Late Carboniferous porphyry copper mineralization at La Voluntad,Neuquén,Argentina: Constraints from Re–Os molybdenite dating

The La Voluntad porphyry Cu–Mo deposit in Neuquén, Argentina, is one of several poorly known porphyry-type deposits of Paleozoic to Early Jurassic age in the central and southern Andes. Mineralization at La Voluntad is related to a tonalite porphyry from the Chachil Plutonic Complex that intruded metasedimentary units of the Piedra Santa Complex. Five new Re–Os molybdenite ages from four samples representing three different vein types (i.e., quartz–molybdenite, quartz–sericite–molybdenite and quartz–sericite–molybdenite ± chalcopyrite–pyrite) are identical within error and were formed between ~312 to ~316 Ma. Rhenium and Os concentrations range between 34 to 183 ppm and 112 to 599 ppb, respectively. The new Re–Os ages indicate that the main mineralization event at La Voluntad, associated to sericitic alteration, was emplaced during a time span of 1.7 ± 3.2 Ma and that the deposit is Carboniferous in age, not Permian as previously thought. La Voluntad is the oldest porphyry copper deposit so far recognized in the Andes and indicates the presence of an active magmatic arc, with associated porphyry style mineralization, at the proto-Pacific margin of Gondwana during the Early Pennsylvanian.     

Observations of estuarine circulation and solitary internal waves in a highly energetic tidal channel

Despite vigorous tidal and wind mixing, observations in an estuarine tidal inlet in the Wadden Sea show that during part of the tidal cycle, vertical stratification and internal waves may still develop. Acoustic Doppler current profiler (ADCP) and conductivity, temperature, depth observations, collected over the past 6 years at 13 h anchor stations (ASs), reveal that these occur especially during slack tide, when there is little wind and large freshwater discharge from nearby Lake IJssel. Measurements with a moored ADCP show that in the same tidal phase, strong cross-channel circulation develops, which may suddenly reverse circulation sense due to passing density fronts. In the vertically stratified phase that follows after the front passage, propagating mode-one solitary internal waves are observed. These are resonantly generated during decelerating tidal ebb currents when the (shear) flow passes a transcritical regime (Froude number equal to 1). A combination of photographs (including one from the International Space Station), bathymetric data, and ASs data leads to the discovery of yet another source of internal waves in this area, produced during slackening tide by propagating lee waves that develop over a deep trench. We suggest that both the cross-channel circulation as well as the (solitary) internal waves may locally be of importance for the (re)distribution and transport of sediments and nutrients and may influence tidally averaged transports.     

An Improved Approach for Parameterizing Surface-Layer Turbulent Transfer Coefficients in Numerical Models

Based on classic iterative computation results, new equations to calculate the surface turbulent transfer coefficients are proposed, which allow for large ratios of the momentum and heat roughness lengths. Compared to the Launiainen scheme, our proposed scheme generates results closer to classical iterative computations. Under unstable stratification, the relative error in the Launiainen scheme increases linearly with increasing instability, even exceeding 15%, while the relative error of the present scheme is always less than 8.5%. Under stable stratification, the Launiainen scheme uses two equations, one for 0 < Ri _B ≤ 0.08 and another for 0.08 < Ri _B ≤ 0.2, and does not consider the condition that Ri _B > 0.2, while its relative errors in the region 0 < Ri _B ≤ 0.2 exceed 31 and 24% for momentum and heat transfer coefficients, respectively. In contrast, the present scheme uses only one equation for 0 < Ri _B ≤ 0.2 and another equation for Ri _B > 0.2, and the relative error of the present scheme is always less than 14%.     

The structure of the mid- and high-latitude ionosphere during the November 2004 storm event obtained from GPS observations

GPS data from the International GNSS Service (IGS) network were used to study the development of the severe geomagnetic storm of November 7–12, 2004, in the total electron content (TEC) on a global scale. The TEC maps were produced for analyzing the storm. For producing the maps over European and North American sectors, GPS measurements from more than 100 stations were used. The dense network of GPS stations provided TEC measurements with a high temporal and spatial resolution. To present the temporal and spatial variation of TEC during the storm, differential TEC maps relative to a quiet day (November 6, 2004) were created. The features of geomagnetic storm attributed to the complex development of ionospheric storm depend on latitude, longitude and local time. The positive, as well as negative effects were detected in TEC variations as a consequence of the evolution of the geomagnetic storm. The maximal effect was registered in the subauroral/auroral ionosphere during substorm activity in the evening and night period. The latitudinal profiles obtained from TEC maps for Europe gave rise to the storm-time dynamic of the ionospheric trough, which was detected on November 7 and 9 at latitudes below 50°N. In the report, features of the response of TEC to the storm for European and North American sectors are analyzed.     

Lateral tidal mixing in the Antarctic marginal seas

Tidal mixing plays an important role in the modification of dense water masses around the Antarctic continent. In addition to the vertical (diapycnal) mixing in the near-bottom layers, lateral mixing can also be of relevance in some areas. A numerical tide simulation shows that lateral tidal mixing is not uniformly distributed along the shelf break. In particular, strong mixing occurs all along the Ross Sea and Southern Weddell Sea shelf breaks, while other regions (e.g., the western Weddell Sea) are relatively quiet. The latter regions correspond surprisingly well to areas where indications for cross-shelf exchange of dense water masses have been found. The results suggest that lateral tidal mixing may account for the relatively small contribution of Ross Sea dense water masses to Antarctic Bottom Water.     

The first field-based descriptions of pumping-induced saltwater intrusion and upconing

Development of the ideas about the equilibrium between freshwater and saline water has received considerable attention in the literature, but little has been written so far about the earliest scientific works about well salinization. Based on a review of the literature from the second half of the 19th century and the early 20th century, this historical note explores how insights into groundwater abstraction and saltwater intrusion developed, and examples of the earliest field studies are provided. Fundamental research was driven by the need for increasing water supply, but the progress of science did not lead to sustainable management practices everywhere. Research outcomes were shared between scientists of different countries, marking the beginning of coastal hydrogeology as a scientific specialization in the first decade of the 20th century.     

PLL Tracking Performance in the Presence of Oscillator Phase Noise

The tracking performance of a Phase Lock Loop (PLL) is affected by the influence of several error sources. In addition to thermal noise and dynamic stress error, oscillator phase noise can cause significant phase jitter which degrades the tracking performance. Oscillator phase noise is usually caused by two different effects: Allan deviation phase noise is caused by frequency instabilities of the receiver's reference oscillator and the satellite's frequency standard. It can be termed as system-inherent phase noise and is relevant for both static and dynamic applications. “External” phase noise, however, is caused by vibration and is a major problem for dynamic applications. In the context of this paper, both types of phase noise will be modeled and the resulting integrals will be evaluated for PLLs up to the third order. Besides, phase jitter induced by thermal noise and signal dynamics will also be discussed, thus providing all necessary formulas for analyzing the performance of a phase lock loop in case of different forms of stress. Since the main focus is centered on the effects of oscillator phase noise, the overall PLL performance is graphically illustrated with and without consideration of oscillator phase noise. © 2002 Wiley Periodicals, Inc.     

Experimental study of the mechanical properties of expansive soil with added nanomaterials

The main purpose of this paper is to describe ways to improve the microstructure of expansive soil by adding nanomaterials. Mechanical tests were done to explore the changes in shear strength and compression index of expansive soil that was modified by adding different amounts of two kinds of nanomaterials (nano-alumina and nano-silica). The test results show that adding 1.2% nano-alumina and about 2% nano-silica to expansive soil provides the optimal compression index. The test results show that adding 1.2% nano-alumina and about 1.5% nano-silica to expansive soil provides the optimal unconfined compression stress. Scanning electron microscopy of the microstructure of expansive soil modified by nanomaterials provided a deeper understanding of the effects of nanomaterials on improving expansive soil.     

Climate change and local adaptation strategies in the middle Inner Mongolia,northern China

According to records of 17 meteorological stations distributed in the study area, climate change of the middle Inner Mongolia in northern China was analyzed in this paper. Based on SPOT VGT data, combined with field investigation, local vegetation change was detected in the last 10 years. The results show that annual mean air temperature obviously rose, while precipitation slightly decreased in fluctuation in the study area during the last 50 years. Air temperature increasing rates are +0.318°C 10 year⁻¹ during 1960-2009 and +0.423°C 10 year⁻¹ during 1980–2009, while precipitation decreasing rates are −2.91 mm 10 year⁻¹ during 1960–2009. There were five different dry or wet periods from the 1960s to the 2000s in order, and the wetter 1990s and the drier 2000s changed dramatically in the study area. Local climate totally tend to warm–dry conditions during the last 50 years. According to coefficient of variation (Cv) of yearly growing-season cumulative NDVI value and yearly NDVI maximum in pixel scale, vegetation had experienced huge temporal and spatial variation during the last 10 years. Recently, frequent droughts and dust storms seriously affected local agriculture and grazing activities, and resulted in heavy economic loss, especially over the drought period of 1999–2001. Faced with those drought disasters accompanied with strong dust storms, the local authorities proposed the enclosing-transferring strategy and made great efforts to adapt overt climate change and improve environment, including making selective emigration, decreasing livestock numbers, fencing grasslands and building forage production bases with irrigation instruments and actively adjusting industry structure. However, some effects and potential problems of this adaptation strategy still need to be comprehensively assessed further in longer time scales and aimed at different sub-regions.