Geochemical and hydrodynamic constraints on the distribution of trace metal concentrations in the lagoon of Nouméa, New Caledonia

Seawater samples were collected in the lagoon of Nouméa (southwest New Caledonia) along two transects from eutrophic coastal bays to the oligotrophic barrier reef. Land-based emissions to the lagoon were measured with dissolved and particulate concentrations of chromium (Cr) and nickel (Ni), used as tracers of both terrigenous and industrial (Ni ore treatment) activities, as well as dissolved and particulate concentrations of zinc (Zn), used as a tracer of urban effluents. The spatial variability of metal concentrations was related to geochemical and hydrodynamic conditions, i.e., respectively: (1) natural and anthropogenic emission sources, and chemical processes occurring in the water column; and (2) water residence times. The parameter used to describe the residence time of water masses was the local e-flushing time, i.e. the time required for a tracer mass contained within a given station to be reduced by a factor 1/e. High metal concentrations were found in coastal areas (up to 9000 ng dissolved Ni L⁻¹), and steeply decreased with distance from the coast (down to 101 ng dissolved Ni L⁻¹ near the barrier reef) to reach levels similar to those found in remote Pacific waters, suggesting a rapid renewal of waters close to the barrier. Distributions of metals in the lagoon are controlled upstream by land-based emission sources and later chemical processes. Then hydrodynamics constrain metal distributions, as shown by the observed relationship between local e-flushing times and the spatial variability of metal concentrations. In addition, a change in the direction of prevailing winds yielded a decrease of dissolved metal concentrations at the same site by a factor of 2.5 (Cr and Ni) and 2.9 (Zn). It is suggested that the residence time is a key parameter in the control of elemental concentrations in the lagoon waters, as much as land-based emission sources.     

Sea,freshwater or saltpans? Foraging ecology of terns to assess mercury inputs in a wetland landscape: The Ebro Delta

The Ebro catchment, the largest river basin in Spain, includes various heavily industrialized areas. Among these is the Flix site, where a chemical plant has been operating since the beginning of the 20th century. This extended operational period, together with the construction of a dam next to the factory around 1960, resulted in the accumulation of large amounts of heavily polluted sediments in the adjacent riverbed, many of which are contaminated by mercury. Pollutants from Flix are carried downstream by the Ebro River to its delta. In order to assess the transfer of mercury to the complex river estuary ecosystem, we studied the ecology of the tern community living there as these birds segregate into a range of habitats. For this purpose, first we used stable isotope analysis (SIA) (δ³⁴S, δ¹³C, δ¹⁵N) of eggs to determine the trophic ecology and habitat partitioning of several tern species (Common, Sandwich, Little, Gull-Billed and Whiskered Tern) breeding sympatrically, in order to link their foraging ecology with habitat types. Next we measured mercury concentrations in eggs to monitor the input of this metal into the diverse habitats. With the exception of the Little Tern, the other terns used a restricted habitat range in the Ebro Delta, as shown by C and S isotopes; the Gull-Billed and Whiskered Tern foraged in freshwater habitats, while the Common and Sandwich Tern used marine habitats. This restricted feeding behavior of the Gull-Billed and Common Tern contrasts with previous reports in other breeding sites. The Little Tern, which showed a wide range of isotopic values, was found to be an opportunistic forager but fed mainly in saltpans, a feeding habitat not reported previously for this species in this area. We found that mercury concentrations are related to foraging habitat and diet, and are unexpectedly higher in species feeding on demersal prey in marine habitats and also higher in birds feeding in saltpans than in those feeding in freshwater habitats. The mercury concentrations found in the Little and Common Tern eggs sampled in “Punta de la Banya” may be sufficiently high to endanger breeding success.     

Retracking considerations in spaceborne GNSS-R altimetry

The European Space Agency Passive Reflectometry and Interferometry System In-orbit Demonstrator (IoD) aims to perform mesoscale altimetric observations by measuring the Global Navigation Satellite System (GNSS) opportunity signals reflected over the sea surface. Altimetry based on GNSS reflectometry (GNSS-R) is significantly affected by satellite motion, since it requires relatively long integration times to reduce noise. We present the impact of the satellite motion on the GNSS-R observables and the need to retrack the waveforms. By using a detailed GNSS-R space mission simulator, the change of delay difference between the direct and the reflected signals during the incoherent averaging of the waveform has been investigated. Their effects on the waveform shape and the altimetric performance are presented comparing the aligned and non-aligned waveforms. Results show that the performance of spaceborne GNSS-R altimeter is seriously degraded without a proper alignment of the waveform samples.     

The electrical structure of the Slave craton

The Slave craton in northwestern Canada, a relatively small Archean craton (600×400 km), is ideal as a natural laboratory for investigating the formation and evolution of Mesoarchean and Neoarchean sub-continental lithospheric mantle (SCLM). Excellent outcrop and the discovery of economic diamondiferous kimberlite pipes in the centre of the craton during the early 1990s have led to an unparalleled amount of geoscientific information becoming available.

Over the last 5 years deep-probing electromagnetic surveys were conducted on the Slave, using the natural-source magnetotelluric (MT) technique, as part of a variety of programs to study the craton and determine its regional-scale electrical structure. Two of the four types of surveys involved novel MT data acquisition; one through frozen lakes along ice roads during winter, and the second using ocean-bottom MT instrumentation deployed from float planes.

The primary initial objective of the MT surveys was to determine the geometry of the topography of the lithosphere–asthenosphere boundary (LAB) across the Slave craton. However, the MT responses revealed, completely serendipitously, a remarkable anomaly in electrical conductivity in the SCLM of the central Slave craton. This Central Slave Mantle Conductor (CSMC) anomaly is modelled as a localized region of low resistivity (10–15 Ω m) beginning at depths of 80–120 km and striking NE–SW. Where precisely located, it is spatially coincident with the Eocene-aged kimberlite field in the central part of the craton (the so-called “Corridor of Hope”), and also with a geochemically defined ultra-depleted harzburgitic layer interpreted as oceanic or arc-related lithosphere emplaced during early tectonism. The CSMC lies wholly within the NE–SW striking central zone defined by Grütter et al. [Grütter, H.S., Apter, D.B., Kong, J., 1999. Crust–mantle coupling; evidence from mantle-derived xenocrystic garnets. Contributed paper at: The 7th International Kimberlite Conference Proceeding, J.B. Dawson Volume, 1, 307–313] on the basis of garnet geochemistry (G10 vs. G9) populations.

Deep-probing MT data from the lake bottom instruments infer that the conductor has a total depth-integrated conductivity (conductance) of the order of 2000 Siemens, which, given an internal resistivity of 10–15 Ω m, implies a thickness of 20–30 km. Below the CSMC the electrical resistivity of the lithosphere increases by a factor of 3–5 to values of around 50 Ω m. This change occurs at depths consistent with the graphite–diamond transition, which is taken as consistent with a carbon interpretation for the CSMC.

Preliminary three-dimensional MT modelling supports the NE–SW striking geometry for the conductor, and also suggests a NW dip. This geometry is taken as implying that the tectonic processes that emplaced this geophysical–geochemical body are likely related to the subduction of a craton of unknown provenance from the SE (present-day coordinates) during 2630–2620 Ma. It suggests that the lithospheric stacking model of Helmstaedt and Schulze [Helmstaedt, H.H., Schulze, D.J., 1989. Southern African kimberlites and their mantle sample: implications for Archean tectonics and lithosphere evolution. In Ross, J. (Ed.), Kimberlites and Related Rocks, Vol. 1: Their Composition, Occurrence, Origin, and Emplacement. Geological Society of Australia Special Publication, vol. 14, 358–368] is likely correct for the formation of the Slave's current SCLM.     

Active spreading and hydrothermalism in North Fiji Basin (SW Pacific). Results of Japanese French Cruise Kaiyo 87

The aim of the Japanese-French Kaiyo 87 cruise was the study of the spreading axis in the North Fiji Basin (SW Pacific). A Seabeam and geophysical survey allowed us to define the detailed structure of the active NS spreading axis between 16° and 22° S and its relationships with the left lateral motion of the North Fiji Fracture Zone. Between 21° S and 18°10′ S, the spreading axis trends NS. From 18°10 S to 16°40 S the orientation of the spreading axis changes from NS to 015°. North of 16°40′ S the spreading axis trends 160°. These two 015° and 160° branches converge with the left lateral North Fiji fracture zone around 16°40′ S to define an RRFZ triple junction. Water sampling, dredging and photo TV deep towing give new information concerning the hydrothermal activity along the spreading axis. The discovery of hydrothermal deposits associated with living communities confirms this activity.     

Quantitative Analysis of Micro-structural Changes in a Bituminous Coal After Exposure to Supercritical CO2 and Water

Natural Resources Research - High-volatile bituminous coal samples were reacted in deionized water with supercritical CO2 (ScCO2–water) under simulated in situ pressure and temperature...     

Youth Mobility and Territorial Disparities: An Analysis of Urban and Rural Barcelona

Travel behavior of the present generation of youths is being increasingly explored due to their relevance in shaping future accessibility needs and mobility habits. The present study offers an original perspective on this topic by identifying territorial disparities that emerge in youth mobility patterns in rural and urban areas. Unlike most previous research, we propose taking a global view on mobility by analyzing all trip purposes and transportation modes. This is conducted by analyzing a comprehensive mobility survey in the Barcelona Metropolitan Region, which provides data on mobility engagement, trip purposes, modal split, travel times and territorial differences. In general, youngsters account for larger daily travel times than older adults, present a higher attachment to public transportation and walk less on a daily basis. These differences are enhanced in rural territories, where while older adults overcome accessibility issues with higher use of the private vehicle, youngsters are more likely to invest larger travel times on transit.     

ITRF2008: an improved solution of the international terrestrial reference frame

ITRF2008 is a refined version of the International Terrestrial Reference Frame based on reprocessed solutions of the four space geodetic techniques: VLBI, SLR, GPS and DORIS, spanning 29, 26, 12.5 and 16?years of observations, respectively. The input data used in its elaboration are time series (weekly from satellite techniques and 24-h session-wise from VLBI) of station positions and daily Earth Orientation Parameters (EOPs). The ITRF2008 origin is defined in such a way that it has zero translations and translation rates with respect to the mean Earth center of mass, averaged by the SLR time series. Its scale is defined by nullifying the scale factor and its rate with respect to the mean of VLBI and SLR long-term solutions as obtained by stacking their respective time series. The scale agreement between these two technique solutions is estimated to be 1.05 ± 0.13 ppb at epoch 2005.0 and 0.049 ± 0.010?ppb/yr. The ITRF2008 orientation (at epoch 2005.0) and its rate are aligned to the ITRF2005 using 179 stations of high geodetic quality. An estimate of the origin components from ITRF2008 to ITRF2005 (both origins are defined by SLR) indicates differences at epoch 2005.0, namely: ?0.5, ?0.9 and ?4.7?mm along X, Y and Z-axis, respectively. The translation rate differences between the two frames are zero for Y and Z, while we observe an X-translation rate of 0.3?mm/yr. The estimated formal errors of these parameters are 0.2?mm and 0.2?mm/yr, respectively. The high level of origin agreement between ITRF2008 and ITRF2005 is an indication of an imprecise ITRF2000 origin that exhibits a Z-translation drift of 1.8?mm/yr with respect to ITRF2005. An evaluation of the ITRF2008 origin accuracy based on the level of its agreement with ITRF2005 is believed to be at the level of 1?cm over the time-span of the SLR observations. Considering the level of scale consistency between VLBI and SLR, the ITRF2008 scale accuracy is evaluated to be at the level of 1.2?ppb (8?mm at the equator) over the common time-span of the observations of both techniques. Although the performance of the ITRF2008 is demonstrated to be higher than ITRF2005, future ITRF improvement resides in improving the consistency between local ties in co-location sites and space geodesy estimates.     

Estimates of groundwater discharge to a coastal wetland using multiple techniques: Taylor Slough, Everglades National Park, USA

Quantifying water exchange between a coastal wetland and the underlying groundwater is important for closing water, energy and chemical budgets. The coastal wetlands of the Florida Everglades (USA) are at the forefront of a large hydrologic restoration project, and understanding of groundwater/surface-water interactions is needed to comprehend the effects of the project. Four independent techniques were used to identify water exchange at varying spatial and temporal scales in Taylor Slough, Everglades National Park. The techniques included a water-budget study and measurements of hydraulic head gradients, geochemical tracers, and temperature. During the 18-month study, the four methods converged as to the timing of groundwater discharge, typically between June and September, contemporaneous with the wet season and increasing surface-water levels. These results were unexpected, as groundwater discharge was predicted to be greatest when surface-water levels were low, typically during the dry season. Either a time lag of 1?C5?months in the response of groundwater discharge to low surface-water levels or precipitation-induced groundwater discharge may explain the results. Groundwater discharge was a significant contributor (27?%) to the surface water in Taylor Slough with greater rates of discharge observed towards the coastline in response to seawater intrusion.     

An improved spectral turning-bands algorithm for simulating stationary vector Gaussian random fields

We propose a spectral turning-bands approach for the simulation of second-order stationary vector Gaussian random fields. The approach improves existing spectral methods through coupling with importance sampling techniques. A notable insight is that one can simulate any vector random field whose direct and cross-covariance functions are continuous and absolutely integrable, provided that one knows the analytical expression of their spectral densities, without the need for these spectral densities to have a bounded support. The simulation algorithm is computationally faster than circulant-embedding techniques, lends itself to parallel computing and has a low memory storage requirement. Numerical examples with varied spatial correlation structures are presented to demonstrate the accuracy and versatility of the proposal.