A catalytic oxidation method for the determination of total nitrogen dissolved in seawater

A detailed examination of a high-temperature catalytic oxidation method for liquid samples in the analysis of total nitrogen dissolved in seawater is reported. The nitrogenous compounds in liquid samples are oxidized on a platinum catalyzer at 680°C under oxygen atmosphere and the generated NO₂ is absorbed into a chromogenic reagent, followed by a spectrophotometric determination. The results of this method are much higher than those of wet oxidation methods. Molecular size dependency of the results clearly indicates that the above discrepancy is caused by the low oxidation capacity of the wet oxidation method against high-polymer organic matter dissolved in seawater. The results revealed that the concentration of total nitrogen in seawater is nearly constant from surface to bottom, ranging from 30 to 40 μM 1^?1, which organic nitrogen concentration higher in the surface layer, and a rapid decrease with depth. An examination of molecular size distribution indicates that the concentration of high-polymer organic nitrogen decreases rapidly from surface to deeper layers, with molecular sizes ranging from 5 × 10³ to 3 × 10⁴. Because of the well-defined principle of the oxidation process, its reliability, ease of sample handling and of analytical procedure on board or in the land laboratory, the present method is much more suitable for the marine analytical chemistry of total and organic nitrogen than the other previous methods.     

A numerical investigation of eddy-induced chlorophyll bloom in the southeastern tropical Indian Ocean during Indian Ocean Dipole—2006

An eddy-resolving coupled physical–biological model is used to study the effect of cyclonic eddy in enhancing offshore chlorophyll-a (Chl-a) bloom in the southeastern tropical Indian Ocean during boreal summer–fall 2006. The results demonstrate that the offshore Chl-a blooms are markedly coincident with the high eddy kinetic energy. Moreover, the vertical variations in Chl-a, nitrate, temperature, and mixed-layer depth (MLD) strongly imply that the cyclonic eddies induce surface Chl-a bloom through the injection of nutrient-rich water into the upper layer. Interestingly, we found that the surface bloom only occurs when the deep Chl-a maximum is located within the MLD. On the other hand, the response of subsurface Chl-a to the eddy pumping is remarkable, although it is hardly observable at the surface.     

Sharing the results of a high-resolution ocean general circulation model under a multi-discipline framework—a review of OFES activities

Quasi-global, eddy-resolving ocean general circulation model experiments, so-called OFES (ocean general circulation model for the Earth Simulator) project, have been conducted with a basic concept of sharing results among scientists in a multi-discipline framework. Studies using such OFES results extend widely from the physical aspects of ocean circulations and energy considerations to biogeochemical tracer distributions and marine ecosystem dynamics. This article reviews the OFES activities during a period from 2004 to 2009 and highlights some interesting scientific results that emerged from the OFES project. Future plans of the project are also presented.     

Impacts of the South China Sea Throughflow on seasonal and interannual variations of the Indonesian Throughflow

Impacts of the South China Sea Throughflow (SCST) on seasonal and interannual variations of the Indonesian Throughflow are studied by comparing outputs from ocean general circulation model (OGCM) experiments with and without the SCST. The observed subsurface maximum in the southward flow through the Makassar Strait is simulated only when the SCST, which is driven by the large-scale wind, is allowed in the model. The mean volume and heat transport by the Makassar Strait Throughflow are reduced by 1.7 Sv and 0.19 PW, respectively, by the existence of the SCST in the model. The difference is particularly remarkable during boreal winter when the SCST reaches its seasonal maximum. Furthermore, the SCST is strengthened during El Niño, leading to the weakening in the southward volume and heat transport through the Makassar Strait by 0.37 Sv and 0.05 PW, respectively. These findings from the OGCM experiments suggest that the SCST may play an important role in climate variability of the Indo-Pacific Ocean.     

MJO change with A1B global warming estimated by the 40-km ECHAM5

This study estimates MJO change under the A1B greenhouse gas emission scenario using the ECHAM5 AGCM whose coupled version (ECHAM5/MPI-OM) has simulated best MJO variance among fourteen CGCMs. The model has a horizontal resolution at T319 (about 40 km) and is forced by the monthly evolving SST derived from the ECHAM5/MPI-OM at a lower resolution of T63 (about 200 km). Two runs are carried out covering the last 21 years of the twentieth and twenty-first centuries. The NCEP/NCAR Reanalysis products and observed precipitation are used to validate the simulated MJO during the twentieth century, based on which the twenty-first century MJO change is compared and predicted. The validation indicates that the previously reported MJO variances in the T63 coupled version are reproduced by the 40-km ECHAM5. More aspects of MJO, such as the eastward propagation, structure, and dominant frequency and zonal wavenumber in power spectrum, are simulated reasonably well. The magnitude in power, however, is still low so that the signal is marginally detectable and embedded in the over-reddened background. Under the A1B scenario, the T63 ECHAM5/MPI-OM projected an over 3 K warmer tropical sea surface that forces the 40-km ECHAM to produce wetter tropics. The enhanced precipitation variance shows more spectral enhancement in background than in most wavebands. The zonal winds associated with MJO, however, are strengthened in the lower troposphere but weakened in the upper. On the one hand, the 850-hPa zonal wind has power nearly doubled in 30–60-days bands, demonstrating relatively clearer enhancement than the precipitation in MJO with the warming. A 1-tailed Student’s t test suggests that most of the MJO changes in variance and power spectra are statically significant. Subject to a 20–100-days band-pass filtering of that wind, an EOF analysis indicates that the two leading components in the twentieth-century run have a close structure to but smaller percentage of explained-to-total variance than those in observations; the A1B warming slightly increases the explained percentage and alters the structure. An MJO index formed by the two leading principal components discloses nearly doubling in the number of prominent MJO events with a peak phase occurring in February and March. A composite MJO life cycle of these events favors the frictional moisture convergence mechanism in maintaining the MJO and the nonlinear wind-induced surface heat exchange (WISHE) mechanism also appears in the A1B warming case. On the other hand, the Slingo index based on the 300-hPa zonal wind discloses that the upper-level MJO tends to be suppressed by the A1B warming, although the loose relationship with ENSO remains unchanged. Possible cause for the different change of MJO in the lower and upper troposphere is discussed.     

Constraining paleo-latitude of a biogeographic boundary in mid-Panthalassa: Fusuline province shift on the Late Guadalupian (Permian) migrating seamount

The Guadalupian paleo-atoll limestone (Iwato Formation) in SW Japan was primarily formed in low-latitude mid-Panthalassa and was later tectonically accreted to South China (Japan) margin during the Jurassic. The present biostratigraphic study clarified that the Iwato Formation consists of 5 biostratigraphical intervals; i.e. four fusuline assemblage zones (Assemblage zones 1 to 4) and a barren interval on the top. Assemblage zones 1 to 4 correspond to the Neoschwagerina craticulifera Zone, N. margaritae Zone, Yabeina globosa Zone, and Lepidolina multiseptata Zone of the conventional Tethyan fusuline stratigraphy, respectively. The present study newly clarified the following significant aspects of paleobiogeography of the Permian fusulines as to the extinction of large-tested taxa in the latest Guadalupian. 1) The long unknown stratigraphic relationship was documented for the first time between the Yabeina-dominant interval and the overlying Lepidolina-dominant one within a single limestone unit. 2) The occurrence of Lepidolina cf. kumaensis Kanmera, the unique last runner of large-tested fusuine, was detected for the first time in mid-oceanic paleo-atoll limestones. 3) With respect to the northbound migration history of the paleo-seamount capped by the Iwato Formation, the development of the two coeval fusuline biogeographic territories in the low-latitude Panthalassa, i.e., the Yabeina territory on the south and the Lepidolina territory on the north, was confirmed. 4) The paleo-latitude of the biogeographic boundary between the Yabeina and Lepidolina territories is constrained around 12° in the southern hemisphere on the basis of the latest geomagnetic data from the same limestone. This new approach utilizing biostratigraphy on ancient migrating seamounts coupled with geomagnetic paleo-latitude data is applicable to other cases in different time-space co-ordinates and of other fossil groups for constraining position of ancient biogeographic boundaries within lost oceanic domains of deep past.     

Accuracy of quantized Voronoi diagrams

Quantization of spatial objects, which usually means vector‐to‐raster conversion in GIS and remote sensing, is a basic operation used for handling spatial data from data creation to visualization. Since quantization is an approximation of spatial objects, it inevitably yields errors in measuring their properties such as area, perimeter, diameter, and so forth. This paper discusses the accuracy of a quantized Voronoi diagram, a spatial tessellation generated from a set of points. A measure is proposed to evaluate the accuracy of the area of Voronoi regions calculated after quantization. In one‐dimensional space the measure is expressed as an explicit function of the expected number of generators in a cell. In two‐dimensional space, on the other hand, the measure is defined by an implicit function, whose approximation is derived in an explicit form. These functions permit us to evaluate the accuracy of quantization in relation to the size of lattice cells and the density of Voronoi generators. This leads to an appropriate choice of a lattice to keep the quality of a quantized Voronoi diagram at a desirable level.     

Analysis of the appearance and disappearance of point objects over time

The appearance and disappearance of immovable points are important spatiotemporal events in geographical information science. They represent phenomena such as the birth and death of trees in forests, construction and destruction of buildings in cities and openings and closures of shops and restaurants. This paper proposes a new method for analyzing the appearance and disappearance of points. The method helps analysts capture the overall picture and regional variation of event pattern and detecting significant local patterns. Four measures are defined that indicate the intensity of spatial and temporal patterns of events. The measures are visualized as grid maps. A statistical test is used to evaluate the significance of the measures to extract the regions of significant patterns. The proposed method is applied in an analysis of shops and restaurants in Shibuya, Tokyo. Technical soundness of the method is discussed along with empirical findings.     

Comparative Measurements Of Co2flux Over A Forest Using Closed-Path And Open-Path Co2analysers

An eddy covariance system using a closed-path CO₂analyser was constructed for long-term CO₂flux measurements above a forest, and its total frequency response was valuated experimentally. The amplitude and phase responses of the system wereexamined through a preliminary test, in which a prescribed pattern of CO₂fluctuation was input to the system. The result showed that the amplitude of the output from the system was attenuated as frequency increased, with a half-power frequency of 0.3 Hz. The phase was delayed by the air sampling through a long tube, but the delay in phase decreased asfrequency increased. We then presented a new technique for the correction of flux loss due to the inadequate system response for the eddy covariance measurements of CO₂ flux. Using the present system and the correction technique, diurnal variations in CO₂ flux were measured over a temperate deciduous forest on three days in 1997. The results were compared with the CO₂fluxes measured with a fast response open-path gas analyser. The CO₂fluxes from the closed-path system agreed with those from the open-path system after the Webb, Pearman and Leuning correction was made for the latter. In the present test over a forest, the contribution of the frequency-response correction to the CO₂fluxes was small and its averaged percentage was only 3%in the daytime. However, the percentage would likely increase, if the system were applied to a shorter vegetation site where high frequency components are more important. The comparison confirmed that we can obtain correct measurements of CO₂flux using the present closed-path system and the correction technique.     

Number of Polygons Generated by Map Overlay: The Case of Convex Polygons

This paper analyzes the number of polygons generated by map overlay. Overlay of maps yields a number of small polygons, and often causes problems in computation, handling, and storage of derived polygons. One method to deal with these problems is to estimate the number of derived polygons before executing overlay operation. To this end, a stochastic model is proposed by which the expected number of derived polygons is calculated. The results are summarized as follows: (1) the number of polygons generated by map overlay depends on the number of original polygons and their perimeters; (2) the number of derived polygons increases with the perimeters of original polygons; (3) McAlpine and Cook's (1971) earlier method underestimated the number of derived polygons; and (4) the number of polygons generated by the overlay of maps having the same lattice system is proportional to the square of the number of overlaid maps and the number of polygons on the map, and inversely proportional to the area-perimeter ratio of the unit cell.