Effect of Biofuels on Biodegradation of Benzene and Toluene at Gasoline Spill Sites

The risk that benzene and toluene from spills of gasoline will impact drinking water wells is largely controlled by the natural anaerobic biodegradation of benzene and toluene. Benzene and toluene, as well as ethanol and other biofuels, are degraded under anaerobic conditions to the same pool of degradation products. Biodegradation of biofuels may produce concentrations of degradation products that make the thermodynamics for degradation of benzene and toluene infeasible under methanogenic conditions and produce larger plumes of benzene and toluene. This study evaluated the concentrations of fuel alcohols that are necessary to inhibit the anaerobic degradation of benzene and toluene under methanogenic conditions. At two ethanol spill sites, concentrations of ethanol greater ≥42 mg/L inhibited the anaerobic degradation of toluene. The pH and concentrations of acetate, dissolved inorganic carbon, and molecular hydrogen were used to calculate the Gibbs free energy for the biodegradation of toluene. In general, the anaerobic biodegradation of toluene was not thermodynamically feasible in water with ≥42 mg/L ethanol. In a microcosm study, when the concentrations of ethanol were ≥14 mg/L or the concentrations of n‐butanol were ≥16 mg/L, the biodegradation of the alcohols consistently produced concentrations of hydrogen, dissolved inorganic carbon, and acetate that would preclude natural anaerobic biodegradation of benzene and toluene by syntrophic organisms. In contrast, iso‐butanol and n‐propanol only occasionally produced conditions that would preclude the biodegradation of benzene and toluene.     

Effective impervious area for runoff in urban watersheds

Effective impervious area (EIA), or the portion of total impervious area (TIA) that is hydraulically connected to the storm sewer system, is an important parameter in determining actual urban runoff. EIA has implications in watershed hydrology, water quality, environment, and ecosystem services. The overall goal of this study is to evaluate the application of successive weighted least square (WLS) method to urban catchments with different sizes and various hydrologic conditions to determine EIA fraction. Other objectives are to develop insights on the data selection issues, EIA fraction, EIA/TIA ratio, and runoff source area patterns in urban catchments. The successive WLS method is applied to 50 urban catchments with different sizes from less than 1 ha to more than 2000 ha in Minnesota, Wisconsin, Texas, USA as well as Europe, Canada, and Australia. The average, median, and standard deviation of EIA fractions for the 42 catchments with residential land uses are found to be 0.222, 0.200, and 0.113, respectively. These values for the EIA/TIA ratio in the same 42 catchments are 0.50, 0.48, and 0.21, respectively. While the EIA/TIA results indicate the importance of EIA, 95% prediction interval of the mean EIA/TIA is found to be 0.07 to 0.93, which shows that using an average value for this ratio in each land use to determine EIA from TIA in ungauged urban watersheds can be misleading. The successive WLS method was robust and is recommended for determining EIA in gauged urban catchments. Copyright © 2016 John Wiley & Sons, Ltd.     

Introduction: Racialized Poverty in U.S. Cities: Toward a Refined Racial Economy Perspective

This discussion hones and refines one conceptual orientation in geography and urban studies increasingly used to understand racialized poverty and marginalization in U.S. cities: racial economy. The article illuminates two aspects of this perspective, as an ongoing ontological project with six dominant features and as a base of epistemological understandings about contemporary racialized realities in current U.S. cities and society. This discussion shows racial economy to be still developing and in need of deeper theorizing.     

A GIS-Based Tool for Representing Larval Dispersal for Marine Reserve Selection

Increasing efforts to implement marine protected areas (MPAs) as a means of managing marine ecosystems have created a need for evaluating potential spatial management plans. Almost all marine populations are metapopulations, connected reproductively by the dispersal of pelagic larvae. Models of marine population dynamics must account for larval connectivity, but despite recent advances connectivity patterns are still poorly understood. To allow more informed decision making when complete information on dispersal is lacking, we have developed a method based on geographic information systems (GIS) for representing larval dispersal distributions based on bathymetry and typical flows in the coastal ocean. These distributions reflect (1) generally greater flow in directions along, rather than across, lines of constant bathymetry and (2) lesser flow in shallow near-shore waters. We demonstrate how to parameterize this two-dimensional method for depicting larval dispersal based on comparisons to local oceanographic data. We then compare the predictions of the two-dimensional method to those of a simpler one-dimensional alternative in a population model used to evaluate proposed MPAs along the coast of central California. The method produces reasonable larval dispersal patterns and appears to include the effects of bathymetry on population dynamics better than commonly used one-dimensional methods and without requiring the significantly greater investment of developing particle-tracking circulation models. An important advantage of a two-dimensional approach is more realistic portrayal of the dependence of population persistence on the cross-shelf dimension of available habitat.     

Spatial Access to Health Care Services and Disparities in Colorectal Cancer Stage at Diagnosis in Texas

Early diagnosis of colorectal cancer (CRC) is important for improving the survival rate of the disease. Disparities in CRC diagnosis among different population groups have persisted in the United States. This study examines whether spatial access to medical services contributes to disparities of late-stage diagnosis of CRC in Texas. Analysis results suggest that there are significant disparities in late-stage CRC diagnosis by race/ethnicity, socioeconomic status, and geographic location in Texas. It is concluded that spatial access to primary care is associated with CRC stage at diagnosis, but not with racial/ethnic and socioeconomic disparities.     

Community resilience,globalization, and transitional pathways of decision-making

This article investigates the impacts of globalization processes on community resilience. It argues that theoretical concepts such as transition theory can provide a lens through which resilience pathways at community level can be better understood, and proposes a framework focused on a social resilience approach for understanding community resilience as the conceptual space at the intersection between economic, social and environmental capital. It argues that certain types of communities are losing resilience through increased embeddedness into globalized pathways of decision-making, while other communities may be gaining resilience, although not one system is either totally resilient or totally vulnerable. Striking the right ‘balance’ between communities and their scalar interactions with the global level is key for maximization of community resilience: while too much isolation of a community may be bad in light of over-dependency on local resources, skills and people, ‘over-globalization’, with possible loss of autonomy and identity, may be equally fraught with problems. In particular, relocalized communities have, so far, not shown much tangible success, as almost all members of the relocalization process at community level are simultaneously embedded within the global capitalist system through their dependencies on global economic processes.     

Phase transitions and path dependence in urban evolution

There is a long history of recognising and interpreting discontinuous change—phase transitions—in urban systems. In this paper, we use the aggregate retail model as an archetype to explore some new ideas. For example, we argue that the dependence of paths of development on initial conditions has been understudied, and we offer a new graphical analysis that demonstrates explicitly their influence on discrete change. We introduce an order parameter, and we plot this on a ‘results grid’ to facilitate the discovery of possible phase transitions. We illustrate the use of these new developments with an application to London. We show how retail developers can change the ‘initial conditions’ at a point in time and possibly bring about phase transitions by their actions. This also shows that it should be possible to account for the history of urban development as a sequence of initial conditions, illustrating path dependence. Secondly, the model could be deployed in relation to a new shopping zone, and the tools developed here used to calculate the minimum size of a new development in order for it to compete. We explore the ‘minimum size’ idea in relation to a new shopping zone in London.     

Evaluation of the 15 July 2009 Fiordland,New Zealand Tsunami in the Source Region

We undertake detailed near-field numerical modelling of the tsunami generated by the 15 July 2009 earthquake (Mw 7.8) in Fiordland, New Zealand. High resolution bathymetry and topography data at Breaksea and Dusky Sounds, and Chalky and Preservation Inlets are derived mostly from digitised New Zealand nautical charts, Shuttle Radar Topographic Mission (SRTM) 3 arc-second data, and General Bathymetric Chart of the Ocean (GEBCO) 30 s data. A combination of continuous and campaign Global Positioning System (GPS), satellite radar (ALOS/PALSAR InSAR images) and seismology data are used to constrain the seafloor deformation for the initial tsunami condition. This source model, derived independently of DART observations, provides an excellent fit to observed tsunami elevations recorded by DART buoy 55015. The model results in the near field show maximum tsunami elevations in the range 0.5–2.0 m inside the sounds and inlets with maximum flow speeds of 3.0 m/s. Along the open coast, maximum tsunami elevations reach 2.0 m. The high flow speeds through the inlets may change the inlet stratifications and water mass inside the sounds. Media reports and field reconnaissance data show some tsunami evidence at Cormorant Cove, Duck and Goose Coves, and Passage Point.