The initial responses of hot liquid water released under low atmospheric pressures: Experimental insights

Experiments have been performed to simulate the shallow ascent and surface release of water and brines under low atmospheric pressure. Atmospheric pressure was treated as an independent variable and water temperature and vapor pressure were examined as a function of total pressure variation down to low pressures. The physical and thermal responses of water to reducing pressure were monitored with pressure transducers, temperature sensors and visible imaging. Data were obtained for pure water and for solutions with dissolved NaCl or CO₂. The experiments showed the pressure conditions under which the water remained liquid, underwent a rapid phase change to the gas state by boiling, and then solidified because of removal of latent heat. Liquid water is removed from phase equilibrium by decompression. Solid, liquid and gaseous water are present simultaneously, and not at the 611 Pa triple point, because dynamic interactions between the phases maintain unstable temperature gradients. After phase changes stop, the system reverts to equilibrium with its surroundings. Surface and shallow subsurface pressure conditions were simulated for Mars and the icy satellites of the outer Solar System. Freezing by evaporation in the absence of wind on Mars is shown to be unlikely for pure water at pressures greater than c. 670 Pa, and for saline solutions at pressures greater than c. 610 Pa. The physical nature of ice that forms depends on the salt content. Ice formed from saline water at pressures less than c. 610 Pa could be similar to terrestrial sea ice. Ice formed from pure water at pressures less than c. 100 Pa develops a low thermal conductivity and a ‘honeycomb’ structure created by sublimation. This ice could have a density as low as c. 450 kg m⁻³ and a thermal conductivity as low as 1.6 W m⁻¹ K⁻¹, and is highly reflective, more akin to snow than the clear ice from which it grew. The physical properties of ice formed from either pure or saline water at low pressures will act to reduce the surface temperature, and hence rate of sublimation, thereby prolonging the lifespan of any liquid water beneath.     

Formation of an eroded lava channel within an Elysium Planitia impact crater: Distinguishing between a mechanical and thermal origin

A lava channel identified on the wall of an Elysium Planitia impact crater is investigated to identify the dominant erosion mechanism, mechanical vs. thermal, acting during channel formation. Observations of channel morphology are used to supplement analytical models of lava channel formation in order to calculate the duration of channel formation, the velocity of the lava flowing through the channel, and the erosion rate in each erosion regime considered. Results demonstrate that the channel observed in the Elysium Planitia impact crater formed primarily due to mechanical erosion. In a more general sense, results of this study suggest that lava channels can form primarily due to thermal erosion in the presence of more gradual slopes and more consolidated substrates whereas lava channels can form primarily due to mechanical erosion in the presence of more energetic flows on steeper slopes and more poorly consolidated substrates. Therefore, both erosion regimes must be considered when analyzing origins of eroded lava channels that cut through strata of different strengths.     

Hooker's sea lions in southern New Zealand

The discovery at Stewart Island of a hauling‐out ground regularly used by Hooker's sea lions (Phocarctos hooked) is described, and recent sightings of sea lions in southern New Zealand are reported. An attempted copulation between a male Hooker's sea lion and a dead female fur seal (Arctocephalus forsteri) is also described.     

Some things old, some things new: The spatial representations and politics of change of the peak oil relocalisation movement

Despite continued uncertainty about the physical realities and political, economic and social implications of peak oil, combined concerns about oil scarcity, climate change and globalisation has spawned an energetic relocalisation movement dedicated to achieving a comprehensive reduction in oil dependency through community-scale initiatives. This paper uses a discourse approach to examine the emergence, geographical spread and practices of the Transition Network, a UK-originated relocalisation movement now involving 186 local initiatives in the UK and other countries. We trace the movement’s drawing upon, and innovation from, discourses and techniques used by other grassroots environmental movements to promote a spatial representation of peak oil as an inevitable and geographically undiscriminating problem, and its use of addiction metaphors and participatory techniques to promote personal and community-scale energy descent initiatives as a viable and necessary alternative to globalisation. We also analyse the spatial representations and techniques used in the Network’s “rhizomic” spread across multiple localities around the world and embedding in communities where relocalisation initiatives are established. We conclude by examining the future challenges these spatial constructions of peak oil pose for the relocalisation movement.     

Got green? addressing environmental justice in park provision

We present a pragmatic approach to assist planners in addressing racial inequities in park access. Utilizing the Los Angeles metropolitan region as an example, we used Thiessen polygons to delineate a service area for each park, and described potential park congestion or ‘pressure’ in each park service area. Results show that Latinos, African-Americans, and low-income groups in general were likely to live close to parks with higher potential park congestion. On the other hand, predominantly White, high-income areas were typically located close to parks with lower potential park congestion levels. The park service area analysis presented here facilitates the identification of areas with greater park need and provides a pragmatic way to redress existing disparities in park access. Built into a set of web-based decision support tools, the approach fosters greater community participation and empowers local stakeholders in the process of park provision.     

Postbellum race relations in commodity exchange

A structural imperative of capital is to expand commodity exchange. To realize surplus value, capitalists not only have to exploit workers in the production process, but also make workers buy what they produce. This paper examines how this imperative of capital shaped race relations from the end of slavery through the Jim Crow era. The racism that sustained black slavery was highly exclusionary––a fixed racism that undermined this imperative of capital to expand commodity exchange. A more flexible racism would resolve this contradiction. Reconstruction was a move to erase all vestiges of the fixed racism that sustained slavery from relations of commodity exchange. Jim Crow countered with a more flexible racism that maintained the racial status quo but was less of a barrier to blacks participating in commodity exchange in the consumption process.     

Sr and Nd isotopic geochemistry of the early ultramafic–mafic rocks of the Mako bimodal volcanic belt of the Kedougou–Kenieba inlier (Senegal)

The Mako bimodal volcanic belt of the Kédougou–Kéniéba inlier is composed of volcanic basalts and peridotites interbedded by quartzites and limestones intruded by different generations of granitoïds. The early volcanic episode of the belt is constituted of submarine basalts with peridotite similar to those of the oceanic abyssal plains. It is intruded by the Badon Kakadian TTG?granitic batholite dated around 2200 Ma. The second volcanic phase is constituted of basaltic, andesitic, and felsitic flows exhibit structures of aerial volcanic rocks. It is intruded by granites dated between 2160 and 2070 Ma. The general pattern of trace element variation of submarine volcanic rocks is consistent with those of basalts from oceanic plateaus which are the modern equivalent of the Archean greenstones belts. The Nd and Sr isotopic systematics typical of juvenile material indicates that the source of these igneous rocks is derived from a depleted mantle source. These results are consistent with the idea of a major accretion within the West African Craton occurring at about 2.1 Ga and corresponding to an important process of mantle–oceanic lithosphere differentiation.     

Experimental investigation on shear strength and permeability of a deeply dewatered sewage sludge for use in landfill covers

This paper presents an experimental study on a deeply dewatered sewage sludge produced by using a new technique of membrane filter press. The experiments involve measurements of sludge composition, basic physical properties, shear strength, water permeability, and leaching toxicity. The measurements of shear strength and permeability were also performed on the sludge specimens soaked in a low acid leachate or distilled water for 1 and 2 months. This is to investigate the influence of chemical change in pore fluid as a result of rainfall infiltration or leachate seepage at landfills. Comparison tests were also carried out on silty clay that is commonly used for landfill cover material. The experimental results show that the deeply dewatered sludge contains 66 % organic content and 85 % water content (dry mass basis). The undrained shear strength of the sludge is >25 kPa even after 2-month soaking in the leachate and distilled water, meeting the requirement of the Chinese standard [CJ/T249-2007, Disposal of sludge from municipal wastewater treatment plant: sludge quality for co-landfilling. Ministry of Building and Construction, P.R. China (in Chinese), 2007]. The measured cohesion and friction angle for the sludge are >20 kPa and 22.3°, respectively. The soaking of sludge specimens in either leachate or distilled water resulted in an increase in frictional angle by several degrees. The water permeability for the sludge ranges from 0.68 × 10^?8 to 1.3 × 10^?8 cm/s, and permeability after 2-month soaking is less than the minimum requirement for the barrier layer of landfill covers (i.e., 1.0 × 10^?7 cm/s). The concentrations of heavy metals leaching from the dewatered sludge are lower than the limit values of leaching toxicity for the wastewater discharge standard of China. The experimental results indicate that deeply dewatered sludge can be used as an alternative material for the barrier layer of landfill covers.     

Temporal evolution and compositional signatures of two supervolcanic systems recorded in zircons from Mangakino volcanic centre,New Zealand

Mangakino, the oldest rhyolitic caldera centre delineated in the Taupo Volcanic Zone of New Zealand, generated two very large (super-sized) ignimbrite eruptions, the 1.21 ± 0.04 Ma >500 km³ Ongatiti and ~1.0 Ma ~1,200 km³ Kidnappers events, the latter of which was followed after a short period of erosion by the ~200 km³ Rocky Hill eruption. We present U/Pb ages and trace-element analyses on zircons from pumice clasts from these three eruptions by Secondary Ion Mass Spectrometry (SIMS) using SHRIMP-RG instruments to illustrate the evolution of the respective magmatic systems. U–Pb age spectra from the Ongatiti imply growth of the magmatic system over ~250 kyr, with a peak of crystallisation around 1.32 Ma, ~100 kyr prior to eruption. The zircons are inferred to have then remained stable in a mush with little crystallisation and/or dissolution before later rejuvenation of the system at the lead-in to eruption. The paired Kidnappers and Rocky Hill eruptions have U–Pb zircon ages and geochemical signatures that suggest they were products of a common system grown over ~200 kyr. The Kidnappers and Rocky Hill samples show similar weakly bimodal age spectra, with peaks at 1.1 and 1.0 Ma, suggesting that an inherited antecrystic population was augmented by crystals grown at ages within uncertainty of the eruption age. In the Kidnappers, this younger age peak is dominantly seen in needle-shaped low U grains with aspect ratios of up to 18. In all three deposits, zircon cores show larger ranges and higher absolute concentrations of trace elements than zircon rims, consistent with zircon crystallisation from evolving melts undergoing crystal fractionation involving plagioclase and amphibole. Abundances and ratios of many trace elements frequently show variations between different sectors within single grains, even where there is no visible sector zoning in cathodoluminescence (CL) imaging. Substitution mechanisms, as reflected in the molar (Sc + Y + REE³⁺)/P ratio, differ in the same growth zone between the sides (along a-axis and b-axis: values approaching 1.0) and tips (c-axis: values between 1.5 and 5.0) of single crystals. These observations have implications for the use of zircons for tracking magmatic processes, particularly in techniques where CL zonation within crystals is not assessed and small analytical spot sizes cannot be achieved. These observations also limit applicability of the widely used Ti-in-zircon thermometer. The age spectra for the Ongatiti and Kidnappers/Rocky Hill samples indicate that both magmatic systems were newly built in the time-breaks after respective previous large eruptions from Mangakino. Trace element variations defining three-component mixing suggest that zircons, sourced from multiple melts, contributed to the population in each system.