Converted-wave seismology in anisotropic media revisited,Part I: Basic theory

We have developed new basic theories for calculating the conversion point and the travel time of the P-SV converted wave (C-wave) in anisotropic, inhomogeneous media. This enables the use of conventional procedures such as semblance analysis, Dix-type model building and Kirchhoff summation, to implement anisotropic processing, and makes anisotropic processing affordable. Here we present these new developments in two parts: basic theory and application to velocity analysis and parameter estimation. This part deals with the basic theory, including both conversion-point calculation and moveout analysis. Existing equations for calculating the PS-wave (C-wave) conversion point in layered media with vertical transverse isotropy (VTI) are strictly limited to offsets about half the reflector depth (an offset-depth ratio, xlz, of 0.5), and those for calculating the C-wave traveltimes are limited to offsets equal to the reflector depth (x/z=l.0). In contrast, the new equations for calculating the conversion-point extend into offsets about three-times the reflector depth (x/z=3.0), those for calculating the C-wave traveltimes extend into offsets twice the reflector depth (x/z=2.0). With the improved accuracy, the equations can help in C-wave data processing and parameter estimation in anisotropic, inhomogeneous media. This work is funded by the Edinburgh Anisotropy Project (EAP) of the British Geological Survey. First author: Xiangyang Li, Mr. Li is currently a professorial research seismologist (Grade 6) and technical director of the Edinburgh Anisotropy Project in the British Geological Survey. He also holds a honorary professorship in multicomponent seismology at the School of Geosciences, University of Edinburgh. He received his BSc(1982) in Geophysics from Changchun Geological Institute, China, an MSc (1984) in applied geophysics from East China Petroleum Institute (now known as the China University of Petroleum), and a PhD (1992) in seismology from the University of Edinburgh. During 1984–1987, he worked as a lecturer with the East China Petroleum Institute. Since 1991, he has been employed by the British Geological Survey. His research interests include seismic anisotropy and multicomponent seismology.     

Assessing the Comparability of Ammonium,Nitrate and Sulfate Concentrations Measured by Three Air Quality Monitoring Networks

Airborne fine particulate matter across the United States is monitored by different networks, the three prevalent ones presently being the Clean Air Status and Trend Network (CASTNet), the Interagency Monitoring of PROtected Visual Environment Network (IMPROVE) and the Speciation and Trend Network (STN). If combined, these three networks provide speciated fine particulate data at several hundred locations throughout the United States. Yet, differences in sampling protocols and samples handling may not allow their joint use. With these concerns in mind, the objective of this study is to assess the spatial and temporal comparability of the sulfate, nitrate and ammonium concentrations reported by each of these networks. One of the major differences between networks is the sampling frequency they adopted. While CASTNet measures pollution levels on seven-day integrated samples, STN and IMPROVE data pertain to 24-hour samples collected every three days. STN and IMPROVE data therefore exhibit considerably more short-term variability than their CASTNet counterpart. We show that, despite their apparent incongruity, averaging the data with a window size of four to six weeks is sufficient to remove the effects of differences in sampling frequency and duration and allow meaningful comparison of the signals reported by the three networks of concern. After averaging, all the sulfate and, to a lesser degree, ammonium concentrations reported are fairly similar. Nitrate concentrations, on the other hand, are still divergent. We speculate that this divergence originates from the different types of filters used to collect particulate nitrate. Finally, using a rotated principal component technique (RPCA), we determined the number and the geographical organization of the significant temporal modes of variation (clusters) detected by each network for the three pollutants of interest. For sulfate and ammonium, the clusters’ geographical boundaries established for each network and the modes of variations within each cluster seem to correspond. RPCA erformed on nitrate concentrations revealed that, for the CASTNet and IMPROVE networks, the modes of variation do not correspond to unified geographical regions but are found more sporadically. For STN, the clustered areas are unified and easily delineable. We conclude that the possibility of jointly using the data collected by CASTNet, IMPROVE and STN has to be weighed pollutant by pollutant. While sulfate and ammonium data show some potential for joint use, at this point, combining the nitrate data from these monitoring networks may not be a judicious choice.     

Observed Evolution of Linear and Nonlinear Effects at the Dahan Downhole Array,Taiwan: Analysis of the September 21, 1999 M 7.3 Chi-Chi Earthquake Sequence

— In this paper, the site characteristics of the Dahan downhole array are studied by analyzing the September 21, 1999 M 7.3 Chi-Chi earthquake sequence including the main shock and some aftershocks. The four-level array (0 m, 50 m, 100 m and 200 m) is located to the north of Hualien City in eastern Taiwan. Polarization analysis is used to check the orientation errors of the seismometers at different levels of depth. If the surface instrument is chosen as reference, the angle between the major polarization axes of the surface and any downhole records is the orientation error that must be corrected for the downhole accelerographs. The orientation errors at depths of 50 m, 100 m and 200 m are 32°, 120° and –84°. After the corrections, the coherency between the surface and downhole records is substantially improved. Spectral ratio analysis shows that the predominant frequency of the Chi-Chi main shock shifts to a lower frequency. We also simulate ground motions at different depths by using the Haskell method with a linear velocity structure model. The record at surface is chosen as the input motion. Compared with the observed data, ground acceleration can be well reproduced for the aftershocks (weak-motion events) of the September 21, 1999 M 7.3 Chi-Chi earthquake. However, for the Chi-Chi main shock, the synthetic waveform cannot match well with the observation neither in amplitude nor in phase. This indicates that large ground shaking probably induced the nonlinear site effect at that time, and the model used cannot support it.Acknowledgement. The authors would like to express their thanks to Dr. L.F. Bonilla and one anonymous reviewer for their valuable suggestions. This research was supported by the National Science Council under grant number NSC 89-2921-M-194-007. The Institute of Earth Sciences, Academia Sinica supplied the strong-motion data. The support of these organizations is gratefully acknowledged.     

致密砂岩的形成机制及其地质意义——以塔里木盆地英南2井为例

砂质岩的孔隙和喉道被网格状粘土矿物和次生加大矿物充填成微细孔喉状结构时,形成具有较高毛细管压力的致密砂岩。它与地层水发生水锁效应,可大大降低渗透率,成为致密砂岩盖层。当含水饱和度在50%以下时,束缚水饱和度比较低,致密砂岩储层可以产气;当含水饱和度在50%～90%区间时,具有较高的束缚水饱和度,相对渗透率非常低,它既不能产气也不能产水,反映为渗透率瓶颈区(具有盖层性质);当含水饱和度大于90%以上时,致密砂岩储层仅微量产水。塔里木盆地英南2井侏罗系气藏盖层由致密砂岩构成,不含水时的气体渗透率在(0.027～0.081)×10-3μm2,不能构成封堵;当含水饱和度达到60%以上时,相对渗透率几乎为零,构成有效盖层。     

Hydrogeochemistry of karst underground waters at shallow depth in Guiyang City, Guizhou Province

The aim of this study is to shed light on the hydrogeochemical characteristics of karst underground waters at shallow depth in Guiyang City, Guizhou Province with an emphasis on the geochemistry of major elements. Guiyang City bears abundant underground waters and it is also an important representative of the karst areas throughout the world. Ca^2 and Mg^2 are the dominant cations, accounting for 81% -99.7% of the total, and HCO3^- and SO4^2- are the dominant anions. Weathering of limestones and dolostones is the most important factor controlling the hydrogeochemistry of underground waters, and weathering of sulfate and evaporite rocks is less important. Moreover, the precipitation and human activities also have a definite influence on the hydrogeoehemistry of underground waters in the region studied.     

海南博螯沿岸地貌与人类活动的潜在影响

The Boao coastal system along the eastern coast of Hainan Island is a dynamic delta-tidal inlet-barrier formed during the late Holocene. The delta developed inside a shallow lagoon barred by a sandy barrier with a narrow, shallow tidal inlet opening. Two major distributary channels separated by small islands characterize the delta. The lagoon is silting up receiving and trapping sediments from both the river and, in minor measure during storms, through the tidal inlet opening and barrier washovers. The barrier at the tidal inlet is highly dynamic and changes its form, accreting (migrating spit) against the inlet during fair-weather conditions and being eroded during storms and river floods.The delta has almost completely filled the lagoon and major concerns exist on the effect that ongoing large development plans may have on the environment. These concerns include the effect on floods and rate of siltation once banks of the islands have been stabilized and floodwater and sediment load are impeded from spreading over the lowlands, and the effect of increasing pollutant loads from the new facilities on the ecosystems of the increasingly restricting lagoon water and on the seashores.     

Analysis on Bearing Capacity of Tunnel-Type Anchorage of a Long-Span Suspension Bridge

INTRODUCTION Tunnel typeanchoragehasobviousadvantages inbearingcapacityversusinvestment(LiuandHu,1996).However,itisrarelyusedinapracticalpro jectbecauseofitsrequirementofgoodrockcondi tions.Siduhebridge(Fig.1),whichliesintheBa dongmountainsinthewestplatea…     

A high-resolution TEM-AEM, pH titration, and modeling study of Zn coprecipitation with ferrihydrite

Experiments of Zn²⁺ and Fe³⁺ coprecipitation as a function of pH were conducted in the laboratory at ambient temperature and pressure. X-ray diffraction patterns of the coprecipitates show two broad peaks at 0.149 and 0.258 nm, which is consistent with published patterns for pure 2-line ferrihydrite. Zn²⁺ uptake occurred at pH ≥5 while Fe³⁺ precipitation occurred between pH 3 and 4, although both Zn²⁺ and Fe³⁺ were present in the same solution during the entire range of pH titration. High-resolution transmission electron microscopy shows that the coprecipitates are 2 to 6 nm sized single crystalline particles but aggregated to 50 to 400 nm sized clusters. Analytical electron microscopy indicated that the 5% atomic Zn with respect to Fe was homogeneously distributed. No segregated phases were found in the clusters or at single crystal edges, which is consistent with published extended X-ray absorption fine structure (EXAFS) results at similar Zn/(Zn + Fe) ratios. Hence, occlusion and surface precipitation may be excluded as possible coprecipitation mechanisms. The bulk solution Zn²⁺ sorption edge was fitted to both solid solution and generalized diffuse layer surface complexation models. However, a solid solution model is inconsistent with published EXAFS results that show tetrahedral polydentate Zn²⁺ complexes sharing apices with Fe³⁺octahedra.