Thermodynamic conditions of framework grain dissolution of clastic rocks and its application in Kela 2 gas field

Feldspar and clastic debris are the most important constituent framework grains of sedimentary clastic rocks and their chemical dissolution plays an essential role in the formation and evolution of the secondary pore in the reservoir rocks. On the basis of thermodynamic phase equilibrium, this study investigates the chemical equilibrium relationships between fluid and various plagioclase and K-feldspar in diagenesis of the sediments, particularly, the impact of temperature and fluid compositions (pH, activity of K+, Na+, Ca2+ and so on) on precipitation and dissolution equilibria of feldspars. Feldspar is extremely easily dissolved in the acid pore water with a low salinity when temperature decreases. The dissolution of anorthite end-member of plagioclase is related to the Ca content of the mineral and the fluid, higher Ca either in the mineral or in the fluid, easier dissolution of the feldspar. Moreover, the dissolution of albite end-member of plagioclase is related to Na of both the mineral and fluid,     

The lacustrine sedimentary records of coal-burning atmospheric pollution

With the acceleration of industrialization, coal- burning atmospheric pollution is getting more and more serious in many regions in China. However, there are only about ten odd years literature records about pollution in some large and mid-sized cities, where the atmosphere has perhaps been polluted for several decades, and therefore it is difficult to know the process and characteristic of pollution, and diffi-cult to evaluate its damage to environment. Lacustrine sediment, a natural record w…     

Analysis of Many-Year Variations in River Runoff into the Arctic Ocean

Statistical analysis of long-term hydrological observations has shown that the interannual variations in the total river runoff into the Arctic Ocean can be considered as a stationary process. Similar are the variations in the annual runoff of the Ob, Lena, and rivers of the northwestern Asia. However, some components of the total runoff into the Arctic Ocean feature distinct and fairly complicated disturbances in the homogeneity of runoff variations. For example, variations in the annual runoff of the Yenisei River have a distinct nonmonotonic trend: the runoff systematically decreased till the late 1950s and increased since the late 1960s. The rivers of the European part of the Arctic Ocean drainage basin featured a decrease in the amplitude of variations in runoff during the past decades. Rivers of the northwestern America and northeastern Asia featured a regular increase in the amplitude of runoff variations and their autocorrelation since the late 1960s.     

Ecotoxicological Assessment of After-Effects of the Volga River Water Contamination

Comprehensive assessment of ecotoxicological situation in the Volga River basin is presented. Concentrations of organic and inorganic toxic substances are cited. Basic clinic and postmortem symptoms of intoxication in fish are described; changes in the cellular structure of their organs and tissues, as well as disturbances in hemogenesis, developing under the effect of toxic agents, are characterized. Based on the dose-effect dependences, calculated according to the values of the total concentration of toxic substances, standardized to MPC, and criteria of the physiological state of fish, cases of exceedance of the critical concentrations of pollutants are demonstrated for the investigated river sections.__________Translated from Vodnye Resursy, Vol. 32, No. 4, 2005, pp. 410–424.Original Russian Text Copyright © 2005 by Moiseenko, Gashkina, Sharova, Pokoeva.     

Study of statistically correcting model CMAQ-MOS for forecasting regional air quality

Based on analysis of the air pollution observational data at 8 observation sites in Beijing including outer suburbs during the period from September 2004 to March 2005, this paper reveals synchronal and in-phase characteristics in the spatial and temporal variation of air pollutants on a city-proper scale at deferent sites; describes seasonal differences of the pollutant emission influence between the heating and non-heating periods, also significantly local differences of the pollutant emission influence between the urban district and outer suburbs, i.e. the spatial and temporal distribution of air pollutant is closely related with that of the pollutant emission intensity. This study shows that due to complexity of the spatial and temporal distribution of pollution emission sources, the new generation Community Multi-scale Air Quality (CMAQ) model developed by the EPA of USA produced forecasts, as other models did, with a systematic error of significantly lower than observations, albeit the model has better capability than previous models had in predicting the spatial distribution and variation tendency of multi-sort pollutants. The reason might be that the CMAQ adopts average amount of pollutant emission inventory, so that the model is difficult to objectively and finely describe the distribution and variation of pollution emission sources intensity on different spatial and temporal scales in the areas, in which the pollution is to be forecast. In order to correct the systematic prediction error resulting from the average pollutant emission inventory in CMAQ, this study proposes a new way of combining dynamics and statistics and establishes a statistically correcting model CMAQ-MOS for forecasts of regional air quality by utilizing the relationship of CMAQ outputs with corresponding observations, and tests the forecast capability. The investigation of experiments presents that CMAQ-MOS reduces the systematic errors of CMAQ because of the uncertainty of pollution emission inventory and improves the forecast level of air quality. Also this work employed a way of combining point and area forecasting, i.e. taking the products of CMAQ for a center site to forecast air pollution for other sites in vicinity with the scheme of model products "reanalysis" and average over the "area".     

Transformation of accommodation space of the Cretaceous Qingshankou Formation, the Songliao Basin, NE China

Analysis of accommodation space variation during deposition of the Cretaceous Qingshankou Formation in the Songliao Basin, NE China, indicates that accommodation space changed both through time and across the basin as a seesaw movement. The mid‐upper Qingshankou Formation is divided into three units. In each unit, changes of accommodation space differ in the southern and northern part of the basin. Increasing accommodation in the southern part is accompanied by a decrease in the northern part, and vice versa. Between the northern and southern basin, there was a neutral belt that is like a fulcrum, called the transformation belt here, where the accommodation did not change to any significant degree. We call this response ‘accommodation transformation’, whose characteristics are defined by tectonic subsidence analysis, palaeontological and sedimentary analyses. The accommodation increasing belt, decreasing belt, transformation belt and accommodation transformation boundary together constitute the accommodation transformation system. The recognition of accommodation transformation in the Songliao Basin provides a new insight into sequence stratigraphy and might be widely applicable.     

Analysis on Bearing Capacity of Tunnel-Type Anchorage of a Long-Span Suspension Bridge

INTRODUCTION Tunnel typeanchoragehasobviousadvantages inbearingcapacityversusinvestment(LiuandHu,1996).However,itisrarelyusedinapracticalpro jectbecauseofitsrequirementofgoodrockcondi tions.Siduhebridge(Fig.1),whichliesintheBa dongmountainsinthewestplatea…     

Analysis of pressuremeter geometry effects in clay using critical state models

The conventional interpretation methods of pressuremeter testing effectively approximate pressuremeter membranes as infinitely long. As a result, the effects of the two‐dimensional geometry of pressuremeters are ignored, leading to an overestimation of soil shear strength by pressuremeter testing, as demonstrated in several previous studies. This paper presents results of a numerical study of two‐dimensional geometry effects on self‐boring pressuremeter tests in undrained clay. The results are obtained using critical state soil models with an effective stress formulation. This is in contrast to most (if not all) existing studies on pressuremeter geometry effects, which were based on perfectly plastic soil models (e.g. Yu (Cavity expansion theory and its application to the analysis of pressuremeters. DPhil Thesis, The University of Oxford, 1990), Yeung and Carter (Proc. 3rd Int. Symp. on Pressuremeters, 1990), and Houlsby and Carter (Géotechnique, 1993; 43 (4):567–576)). The present study suggests that the overestimation of soil strength due to the neglect of finite pressuremeter length is significantly affected by the soil model used in the calculations. It is found that for clays with a high overconsolidation ratio (OCR) the strength overestimation predicted using critical state soil models could be considerably smaller than that predicted using perfectly plastic soil models. The main conclusion of this numerical study is that care must be exercised before directly applying any numerically determined pressuremeter geometry correction factors in practice. Copyright © 2005 John Wiley & Sons, Ltd.     

Pristine and reacted surfaces of pyrrhotite and arsenopyrite as studied by X-ray absorption near-edge structure spectroscopy

Fe L-, S L-, and O K-edge X-ray absorption spectra of natural monoclinic and hexagonal pyrrhotites, Fe_1-xS, and arsenopyrite, FeAsS, have been measured and compared with the spectra of minerals oxidized in air and treated in aqueous acidic solutions, as well as with the previous XPS studies. The Fe L-edge X-ray absorption near-edge structure (XANES) of vacuum-cleaved pyrrhotites showed the presence of, aside from high-spin Fe²⁺, small quantity of Fe³⁺, which was higher for a monoclinic mineral. The spectra of the essentially metal-depleted surfaces produced by the non-oxidative and oxidative acidic leaching of pyrrhotites exhibit substantially enhanced contributions of Fe³⁺ and a form of high-spin Fe²⁺ with the energy of the 3d orbitals increased by 0.3–0.8 eV; low-spin Fe²⁺ was not confidently distinguished, owing probably to its rapid oxidation. The changes in the S L-edge spectra reflect the emergence of Fe³⁺ and reduced density of S s–Fe 4s antibonding states. The Fe L-edge XANES of arsenopyrite shows almost unsplit e_g band of singlet Fe²⁺ along with minor contributions attributable to high-spin Fe²⁺ and Fe³⁺. Iron retains the low-spin state in the sulphur-excessive layer formed by the oxidative leaching in 0.4 M ferric chloride and ferric sulphate acidic solutions. The S L-edge XANES of arsenopyrite leached in the ferric chloride, but not ferric sulphate, solution has considerably decreased pre-edge maxima, indicating the lesser admixture of S s states to Fe 3d orbitals in the reacted surface layer. The ferric nitrate treatment produces Fe³⁺ species and sulphur in oxidation state between +2 and +4.     

Visual extinction towards the Omega Nebula (M17) and the ionization of nitrogen in the nebula

We estimate the absolute intensity of the Hα emission line in M17 based on spectroscopic observations with the 70 cm telescope of the Fesenkov Astrophysical Institute and the 1.25 m telescope of the Sternberg Astronomical Institute’s Crimean Laboratory. The visual extinction, A _v , is derived for about 250 regions in the nebula via a comparison of the optical (Hα) and radio (21 cm continuum) emissions. The A _v values for the eastern, optically bright, part of the nebula are 2–6^m. For the western part, which is covered by a dark cloud, the extinction is A _v = 7?14.5^m. We derived I(Hα)/I([NII] λ6584) ratios and estimated the degree of ionization of nitrogen in the nebula; we find that most nitrogen is in the [NIII] state.