Different from previous studies on effect of weathering upon geochemical variation along a single weathered profile, this paper provides a new methodology validated by comparing a weathered outcrop samples and their stratigraphic counterpart un-weathered core samples in a nearby shallow borehole. This outcrop and borehole penetrated the Ordovician-Silurian Wufeng–Longmaxi shales, located in the same anticline structure in the northern part of Guizhou Province, Southern China. The mineral composition, major, trace and rare earth elements (REEs) composition and Rock-Eval parameters of outcrop and core samples were analyzed and compared. Organic matter (OM) was observed in the microscope and extracted for elements analysis. The results show that short-term weathering still has significant influence on OM, mineral and elemental composition of black shales. The elements composition shows the outcrop profile was moderately weathered. The REEs compositions do not alter much during weathering process and the REEs composition and their relative ratios still are valid for rock origin determination. The OM, mainly composed by graptolite and bitumen, even entering the highly-over thermal maturity, is still sensitive to the weathering with a systematic loss 30–50% of TOC along the outcrop profile, which suggests that the OM consumption is predominantly controlled by weathering duration and the distance from the weathering surface. In turn, OM has significant influence on the trace elements transportation behavior during weathering. Some trace elements associated with the OM such as V, Cr, Th, U, Ni and Co, change significantly in their absolute concentration during weathering, but their relative ratios do not necessarily change too much and might be still reliable proxies for paleo-environmental determination. The mobility of shale minerals during weathering is in the following order: plagioclase?>?potassium feldspar and dolomite >pyrite and OM. Short-term weathering can also result in considerable transportation of elements and significant variation of minerals content in black shale, which may pose potentially high environmental and engineering risk in the regions rich in black shale. 相似文献
Three-dimensional transient groundwater flow and saltwater transport models were constructed to assess the impacts of groundwater abstraction and climate change on the coastal aquifer of Tra Vinh province (Vietnam). The groundwater flow model was calibrated with groundwater levels (2007–2016) measured in 13 observation wells. The saltwater transport model was compared with the spatial distribution of total dissolved solids. Model performance was evaluated by comparing observed and simulated groundwater levels. The projected rainfalls from two climate models (MIROC5 and CRISO Mk3.6) were subsequently used to simulate possible effects of climate changes. The simulation revealed that groundwater is currently depleted due to overabstraction. Towards the future, groundwater storage will continue to be depleted with the current abstraction regime, further worsening in the north due to saltwater intrusion from inland trapped saltwater and on the coast due to seawater intrusion. Notwithstanding, the impact from climate change may be limited, with the computed groundwater recharge from the two climate models revealing no significant change from 2017 to 2066. Three feasible mitigation scenarios were analyzed: (1) reduced groundwater abstraction by 25, 35 and 50%, (2) increased groundwater recharge by 1.5 and 2 times in the sand dunes through managed aquifer recharge (reduced abstraction will stop groundwater-level decline, while increased recharge will restore depleted storage), and (3) combining 50% abstraction reduction and 1.5 times recharge increase in sand dune areas. The results show that combined interventions of reducing abstraction and increasing recharge are necessary for sustainable groundwater resources development in Tra Vinh province.
In displacement-based seismic design, inelastic displacement ratio spectra (IDRS) are particularly useful for estimating the maximum lateral inelastic displacement demand of a nonlinear SDOF system from the maximum elastic displacement demand of its counterpart linear elastic SDOF system. In this study, the characteristics of IDRS for near-fault pulse-type ground motions are investigated based on a great number of earthquake ground motions. The in? uence of site conditions, ratio of peak ground velocity (PGV) to peak ground acceleration (PGA), the PGV, and the maximum incremental velocity (MIV) on IDRS are also evaluated. The results indicate that the effect of near-fault ground motions on IDRS are signifi cant only at periods between 0.2 s - 1.5 s, where the amplifi cation can approach 20%. The PGV/PGA ratio has the most signifi cant in? uence on IDRS among the parameters considered. It is also found that site conditions only slightly affect the IDRS. 相似文献
In the present experiments, ethyl methanesulfonate (EMS) is used to treat blue-green alga Spirulina platensis. Results show that the chemical is a very effective mutagen on the species and some genetic changes, including morphological variation, different growth rate and greater resistance to low temperature, have been found, which may offer an efficient method for the strain breeding of Spirulina platensis. 相似文献