Nutrient and metal accumulation in a freshwater tidal marsh

Stratigraphic records from sediment cores collected in a freshwater tidal marsh and in the estuary upstream and downstream from the marsh were used to determine the accumulation of nutrients and trace metals over long time periods. Analysis of pollen and seeds show that the high marsh has formed only within the past 100 yr, following increased sedimentation rates in the area. Variations in nutrient and trace metal accumulations over several decades show that pollutants from agricultural runoff and wastewater discharge are stored to a greater extent in high-marsh than in low-marsh sediments. Greater accumulation rates in the high marsh are probably related to its greater sedimentary organic carbon concentration.     

Physiographic analysis for small scale soil and landuse mapping of Mewat area,Haryana, using LANDSAT imagery

Visual interpretation of LANDSAT imagery of 1∶250,000 scale (band 5 and 7) and 1∶1 M (FCC) covering 1611 km² in Mewat area, Haryana was carried out for delineating the physiographic units. The physiographic units viz. hills, piedmont plain, intermontane basin and Yamuna alluvial plain were identified and delineated using interpretation elements. Soils and land use in relation to the physiographic units were studied during the field visit and are described in the paper.     

Adsorption of diethyl and dibutyl phthalates onto activated carbon produced from <Emphasis Type="Italic">Albizia julibrissin pods:</Emphasis> kinetics and isotherms

The adsorption behavior study of diethyl and dibutyl phthalates was investigated onto a new activated carbon prepared from an abundant biomass “Albizia julibrissin pods,” treated chemically by H₃PO₄. A series of experiments were conducted in a batch system to estimate the effect of operating conditions such as the adsorbent nature, the dose of adsorbent, the contact time, the initial concentration and the temperature on the adsorption efficiency. The optimum operating conditions were found to be 0.1 and 0.05 g of adsorbent for diethyl and dibutyl phthalates, respectively, at 30 min equilibrium time, 150 mg g^?1 and 293 K. The adsorption isotherms for both phthalates were fit at different temperatures using the nonlinear regression of Langmuir, Freundlich, Dubinin–Radushkevich and Redlich–Peterson. The pseudo-first order, pseudo-second order by nonlinear regression and intraparticle diffusion models were used to describe the adsorption kinetic. The results show that the intraparticle diffusion model is not the limiting step governing the adsorption mechanism. The structural and textural characteristics of adsorbent surface were investigated. FTIR analysis of unloaded and phthalates-loaded adsorbent revealed that the aliphatic groups attached to phthalate esters are involved in adsorption mechanism.     

Hydrologic responses to land cover change: the case of Jedeb mesoscale catchment,Abay/Upper Blue Nile basin,Ethiopia

The objective of this study was to quantify the impacts of land use/land cover (LULC) change on the hydrology of the Jedeb, an agricultural dominated mesoscale catchment, in the Abay/Upper Blue Nile basin, Ethiopia. Two methods have been used. First, the trends of certain daily flow variability parameters were evaluated to detect statistical significance of the change of the hydrologic response. Second, a conceptual monthly hydrological model was used to detect changes in the model parameters over different periods to infer LULC change. The results from the statistical analysis of the daily flows between 1973 and 2010 reveal a significant change in the response of the catchment. Peak flow is enhanced, i.e. response appears to be flashier. There is a significant increase in the rise and fall rates of the flow hydrograph, as well as the number of low‐flow pulses below a threshold level. The discharge pulses show a declining duration with time. The model result depicts a change in model parameters over different periods, which could be attributed to an LULC change. The model parameters representing soil moisture conditions indicated a gradual decreasing trend, implying limited storage capacity likely attributed to increasing agricultural farming practices in the catchment. This resulted in more surface runoff and less infiltration into the soil layers. The results of the monthly flow duration curve analysis indicated large changes of the flow regime. The high flow has increased by 45% between the 1990s and 2000s, whereas the reduction in low flows was larger: a 15% decrease between 1970s and 1980s, 39% between 1980s and 1990s and up to 71% between 1990s and 2000s. These results, could guide informed catchment management practices to reduce surface runoff and augment soil moisture level in the Jedeb catchment. Copyright © 2013 John Wiley & Sons, Ltd.     

Modeling the sediment yield from landslides in the Shihmen Reservoir watershed,Taiwan

Landslides generate enormous volumes of sediment in mountainous watersheds; however, quantifying the downstream transport of landslide‐derived sediment remains a challenge. Landslide erosion and sediment delivery to the Shihmen Reservoir watershed in Taiwan was estimated using empirical landslide frequency–area and volume–area relationships, empirical landslide runout models, and the Hydrological Simulation Program‐ FORTRAN (HSPF). Landslide erosion rates ranged from 0.4 mm yr^‐1 to 2.2 mm yr^‐1 during the period 1986–2003, but increased to 7.9 mm yr^‐1 following Typhoon Aere in 2004. The percentage of landslide sediment delivered to streams decreased from 78% during the period 1986–1997 to 55% in 2004. Although the delivery ratio was lower, the volume of landslide sediment delivered to streams was 2.81 × 10⁶ Mg yr^‐1 in 1986–1997 and 8.60 × 10⁶ Mg yr^‐1 in 2004. Model simulations indicate that only a small proportion of the landslide material was delivered downstream. An average of 13% of the landslide material delivered to rivers was moved downstream during the period 1986–1997. In 2004, the period including Typhoon Aere, the annual fluvial sediment yield accounted for approximately 23% of the landslide material delivered to streams. In general, the transfer of sediment in the fluvial system in the Shihmen Reservoir watershed is dominantly transport limited. The imbalance between sediment supply and transport capacity has resulted in a considerable quantity of landslide material remaining in the upper‐stream regions of the watershed. Copyright © 2012 John Wiley & Sons, Ltd.     

The geometrical and fractal properties of visible radiances associated with breaking waves in the ocean

We consider the natural processes of wind-wave-breaking in the ocean in terms of fractal dimension. Digital algorithms for the analysis of aircraft optical images are employed to investigate spatial and statistical characteristics of foam streaks and whitecaps. The new results are as follows: 1. the fractal dimension of the wave-breaking set (foam streaks and whitecaps) depends on the ocean surface state and changes from d_H=1.05 to 1.25; 2. the fractal dimension differs from foam streaks and whitecaps - d_s=1.23 and 1.39, respectively.     

Assessment of Trace Metal Contamination of Drinking Water in the Pearl Valley,Azad Jammu and Kashmir

The aim of this study was to assess trace metal contamination of drinking water in the Pearl Valley, Azad Jammu and Kashmir (Pakistan). The objectives were to determine physical properties and the dissolved concentration of five trace metals, i. e., lead, copper, nickel, zinc, and manganese, in drinking water samples collected from various sites of municipal water supply, natural water springs and wells in the valley. Concentrations of the metals in the water samples were determined by flame atomic absorption spectrometry. Results showed physical parameters, i. e., appearance, taste and odor within acceptable limits and pH was between 5.5 and 7.0. The observed concentrations of the metals varied between sources of water samples and between sampling sites. Maximum dissolved concentration observed was 4.7 mg/L for Pb and Mn, 4.6 mg/L for Zn, 2.9 mg/L for Ni and 2.8 mg/L for Cu. The observed concentrations of the metals were compared with the World Health Organization's guideline values for drinking water. Overall, the quality of water samples taken from the water springs at Mutyal Mara and Bonjosa was good; however, the water quality was unsuitable for drinking in Kiraki, Kharick, and Pothi Bala localities particularly. Finally, the authors discuss possible causes for increased concentrations of the trace metals in drinking water in the study area.