rich, respectively. Chondrules uniformly enriched in ¹⁶O (Δ¹⁷O<−15‰) are exceptionally rare and have been reported only in CH chondrites. Oxygen isotopic heterogeneity in chondrules is mainly due to the presence of relict grains. These appear to consist of chondrules of earlier generations and rare refractory inclusions; with rare exceptions, the relict grains are ¹⁶O-enriched relative to chondrule phenocrysts and mesostasis. Within a chondrite group, the magnesium-rich (Type I) chondrules tend to be ¹⁶O-enriched relative to the ferrous (Type II) chondrules. Aluminum-rich chondrules in ordinary, enstatite, CR, and CV chondrites are generally ¹⁶O-enriched relative to ferromagnesian chondrules. No systematic differences in oxygen isotopic compositions have been found among these chondrule types in CB chondrites. Aluminum-rich chondrules in carbonaceous chondrites often contain relict refractory inclusions. Aluminum-rich chondrules with relict CAIs have heterogeneous oxygen isotopic compositions (Δ¹⁷O ranges from −20‰ to 0‰). Aluminum-rich chondrules without relict CAIs are isotopically uniform and have oxygen isotopic compositions similar to, or approaching, those of ferromagnesian chondrules. Phenocrysts and mesostases of the CAI-bearing chondrules show no clear evidence for ¹⁶O-enrichment compared to the CAI-free chondrules. Spinel, hibonite, and forsterite of the relict refractory inclusions largely retained their original oxygen isotopic compositions. In contrast, plagioclase and melilite of the relict CAIs experienced melting and ¹⁶O-depletion to various degrees, probably due to isotopic exchange with an ¹⁶O-poor nebular gas. Several igneous CAIs experienced isotopic exchange with an ¹⁶O-poor nebular gas during late-stage remelting in the chondrule-forming region. On a three-isotope diagram, bulk oxygen isotopic compositions of most chondrules in ordinary, enstatite, and carbonaceous chondrites plot above, along, and below the terrestrial fractionation line, respectively. Bulk oxygen isotopic compositions of chondrules in altered and/or metamorphosed chondrites show evidence for mass-dependent fractionation, reflecting either interaction with a gaseous/fluid reservoir on parent asteroids or open-system thermal metamorphism. Bulk oxygen isotopic compositions of chondrules and oxygen isotopic compositions of individual minerals in chondrules and refractory inclusions from primitive chondrites plot along a common line of slope of 1, suggesting that only two major reservoirs (gas and solids) are needed to explain the observed variations. However, there is no requirement that each had a permanently fixed isotopic composition. The absolute (²⁰⁷Pb–²⁰⁶Pb) and relative (²⁷Al–²⁶Mg) chronologies of CAIs and chondrules and the differences in oxygen isotopic compositions of most chondrules (¹⁶O-poor) and most refractory inclusions (¹⁶O-rich) can be interpreted in terms of isotopic self-shielding during UV photolysis of CO in the initially ¹⁶O-rich (Δ¹⁷O−25‰) parent molecular cloud or protoplanetary disk. According to these models, the UV photolysis preferentially dissociates C¹⁷O and C¹⁸O in the parent molecular cloud and in the peripheral zones of the protoplanetary disk. If this process occurs in the stability field of water ice, the released atomic ¹⁷O and ¹⁸O are incorporated into water ice, while the residual CO gas becomes enriched in ¹⁶O. During the earliest stages of evolution of the protoplanetary disk, the inner solar nebula had a solar H₂O/CO ratio and was ¹⁶O-rich. During this time, AOAs and the ¹⁶O-rich CAIs and chondrules formed. Subsequently, the inner solar nebula became H₂O- and ¹⁶O-depleted, because ice-rich dust particles, which were depleted in ¹⁶O, agglomerated outside the snowline (5 AU), drifted rapidly towards the Sun and evaporated. During this time, which may have lasted for 3 Myr, most chondrules and the ¹⁶O-depleted igneous CAIs formed. We infer that most chondrules formed from isotopically heterogeneous, but ¹⁶O-depleted precursors, and experienced isotopic exchange with an ¹⁶O-poor nebular gas during melting. Although the relative roles of the chondrule precursor materials and gas–melt isotopic exchange in establishing oxygen isotopic compositions of chondrules have not been quantified yet, mineralogical, chemical, and isotopic evidence indicate that Type I chondrules may have formed in chemical and isotopic equilibrium with nebular gas of variable isotopic composition. Whether these variations were spatial or temporal are not known yet.     

Three-dimensional ionospheric tomography by an improved algebraic reconstruction technique

An improved algebraic reconstruction technique (IART) is presented for the tomographic reconstruction of ionospheric electron density (IED). This method applies the total electron content (TEC) measurements to invert the spatial distribution of the IED from a set of apriori IED distributions. In this new method, a data-driven adjustment of the relaxation parameter is performed to improve the computation efficiency and image quality of the classical algebraic reconstruction technique (ART). In addition, the new algorithm is also combined with ionospheric space discretization technique to simplify the inversion of IED, and it applies CHAMP occultation data to improve the vertical resolution. A numerical simulation experiment is carried out to validate the reliability of the new method. It is then applied to the inversion of IED from real GPS data. Inverted results show that the IART algorithm has better accuracy and efficiency than the conventional ART algorithm. The reliability of the IART algorithm is also validated by ionosonde data recorded at Wuhan station.     

一种无须变换参考星的GNSS单基线卡尔曼滤波算法

处理单基线全球导航卫星系统观测数据可获取位置、时间、大气延迟等信息,其应用包括相对定位、时频传递等。为实现实时性,常采用卡尔曼滤波递归地估计各类参数;为确保可靠性,还需形成一组独立的双差模糊度,并将其正确地固定为整数。实践中,滤波函数模型较常采用双差观测方程(即双差滤波模型)。若在当前历元原先的参考星不再可视时,双差滤波模型则需要定义新的参考星,并"映射"双差模糊度预报值以确保滤波连续。此外,双差滤波模型所计算的接收机相位钟差估值吸收了对应于参考星的站间单差模糊度,因此当参考星变换后可能会发生"整周跳跃"。在仍将双差模糊度作为一类可估参数的前提下,本文推导出以站间单差观测方程为滤波函数模型的算法(单差滤波模型),并证明了其与双差滤波模型具备理论上的等价性和实施上的差异性。与双差滤波模型相比,单差滤波模型不再需要"映射"双差模糊度预报值等运算,从而具备了更高的计算效率和灵活性;单差滤波模型所提供的接收机相位钟差估值也不受"整周跳跃"的影响,因此特别有利于频率传递应用。     

GNSS非差非组合数据处理与PPP-RTK高精度定位

本文首先回顾了GNSS差分和组合数据处理的起源、特点和应用,并阐述了其在多频多模背景下的局限。然后,引出了非差非组合数据处理的诸多优势,介绍了构建满秩非差非组合函数模型的消秩亏方法。基于该方法,本文系统构建了系列非差非组合PPP-RTK模型,包括伪距加相位和仅用相位两大类。两类模型均考虑不同的大气约束而衍生出电离层加权、浮点和固定3种变体,且所有模型均顾及码分多址和频分多址两类系统。最后,本文测试分析了非差非组合PPP-RTK在无人船、无人机和农机应用中的动态定位性能。试验结果表明,3个场景下的模糊度首次固定时间均在10 s以内,模糊度固定成功率在96%以上,水平定位精度优于2 cm,高程定位精度优于5 cm。在Galileo+GPS+BDS三系统农机定位中,仅用相位PPP-RTK与伪距加相位PPP-RTK定位性能相当。与Galileo+GPS双系统定位相比,三系统PPP-RTK将模糊度首次固定时间从几百秒缩短至几秒,模糊度固定成功率从85%左右提升至99%以上,定位精度提升了30%左右。