Exfoliation of kaolinite by urea-intercalation precursor and microwave irradiation assistance process

A type of exfoliated kaolinite was produced by urea-intercalation and original microwave irradiation assisted method. The product was investigated by Fourier transformation infrared (FT-IR) spectroscopy, X-ray diffraction (XRD), scanning electronic microscopy (SEM), Brunauer-Emmett-Teller (BET) and laser particle analysis techniques. FT-IR spectra show that NHCO molecule exists in the intercalated kaolinite. XRD analyses indicate that the kaolinite sheet-like structure was disordered after microwave irradiation. The urea decomposition process and explosion effect between the sheet-like structures of kaolinite under microwave irradiation were discussed. The SEM and BET analyses reveal that the end product is exfoliated kaolinite with thin particles and increased surface area. Size and zeta potential analyses show that the particle size distribution is between 250 nm and 550 nm with normal distribution and the particle is negatively charged. In comparison with the conventional grind method, the process adopted appears to be economic and the exfoliated kaolinite end product may display a significantly enhanced performance in industrial applications.     

会理菜子园镍矿床方辉橄榄岩铂族元素、Re-Os同位素及其地质意义

四川省会理菜子园红土型镍矿床中出露较多的基性-超基性岩体,文章系统报道了其中3个橄榄岩体的岩石化学、铂族元素及Re-Os同位素地球化学特征.岩石化学均显示为高MgO及高Mg#值,低SiO2、Al2O3、Na2O、K2O特征,计算显示出主要的标准矿物为橄榄石和紫苏辉石(体积百分数＞90％),表明菜子园属镁质方辉橄榄岩.铂族元素总量比世界上大多数地幔橄榄岩低,且Cu/Pd比值大于原始地幔,可能是早期地幔较高部分熔融出的基性岩浆中硫化物的萃取、抽提作用所致.PPGE相对IPGE强烈亏损,与正常蛇绿岩底部的地幔橄榄岩特征类似,向右倾斜的原始地幔标准化配分模式表明菜子园铂族元素体系主要受地幔部分熔融的控制.PPGE中,Pt相对于Pd富集,可能与后期强烈蚀变有关,此外还可能反映了少量Pt以合金形式残留于方辉橄榄岩中,Pd以不相容元素的形式更多被熔体带走.菜子园方辉橄榄岩的Re-Os同位素体系封闭性相对好,γ(Os)值较小.岩石化学、铂族元素及Re-Os同位素地球化学显示,菜子园橄榄岩直接来自地幔,属正常蛇绿岩套底部的方辉橄榄岩,为古小洋盆洋壳的残片.菜子园蛇绿岩反映了中元古代晚期昆阳裂谷在菜子园-踩马水-麻塘断裂带以北演化成小洋盆,于其中沉积会理群,并在中元古代末期与南侧的东川群、汤丹群碰撞、拼贴.菜子园橄榄岩的蛇绿岩属性进一步证明,扬子地台西南缘的基底由不同时代的小陆块碰撞、拼贴导致基底陆壳增生.     

藏东南部泥石流堵河试验研究

通过模型试验对泥石流入汇主河后堵塞坝形成过程以及堵塞坝体溃决后主河河床形态特征进行了研究。实验历时3个月,共13组试验。在支主沟交汇角为90°的情况下,通过改变支沟泥石流容重、支主沟的流量比和动量比,建立了泥石流堵河的判别公式,当r>1 001.16时容易发生堵河现象,并对培龙沟两次泥石流堵河事件进行了判定;定义了主河的束窄率S与主河流速变异系数Fv,并发现了主河的束窄率与支主沟动量比之间存在线性关系;主河稳定后的平均宽度与流速变异系数之间存在幂的关系。该实验能够较好地模拟泥石流堵塞坝形成的过程,结果比较合理,并为泥石流灾害的防治提供了相应的理论基础。     

多工况下汉源二蛮山滑坡机理数值模拟

利用FLAC3D软件对四川省雅安市汉源县二蛮山滑坡坡体进行建模,模拟降雨滑坡过程,并进行应力应变特征及稳定性计算分析,从而为深入研究地震及降雨诱发再次滑坡及防灾减灾提供可靠依据。研究中假设地震工况,对边坡进行详细的动力分析,得到了各监测点动力特征曲线;通过降雨工况下坡体稳定性系数分析得到了不同强度折减安全系数。研究结果表明,滑源区相对特殊的地形条件和地质构造以及不利的结构面组合是滑坡的基础;前期强降雨期间饱水加载以及大量雨水沿斜沟张裂结构面的下渗软化作用,是诱发滑坡发生的关键因素。      

U-Pb zircon geochronology, geochemistry and kinetics of the Huaniushan A-type granite in Northwest China

The Huaniushan granite is located at the Beishan orogenic belt, northwestern China. At the contact zone between the granite and marble, a hydrothermal Pb-Zn and skarn Au deposit is formed. LA-ICP-MS zircon U-Pb dating yielded a weighted mean 206Pb/238U age of 229.5±2.6 Ma (MSDW=0.93) for the Huaniushan granite, imply-ing its Late Triassic intrusion. Geochemistry analyses show that the Huaniushan granite is enriched in Si, K, Na, and REE, and depleted in Mg and Ca, with contents of SiO2 (70.8% to 74.4%), Na2O+K2O (8.8% to 10.2%), CaO (0.93% to 1.44%), and MgO (0.14% to 0.48%). REE is characterized by obvious negative Eu anomaly. Rb, Th, U, K, Pb, Nb, Zr and Hf elements are rich in the granite while Ba, Sr, P, Ti and Eu are deplete. The granite has a high (Zr+Nb+Ce+Y) abundance and 104 Ga/Al ratios. Petrology, major and trace elements data all indicate that the Hua-niushan granite is A-type granite which intruded in a post-collisional extensional tectonic setting. The magma was dominantly sourced from partial melting of crustal intermediate-felsic igneous rocks. Intensive magmatic activities and Au-Cu-Mo mineralization occurred throughout the Beishan orogenic belt during the period from ca. 240 to 220 Ma.     

水汽和潜热释放对背风波影响的数值试验

利用中尺度数值模式ARPS进行了理想场的数值模拟,分析研究了水汽和潜热释放对大气层结稳定度的影响以及其在背风波的发展和演变过程中的作用,研究发现,潜热释放对大气层结分布的影响要远大于水汽对大气层结分布的直接影响,如果没有潜热的释放,水汽对背风波的发展和演变的作用非常小,而潜热释放可以使湿层结稳定度急剧下降,迅速破坏原有的层结分布,使这个区域出现非拦截的强烈的垂直运动,波动的崩溃更加迅速和明显。但需要说明的是在试验中,将数值模式里控制潜热释放的参数设为:0、1/2、2的假定情况,则在实际的大气运动过程中是不可能存在的。     

2015年11月沈阳地区一次PM2.5重污染过程综合分析

利用多源观测资料综合分析了2015年11月沈阳地区一次PM2.5 重污染天气的气象条件、垂直风场演变、大气边界层特征以及污染物的来源。结果表明:本次重污染过程中,沈阳市区PM2.5浓度长达81h超过250μg · m^-3 ,其中峰值浓度达到1287μg · m^-3 ,重污染期间PM2.5 /PM10 的比例最高为90%。受地面倒槽和黄淮气旋影响,近地面层持续存在的逆温层、高相对湿度和弱偏北风为颗粒物吸湿增长和长时间聚集提供有利的天气条件。风廓线雷达风场资料显示在重污染期间,近地面层存在弱风速区、凌乱风场和弱下沉气流。利用风廓线雷达资料计算了边界层通风量(Ventilation Index,VI)和局地环流指数(Recirculation,R),边界层通风量VI和PM2.5 存在明显的负相关,非污染日VI是重污染日的2倍,局地环流指数R在重污染天气前大于0.9,而在污染期间部分空间R小于0.8。通过后向轨迹模式和火点监测资料分析发现,沈阳上空300m高度气团来自于生物质燃烧区域,而且沈阳地区NO2和CO浓度的变化与PM2.5一致,说明本次重污染过程也可能和生物质燃烧有关。     

强对流天气雷达回波与闪电特征的个例分析

利用闪电定位资料和多普勒天气雷达强度产品,分析了2006年6月22日发生在南京西南140km处的一次强对流天气过程中闪电的演变特征及其与回波强度的关系。结果表明,地闪多发生于雷暴云中回波强度大于40dBz且回波强度梯度较大的区域;正、负地闪频次在强对流系统发展的不同阶段呈现出不同的特点,负地闪占总闪数的90％以上,正地闪出现在系统进入成熟阶段之后,且占总闪的比例在系统消散阶段明显增大;地闪强度越大,相应的地闪频次越小,除少数弱闪（1/1〈10kA）外,二者基本上呈反相位关系。     

Influence of future tropical cyclone track changes on their basin-wide intensity over the western North Pacific: Downscaled CMIP5 projections

The possible changes of tropical cyclone(TC) tracks and their influence on the future basin-wide intensity of TCs over the western North Pacific(WNP) are examined based on the projected large-scale environments derived from a selection of CMIP5(Coupled Model Intercomparison Project Phase 5) models. Specific attention is paid to the performance of the CMIP5 climate models in simulating the large-scale environment for TC development over the WNP. A downscaling system including individual models for simulating the TC track and intensity is used to select the CMIP5 models and to simulate the TC activity in the future.The assessment of the future track and intensity changes of TCs is based on the projected large-scale environment in the21 st century from a selection of nine CMIP5 climate models under the Representative Concentration Pathway 4.5(RCP4.5)scenario. Due to changes in mean steering flows, the influence of TCs over the South China Sea area is projected to decrease,with an increasing number of TCs taking a northwestward track. Changes in prevailing tracks and their contribution to basin-wide intensity change show considerable inter-model variability. The influences of changes in prevailing track make a marked contribution to TC intensity change in some models, tending to counteract the effect of SST warming. This study suggests that attention should be paid to the simulated large-scale environment when assessing the future changes in regional TC activity based on climate models. In addition, the change in prevailing tracks should be considered when assessing future TC intensity change.     

郑州强对流天气成因分析

对2004年郑州出现的7次强对流天气过程的天气形势、影响系统及稳定度的分析结果表明：华北低涡和NW气流形势下存在着低层升温、高层降温机制,使大气层结趋于不稳定,当测站高低空温差或温度平流差达到一定量值,且近地层存在辐合系统时,易出现强对流; SW气流或高压控制时,大气高温高湿,具有较强不稳定能量,若850 hPa或地面出现辐合系统时,易产生强对流;地面湿度连续数天加大或保持在某一值域,其上空温湿24 h变化呈上趋冷下趋暖或上趋干下趋湿并达到一定量值,预示强对流的发生;700～500 hPa湿度明显减小,24 h温度露点差加大4 ℃以上,或近地层θse≥350K,中低层Δθse≥26 K,θse小值位于700 hPa或500 hPa,其厚度≥2000 m,易出现强雷雨大风; 700 hPa以下t-td≤4.3 ℃,或连续4天850 hPa t-td≤7 ℃、700 hPa t-td≤5 ℃、500 hPa t-td≤9 ℃,PW≥12,可预示短时暴雨的出现.