Spectroscopic properties of Cr-doped melilite crystals

 Four kinds of Cr-droped melilite crystals, Ca₂MgSi₂O₇ (akermanite), CaAl₂SiO₇ (gehlenite), CaGa₂SiO₇ (Ga-gehlenite) and CaGa₂GeO₇ (GaGe-gehlenite), with different sizes of the sites for Cr ions to substitute, were grown in series, using both the CZ and FZ techniques. Although Cr⁴⁺ is regarded as a major species in melilites, the existence of Cr⁶⁺ in gehlenite is also suggested from the change in absorption spectra by annealing, and the dependence of distribution coefficient of Cr ions on growth atmosphere. Spectral peak shifts are not obvious if the host crystal field is altered in melilites, because the local environment of the sites for Cr ion is possibly changed by reforming the packing features of the host lattice. Received February 7, 1996 / Revised, accepted September 20, 1996     

Measurement of directional spectrum of wind waves using an array of wave detectors

A method is proposed to estimate the true directional spectrum of wind waves by making use of more than four wave detectors. The true spectrum of wind waves whose wave lengths lie between about 1.1 and 2.6 times the largest span between the wave gauges can be recovered with an error less than 0.5 %. An additional wave gauge with fixed maximum span extends its effectivity to shorter wave lengths, but does not effect the upper limit of wave length.The method is based on the fact that the spectrum estimated byBarber (1961) is connected with true directional spectrum by the Fredholm integral equation of the first kind if the wave component satisfies the dispersion relation. Solving the equation by using the Fourier series method, we can get true spectrum.     

A model on the mechanism of momentum transfer from turbulent atmosphere to water waves

Interaction between the turbulence and the wave-induced air disturbances is treated by use of the mass and momentum conservation equations and the rapid distortion assumption. Assuming the correlation functions of the velocity derivatives, growth rates of waves are calculated. The growth rate obtained for the reasonable values of parameters shows the agreement with that obtained in the laboratory experiment byKendall (1970) and in the field experiments.     

Interactions between mesoscale eddy variability and Indian Ocean dipole events in the Southeastern tropical Indian Ocean—case studies for 1994 and 1997/1998

Interannual modulation of mesoscale eddy activity at the intraseasonal timescale in the southeastern tropical Indian Ocean and its relation to the Indian Ocean dipole mode (IOD) events are investigated using results from a high-resolution ocean general circulation model. The model reproduces observed characteristics of the intraseasonal variability and its interannual modulation fairly well, with large variances of the intraseasonal variability during the 1994 and 1997/1998 IOD events. Large negative temperature anomaly off the coasts of Java and the Lesser Sunda Islands in boreal summer, due to seasonal variation and interannual anomaly, extended further to the east in 1994, and the associated strong Indonesian throughflow enhanced the baroclinic instability in the upper layer, generating anomalously large mesoscale eddy activity. The eddy heat transport, in turn, significantly affected decaying phase of the 1994 IOD event. On the other hand, the development of the cold region off the Java Island associated with the 1997/1998 IOD event occurred in boreal winter, causing weaker baroclinic instability and hence weaker eddy activity off Java. This led to little influence on the heat budget in the southeastern tropical Indian Ocean for the 1997/1998 IOD event.     

Mass distribution of Antarctic ordinary chondrites and the estimation of the fall-to-specimen ratios

Abstract— The cumulative mass distributions (mass range > 100 g) of each type of Japanese and U.S. Antarctic ordinary chondrites are compared with those of non-Antarctic falls and those obtained from the present-day flux of meteorites. The steeper slope of the mass distribution of Antarctic chondrites is indicative of the presence of several chondrite showers. The fall-to-specimen ratio of Antarctic ordinary chondrites larger than 100 g is about 1:2, indicating that half of them are shower components. The fall-to-specimen ratios of each group range from 1:1 to 1:6; those of the Japanese and U.S. Antarctic meteorite collections are 1:1 to 1:2 and 1:4 for H chondrites, 1:1 to 1:2 and 1:2 for L chondrites, and 1:2 and 1:6 for LL chondrites, indicating that the Japanese collection includes less abundant shower components than the U.S. collection. The fall-to-specimen ratios of each H4-6 and L4-6 type range from 1:1 to 1:4, and U.S. H6 and Japanese H4 have the low ratios of 1:4.     

Origin of ureilites inferred from a SIMS oxygen isotopic and trace element study of clasts in the Dar al Gani 319 polymict ureilite

Secondary ion mass spectrometer (SIMS) oxygen isotope analyses were performed on 24 clasts, representing 9 clast types, in the Dar al Gani (DaG) 319 polymict ureilite with precisions better than 1‰. Olivine-rich clasts with typical ureilitic textures and mineral compositions have oxygen isotopic compositions that are identical to those of the monomict ureilites and plot along the CCAM (Carbonaceous Chondrite Anhydrous Mineral) line. Other igneous clasts, including plagioclase-bearing clasts, also plot along the CCAM line, indicating that they were derived from the ureilite parent body (UPB). Thus, we suggest that some of the plagioclase-bearing clasts in the polymict ureilites represent the “missing basaltic component” produced by partial melting on the UPB.Trace element concentrations (Mg, K, Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Rb, Sr and Ba) in ureilitic plagioclase and glass from 13 clasts were obtained by using the SIMS high mass resolution method. The trace element contents of the plagioclase generally show monotonic variations with anorthite content (mol%) that are consistent with partial melting and fractional crystallization. Incompatible trace element concentrations (K, Ti, and Ba) are low and variable for plagioclase with An > 40, indicating that the parental magmas for some clasts were derived from a depleted source. We performed partial melt modeling for CI and CM precursor compositions and compared the results to the observed trace element (K, Ba, and Sr) abundances in the plagioclase. Our results indicate that (1) the UPB evolved from a alkali-rich carbonaceous chondritic precursor, (2) parent melts of porphyritic clasts could have formed by 5-20% equilibrium partial melting and subsequent fractional crystallization, and (3) parent melts of the incompatible trace element-depleted clasts could be derived from fractional melting, where low degree (<10%) partial melts were repeatedly extracted from their solid sources.Thus, both the oxygen isotopic and trace element compositions of the plagioclase bearing clasts in DaG-319 suggest that the UPB underwent localized low degree-partial melting events. The partial melts could have been repeatedly extracted from the precursor, resulting in the formation of the olivine-pigeonite monomict ureilites as the final residue.     

Interannual variations of the Hawaiian Lee Countercurrent induced by potential vorticity variability in the subsurface

Interannual variations of the Hawaiian Lee Countercurrent (HLCC) in the 2000s were investigated using satellite and Argo profiling float observations. The satellite-observed sea surface height shows that the geostrophic eastward current was anomalously strong to the west away from Hawaii in 2003 and 2005. However, the trade winds and the orographic wind curl dipole in the lee of Hawaii that drives the climatological mean HLCC were not particularly strong in these years, suggesting that the accelerations of the HLCC were not caused by the wind stress curl forcing around Hawaii and subsequent Rossby wave propagation. Using Argo observations, we found negative potential vorticity (PV) anomalies in the subsurface north of the HLCC in these 2 years. The pycnocline is lifted northward as low PV waters of different densities stack up in the vertical, and the HLCC is then accelerated via the thermal wind. The intensification and/or southward intrusion of the eastern subtropical mode water and subtropical mode water seem to have induced negative PV anomalies in 2003 and 2005, respectively. Using high-resolution ocean simulations, we confirmed the migrations of PV anomalies and their contributions to the HLCC accelerations. Although the HLCC is located away from the cores of major mode waters, our results suggest that interannual variations of the HLCC are affected by those of mode waters.     

Effects of Interannual Variability in the Eastern Indian Ocean on the Indonesian Throughflow

The influences of the large-scale interannual variations in the eastern Indian Ocean on the variability of the Indonesian throughflow are investigated by using an ocean general circulation model, driven by the ERS satellite winds from July 1992 to June 1997. The empirical orthogonal function (EOF) analysis of the simulated surface dynamic height variability captures two dominant modes on an interannual time scale, which are quite consistent with the available observations. The first mode indicates large amplitude in the western tropical Pacific and has a strong relation to the El Niño events, while the second EOF exhibits the large amplitude in the eastern Indian Ocean. The simulated net Indonesian throughflow shows an interannual variation of amplitude of about 15 Sv, with large transport from the Pacific to the Indian Ocean during 1994/95 and small transport during 1992 and 1997. It turns out that the net throughflow variation shows a high correlation with the second EOF mode (r = 0.51) for the whole five-year simulation. On the other hand, the correlation with the first mode is rather low (r = ?0.07). However, the relative importance of the EOF modes to the throughflow variability changes with time. The upper-layer transport above a depth of 230 m in the Indonesian archipelago is also affected by the second mode. The difference in the upper-layer transport across 1°S and 110°E generates warm water convergence/divergence with a magnitude of 4 Sv within the Indonesian Seas on the interannual time scale, which shows good correspondence with sea surface temperature variation averaged over the Indonesian archipelago.