The composition and concentration of dissolved free amino acid (DFAA) of seawater samples collected in May 2016 from the surface to the hadal zone of the northern region of the Yap Trench were analyzed by pre-column derivatization of o-phthalaldehyde. Results show that the average concentration of DFAA in the study area was 0.47±0.36 µmol/L. In different sampling stations, the concentrations of DFAA with water depth showed complex variation patterns. At the sediment-seawater interface, the concentrations of DFAA in the western side of the trench were obviously higher than that in its eastern side. In the study area, there were no significant correlations between the concentrations of DFAA and the environmental parameters such as concentrations of chlorophyll a (Chl a), dissolved oxygen (DO), pH, and dissolved inorganic nitrogen (DIN), indicating that the concentrations of DFAA in seawater of the trench are affected by many factors, such as photosynthesis, respiration, temperature, pressure, illumination, and circulation. The dominant DFAA are similar in different water layers of sampling stations, including aspartic acid (Asp), glutamic acid (Glu), glycine (Gly), and serine (Ser). The composition of different amino acids, and the relative abundance of acidic, basic, and neutral amino acids might be related to the sources and consumption of various amino acids. Nine pairs of amino acids in the DFAA showed significantly positive relationship by correlation matrix analysis, suggesting that they might share similar biogeochemical processes. The degradation index (DI) of the DFAA in seawater of the Yap Trench could reflect the degradation, source, and freshness of DFAA in the trench to some extents. This is a preliminary study of amino acids from sea surface to hadal zone in the ocean, more works shall be done in different trenches to reveal their biogeochemical characteristics in extreme marine environments.
Laboratory flume experiments were done to investigate bed load sediment transport by both steady and unsteady flows in a degrading channel. The bed, respectively composed of uniform sand, uniform gravel, or sand-gravel mixtures, always undergoes bulk degradation. It is found that both uniform and non-uniform bed load transport is enhanced greatly by unsteady flows as compared to their volume-equivalent steady flows. This enhancement effect is evaluated by means of an enhancement factor, which is shown to be larger with a coarser bed and lower discharges. Also, the fractional transport rates of gravel and sand in non-uniform sand-gravel mixtures are compared with their uniform counterparts under both steady and unsteady flows. The sand is found to be able to greatly promote the transport of gravel, whilst the gravel considerably hinders the transport of sand. Particularly, the promoting and hindering impacts are more pronounced at lower discharges and tend to be weakened by flow unsteadiness. 相似文献
Although thin on the order of several to tens of millimeters, sheet flows normally comprise a lower pick-up sub-layer and an upper contact-load sub-layer, separated at the bed level (z = 0). The time-averaged concentration profile in the pick-up sub-layer shows a ‘convex upward’ curvature, but ‘concave upward’ shape characterizes the time-averaged concentration profile in the contact-load sub-layer. The time-dependent concentration in the contact-load sub-layer is approximately in-phase with the free stream flow velocity, whereas it is nearly in anti-phase with the free stream flow velocity in the pick-up sub-layer. Two distinct analytical expressions of the time-averaged concentration profiles for the respective sub-layers are proposed. The expressions are validated with detailed observation datasets collected in the Groβer Wellenkanal (GWK) prototype wave flume in Hannover, Germany. The agreement between the predicted and the measured values is excellent. Interparticle collisions in the pick-up sub-layer and convective lifting processes associated with vortex shedding in the contact-load sub-layer are considered responsible for the opposite curvatures and in-phase/anti-phase concentration variations. Both transitional boundary and reference concentration are also elaborated. 相似文献