Low-temperature thermodynamic properties of disordered zeolites of the natrolite group

 The heat capacity of paranatrolite and tetranatrolite with a disordered distribution of Al and Si atoms has been measured in the temperature range of 6–309 K using the adiabatic calorimetry technique. The composition of the samples is represented with the formula (Na_1.90K_0.22Ca_0.06)[Al_2.24Si_2.76O₁₀]·nH₂O, where n=3.10 for paranatrolite and n=2.31 for tetranatrolite. For both zeolites, thermodynamic functions (vibrational entropy, enthalpy, and free energy function) have been calculated. At T=298.15 K, the values of the heat capacity and entropy are 425.1 ± 0.8 and 419.1 ±0.8 J K⁻¹ mol⁻¹ for paranatrolite and 381.0 ± 0.7 and 383.2 ± 0.7 J K⁻¹ mol⁻¹ for tetranatrolite. Thermodynamic functions for tetranatrolite and paranatrolite with compositions corrected for the amount of extraframework cations and water molecules have also been calculated. The calculation for tetranatrolite with two water molecules and two extraframework cations per formula yields: C _p (298.15)=359.1 J K⁻¹ mol⁻¹, S(298.15) −S(0)=362.8 J K⁻¹ mol⁻¹. Comparing these values with the literature data for the (Al,Si)-ordered natrolite, we can conclude that the order in tetrahedral atoms does not affect the heat capacity. The analysis of derivatives dC/dT for natrolite, paranatrolite, and tetranatrolite has indicated that the water- cations subsystem within the highly hydrated zeolite may become unstable at temperatures above 200 K. Received: 30 July 2001 / Accepted: 15 November 2001     

East Asian monsoon instability at the stage 5a/4 transition

The physics involved in the abrupt climate changes of the late Quaternary have eluded paleoclimatologists for many years. More paleoclimatic records characteristic of different elements of the global climate system are needed for better understanding of the cause-feedback relationships in the system. The East Asian monsoon is an important part of the global climate system and the mechanical links between the East Asian monsoon and other climatic elements around the world may hold a key to our knowledge of abrupt climate changes in East Asia and probably over a larger part of the globe. Previous studies have detected millennial-scale winter monsoon oscillations during the last glaciation and probably also during the last interglaciation in loess sequences across China. However, less attention has been paid to the abrupt summer monsoon changes and the stage 5a/ 4 transition, an important period for the evolution of the East Asian monsoon when the global climate shifted towards the last glaciation. Here we report on two loess sections from eastern China which were dated using a thermoluminescence (TL) technique. The pedogenic and other sediment parameters suggest that the summer monsoon experienced a two-step abrupt retreat at the stage 5a/4 transition. The variations in the proxies for the winter monsoon are synchronized with the summer monsoon proxies during this brief interval, implying a direct and immediate link between high latitude and low latitude mechanisms. These changes may be correlated with similar climatic oscillations observed in the North Atlantic, Europe and Antarctica, raising the possibility that the forcing factors that induced these changes are global in extent.     

A Model for the polar motion of the deformable Earth adequate for astrometric data

Refined analytical expressions for the frequencies corresponding to the Chandler motion of the pole and the diurnal rotation of the deformable Earth are derived. Numerical estimates of the period and amplitude of the polar oscillations are presented. The trajectory of the Chandler polar motion derived via numerical modeling is in qualitative and quantitative agreement with experimental data from the International Earth Rotation Service (IERS). An evolutionary model describing slow variations in the Earth’s rotation parameters under the action of the dissipative moments of the tidal gravitational forces on time scales considerably longer than the precession period of the Earth’s axis is constructed. The axis of the Earth’s figure tends to approach the angular momentum vector of the proper rotation.     

人工值守台数字化地震仪标定原理

推导了人工台数字化地震仪的分段标定公式，提出数字化记录系统的微分近似标定和拾震器阻尼衰减法标定的方法，并提供了不同短周期地震仪与数字化地震仪并行的藕合方式和标定计算公式。     

山西夏县台热水井水氡异常特征与地震的关系初探

为弄清山西夏县中心地震台水氡震前异常的原因 ,对山西夏县中心地震台热水井水氡 1984年以来的观测资料用概率论的数据处理方法进行了处理 ,以负异常的发震原理进行了分析 ,结果表明震前负异常的发震概率为 70 %。     

圆弧状沉积盆地与软土单覆盖层出平面地表运动对比

采用解析方法，通过圆弧状沉积盆地与同样参数的软土均匀单覆盖层的对比，研究沉积盆地对平面SH波二维散射效应和其出平面地表运动。数值对比结果表明：（1）波垂直入射时盆地中央地表位移幅值反应，其随频率变化形式与软土单覆盖层的地表运动有较强的对应性，且此时单覆盖层地表位移幅值为其下降；（2）盆地的二维散射效应特点显著波的汇聚作用使盆地中的地表运动显著放大，总体上较软土单覆盖层的地表位移幅值要大，其频域内的最大反应则明显大于单覆盖层情况，但最大反应在盆地表面出现的位置依赖于入射波角度、盆地深宽比和盆地的软硬程度；（3）沉积盆地中地表位移运动有强烈扭转效应，且随盆地变软和入射波频率增高而增强。     

基于ODBC的地震前兆数据批量卸出与转换程序的实现

介绍了CDBC技术、工作流程及数据传递方式；分析了研制数据卸出与转换程序的关键技术及实现方法；描述了程序的组织结构。通过实例说明了该程序在全国前兆台网中心卸载与转换地震前兆数字化的观测数据中的应用。     

Mathematical modeling of PCB bioaccumulation in Perna viridis

In the present work, we built a mathematical model of polychlorinated biphenyl (PCB) bioaccumulation in Perna viridis, namely, a one-compartment model with a time dependent incorporation rate R (μg g⁻¹ lipid per ppb water per day), with positive substrate cooperativity as the underlying physical mechanism. The temporal change of the PCB concentration Q (μg g⁻¹ lipid) in the soft tissues of the mussel depends on the competition of the input rate RW and the output rate kQ, where W is the concentration of PCB in water (ppb water) and k is the elimination rate (per day). From our experimental data, k=0.181±0.017 d⁻¹. The critical concentration in water W_c for positive substrate cooperativity was found to be 2.4 ppb. Below W_c, R is a constant. For a water concentration of 0.5 ppb Aroclor 1254, R=24.0±2.4 μg g⁻¹ lipid ppb⁻¹ d⁻¹. Above W_c, positive substrate cooperativity comes into effect and R becomes a function of time and dependent on the concentration Q in a form R=γQ/(Q+δ). This is the case for a water concentration of 5 ppb Aroclor 1254, where γ=15.1 μg g⁻¹ lipid ppb⁻¹ d¹ and δ≈200 μg g⁻¹ lipid. From this model, the uptake is exponentially increasing when the PCB concentration in the mussel is small compared to 200 μg g⁻¹ lipid, and hyperbolically increasing when the concentration is large compared to 200 μg g⁻¹ lipid, which are consistent with the experimental data. The model is useful for understanding the true processes taking place during the bioaccumulation and for risk assessment with higher confidence. Future experimental data which challenge the present model are anticipated and in fact desirable for improvement and perfection of the model.     

Simultaneous radio and optical observations of the mid-latitude atmospheric response to a major geomagnetic storm of 6–8 April 2000

Basic properties of the mid-latitude traveling ionospheric disturbances (TIDs) during the maximum phase of a major magnetic storm of 6–8 April 2000 are shown. Total electron content (TEC) variations were studied by using data from GPS receivers located in Russia and Central Asia. The nightglow response to this storm at mesopause and termospheric altitudes was also measured by optical instruments FENIX located at the observatory of the Institute of Solar-Terrestrial Physics (51.9°N,103.0°E), and MORTI located at the observatory of the Institute of Ionosphere (43.2°N, 77.0°E). Observations of the O (557.7 and 630.0 nm) emissions originating from atmospheric layers centered at altitudes of 90 and 250 km were carried out at Irkutsk and of the O₂(b¹∑_g⁺−X³∑_g⁻) (0-1) emission originating from an atmospheric layer centered at altitude of 94 km was carried out at Almaty. Our radio and optical measurement network observed a storm-induced solitary large-scale wave with duration of 1 h and a wave front width of no less than 5000 km, while it traveled equatorward with a velocity of 200 m/s from 62°N to 38°N geographic latitude. The TEC disturbance, basically displaying an electron content depression in the maximum of the F2 region, reveals a good correlation with growing nightglow emission, the temporal shift between the TEC and emission variation maxima being different for different altitudes. A comparison of the auroral oval parameters with dynamic spectra of TEC variations and optical 630 nm emissions in the frequency range 0.4–4 mHz (250–2500 s periods) showed that as the auroral oval expands into mid-latitudes, also does the region with a developed medium-sale and small-scale TEC structure.     

桥梁隔震体系振动台试验研究(IV)——隔震桥梁的设计方法探讨

在前文模型试验的基础上 ,本文总结归纳了隔震桥梁的设计方法与设计流程 ,着重论述探讨了隔震桥梁的概念设计与细部构造设计应注意的问题