超声提取-固相萃取小柱净化-气相色谱法测定土壤中14种有机氯农药

对土壤中14种有机氯农药的超声提取技术和磺化、固相萃取小柱两种净化方法进行系统研究。结果表明,超声提取节省提取时间,提高分析效率;磺化法和固相萃取小柱法都有净化作用,但磺化法使样品中的艾氏剂、狄氏剂和异狄氏剂全部损失;固相萃取小柱净化当丙酮-正己烷淋洗液体积比为1∶9、淋洗液收集8 mL时回收率>90%,干扰最小。方法检出限为0.63~2.59μg/kg,精密度(RSD,n=7)为1.17%~14.66%,基体加标平均回收率为82.78%~106.94%。方法用于生态地球化学调查评价批量土壤样品的实际分析,检测结果满足评价工作需要。     

黔北下寒武统黑色岩系古地温及其指示意义

采用显微光度计测定黔北下寒武统牛蹄塘组黑色岩系固体沥青反射率平均为5.89%,按相关经验公式折算出来的镜质体反射率平均为4.123%,在迈维尔图解、Karwell图解、Hood图解上投点,结合干酪根和孢粉颜色指数法,推断黑色岩系的古地温为60～250℃。结合黄铁矿热电系数法和包裹体均一法测温值,认为黑色岩系属中、低温沉积成岩成矿作用,以低温沉积成岩成矿作用为主。"热"的来源为海底火山喷溢,含矿热卤水提供了丰富的有用元素。黑色岩系有机碳含量高,属好烃源岩,有机质成熟度高,热演化程度高,属过成熟。黑色岩系古地温的研究,对阐明黑色岩系的沉积、成岩和成矿条件具有重要意义。     

煤田三维地震资料解释的时深转换方法研究

时深转换是三维地震资料解释中提高勘探精度非常关键的一步。本文介绍了三种不同的时深转换方法及时深转换速度的求取,并分别用实例加以说明,阐述了如何根据不同的地质及地震地质条件,选择合适的时深转换方法,以达到最佳的勘探效果。     

济阳拗陷特殊生物降解油的初步研究

济阳拗陷草古100平19井奥陶系储层原油,饱和烃馏分均已损失殆尽,仅残余藿烷系列化合物;同时,芳烃馏分化合物也已损失殆尽,仅残余三芳甾烷系列化合物。上述芳烃化合物俱已损失殆尽的蚀变特征,在相关文献中的报道较为少见。原油中不受水洗作用影响的正构烷烃和不受生物降解作用影响的有机硫化合物(苯并噻吩和二苯并噻吩)均已损失殆尽,显然暗示了原油蚀变是遭受水洗作用和生物降解作用共同作用的结果。原油芳烃馏分的“UCM”鼓包幅度明显大于饱和烃馏分的“UCM”鼓包,暗示了芳烃化合物的降解速率平行甚至超过饱和烃的降解速率。原油中低分子量芳烃化合物的快速降解,暗示了油藏可能是在氧化条件下而非在还原条件下发生蚀变的。     

Impact assessment of the "Grain for Green Project" and discussion on the development models in the mountain-gorge regions

To restore China’s degraded ecological environment, the government has launched an environmental restoration project named the “Grain for Green Project” (GGP) in 1999. From 1999 to 2010, the government will spend 40 billion dollars to convert 147 million ha of croplands and 173 million ha of wastelands into forestlands and grasslands in 25 provinces, municipalities and autonomous regions. A primary goal is to replace cropping and livestock grazing in fragile areas with trees and grass. Given the tremendous scale and great number of participants in the project, the attitudes of the affected farmers and the future development in the area where GGP is implemented have a direct influence on the success of the project. To gain a clear idea about the farmers’ attitudes towards the project and put forward the development models for the forestlands converted from croplands, two case sites in the mountain-gorge region in Nujiang River are selected as the study areas, and the methods of field survey and semi-structured interview are adopted to make interviews with more than 100 households in 2002 and 2003 in order to quantify the farmers’ opinions about the GGP and how it has affected their livelihood, socio-cultural and industrial structures, etc. The results are as follows: 1) the project has a certain influence on the farmers with better economic basis and exerts greater influence on the farmers living in the low-elevation regions than on those living in the regions with middle-high elevation; 2) the production models of the local farmers has changed from cultivation and animal husbandry to forestry and sidelines due to the project and the income structure has changed from animal husbandry as main income source to state subsidy and sideline as main income sources; 3) the reduction in the grain income and decrease in the quantity of livestock because of the project have led to the diminution in the total income of the farmers; 4) the project has resulted in changes in the lifestyles and architecture styles of the local farmers, and the traditional “huotang” culture has gone away after the implementation of the project; 5) energy utilization has changed from firewood to methane and electricity in the wake of the implementation of the project. The above-mentioned study results have indicated that the GGP has truly exerted influence on the livelihood and production of the local farmers. Therefore, it is very necessary to make a research into the development models in the forestlands converted from croplands to resolve the problems of the farmers’ livelihood and production. The study results will provide some references for the sustainable development of the mountain-gorge regions.     

滇东南中三叠统法郎组锰矿床成因的新认识

产于滇东南中三叠世拉丁期法郎组地层中的锰矿床,锰矿石出现氧化锰矿与碳酸盐锰矿混合存在现象,没有明显的变质现象,为沉积成因。矿石中一般都含有生物碎屑。我们对采自这一地区的斗南、岩子脚、老乌,土基冲等典型矿床的锰矿石样品,进行了系统的薄片显微镜和扫描电镜观察,同时应用X射线衍射对矿石矿物成份作了相应分析。观察到这些矿石中的鲕、豆状结构是由蓝绿藻类微生物凝聚作用形成的显微叠层构造,具有核形石特有的核心和包壳,其明—暗纹层相间的显微结构特征可以与现代深海大洋铁锰结核相类比。本文通过对核形石显微结构特征的观察和对锰矿物生成时介质环境的讨论,初步研究结果表明,锰矿形成可能位于古氧化还原界面附近,该区锰的富集可能与微生物活动密切相关。     

陕西省泾惠渠灌区土壤重金属地质累积指数评价

通过对陕西省泾惠渠灌区现场调查及土壤样品的采集,分析了灌区土壤中Hg、Cd、Cr、Pb、As、Cu、Zn等7种元素的含量,应用地质累积指数对灌区土壤进行了评价。结果表明：从区域分布看,阎良区、临潼区、高陵县所属采样点污染较严重;Hg污染最严重,地质累积指数为1.007～3.117,58%的采样点级别为3级,属中度污染到强污染,38%的采样点级别为2级,属中度污染;Zn污染程度次之,地质累积指数为-0.407～1.644,71%的采样点级别为1级,属无污染到中污染;Cd污染变异程度最大,地质累积指数为-2.705～3.312,70%的采样点级别0级,属无污染,但个别采样点达到了强污染;Cu的地质累积指数为-0.535～0.421,Pb为-1.119～-0.144,Cr为-1.005～-0.458,As为-0.562～0.077,除个别点外这些重金属污染级别皆为0级,属无污染。     

宁芜地区三个辉长岩的全岩和矿物Rb-Sr等时线年龄

 从南京到芜湖有许多辉长岩体分布,如南京蒋庙岩体、高古山岩体、大栏杆岩体,马鞍山阳湖塘岩体,当涂姑山岩体和芜湖市区的辉长岩体等。     

铅离子污染对桂林红黏土力学性质影响的试验研究

桂北地区铅锌矿产资源的开采对红黏土土层产生了不同程度的污染,为研究铅离子污染对桂林红黏土力学性质的影响,对其重塑样进行三轴不固结不排水剪切试验,测试获得了不同铅离子浓度、作用时间、围压下的应力-应变关系曲线、弹性模量、抗剪强度参数的变化规律。研究结果表明：铅离子污染对桂林重塑红黏土的力学性质有着显著的影响,随着铅离子浓度的增加,土体力学性质随之衰减,并在浓度最大值（1.0%）时达到最低;铅离子污染红黏土应力-应变曲线均呈硬化型,但是随着铅离子浓度的增大,以及围压的增大,其硬化的趋势均有所减弱;弹性模量、抗剪强度随着浓度的变化有着明显的衰减,但是抗剪强度参数在所选的作用时间梯度内其变化并不明显,说明铅离子污染能够在较短时间内完成对土体结构的主体破坏。     

Comparison of linear and nonlinear shallow wave water equations applied to tsunami waves over the China Sea

This paper discusses the applications of linear and nonlinear shallow water wave equations in practical tsunami simulations. We verify which hydrodynamic theory would be most appropriate for different ocean depths. The linear and nonlinear shallow water wave equations in describing tsunami wave propagation are compared for the China Sea. There is a critical zone between 400 and 500 m depth for employing linear and nonlinear models. Furthermore, the bottom frictional term exerts a noticeable influence on the propagation of the nonlinear waves in shallow water. We also apply different models based on these characteristics for forecasting potential seismogenic tsunamis along the Chinese coast. Our results indicate that tsunami waves can be modeled with linear theory with enough accuracy in South China Sea, but the nonlinear terms should not be neglected in the eastern China Sea region.