东秦岭东段新发现的沙坡岭细脉浸染型钼矿地质特征、Re-Os同位素年龄及其地质意义

豫西洛宁沙坡岭钼矿床位于华北克拉通南缘东秦岭钼矿带东段,是新近发现的赋存于太古宙太华群变质岩中的细脉浸染型钼矿床。本文对其地质特征进行了研究,并初步测定了1个辉钼矿样品的Re－Os同位素年龄,获得模式年龄为126.8±1.7Ma,表明沙坡岭钼矿形成于燕山期,接近金堆城、雷门沟钼矿的形成时代,Re同位素含量显示其地幔来源的特征。沙坡岭钼矿形成机制错综复杂,有待进一步研究,特别是深部钻孔工程验证工作,对于验证深部是否隐伏着与成矿相关的斑岩体、储量更大的斑岩型钼矿有着重要作用,找矿潜力巨大。     

Silurian collisional suturing onto the southern margin of the North China craton: Detrital zircon geochronology constraints from the Qilian Orogen

The Qilian Orogen of north western China records mid-Paleozoic collisional suturing of arc and continental blocks onto the south western margin of the North China craton. Silurian strata from the retroarc foreland basin mark the transition from ocean closure and northward subduction to the initiation of collision suturing. Detrital zircons were analysed from the western and eastern parts of the basin and show a spectrum of ages from Archean to Paleozoic with major age concentrations at around 2.5 Ga, 1.6 Ga, 1.2 Ga, 0.98 Ga, 0.7 Ga and 0.45 Ga. Archean age grains are derived from the North China craton, whereas the Central Qilian Bloc, which lies to the south provides the likely source for the bulk of the Proterozoic detritus. Paleozoic grains are restricted to Early Silurian samples from the western part of the basin and are considered to have been derived from the magmatic arc related to ocean closure and ultimate collision of the Central Qilian Belt with the North China craton.     

Geochronological framework and Pb, Sr isotope geochemistry of the Qingchengzi Pb–Zn–Ag–Au orefield, Northeastern China

The Qingchengzi orefield in northeastern China, is a concentration of several Pb–Zn, Ag, and Au ore deposits. A combination of geochronological and Pb, Sr isotopic investigations was conducted. Zircon SHRIMP U–Pb ages of 225.3 ± 1.8 Ma and 184.5 ± 1.6 Ma were obtained for the Xinling and Yaojiagou granites, respectively. By step-dissolution Rb–Sr dating, ages of 221 ± 12 Ma and 138.7 ± 4.1 Ma were obtained for the sphalerite of the Zhenzigou Zn–Pb deposit and pyrargyrite of the Ag ore in the Gaojiabaozi Ag deposit, respectively. Pb isotopic ratios of the Ag ore at Gaojiabaozi (²⁰⁶Pb/²⁰⁴Pb = 18.38 to 18.53) are higher than those of the Pb–Zn ores (²⁰⁶Pb/²⁰⁴Pb = 17.66 to 17.96; Chen et al. [Chen, J.F., Yu, G., Xue, C.J., Qian, H., He, J.F., Xing, Z., Zhang, X., 2005. Pb isotope geochemistry of lead, zinc, gold and silver deposit clustered region, Liaodong rift zone, northeastern China. Science in China Series D 48, 467–476.]). Triassic granites show low Pb isotopic ratios (²⁰⁶Pb/²⁰⁴Pb = 17.12 to 17.41, ²⁰⁷Pb/²⁰⁴Pb = 15.47 to 15.54, ²⁰⁸Pb/²⁰⁴Pb = 37.51 to 37.89) and metamorphic rocks of the Liaohe Group have high ratios (²⁰⁶Pb/²⁰⁴Pb = 18.20 to 24.28 and 18.32 to 20.06, ²⁰⁷Pb/²⁰⁴Pb = 15.69 to 16.44 and 15.66 to 15.98, ²⁰⁸Pb/²⁰⁴Pb = 37.29 to 38.61 and 38.69 to 40.00 for the marble of the Dashiqiao Formation and schist of the Gaixian Formation, respectively).Magmatic activities at Qingchengzi and in adjacent regions took place in three stages, and each contained several magmatic pulses: ca. 220 to 225 Ma and 211 to 216 Ma in the Triassic; 179 to 185 Ma, 163 to 168 Ma, 155 Ma and 149 Ma in the Jurassic, as well as ca. 140 to 130 Ma in the Early Cretaceous. The Triassic magmatism was part of the Triassic magmatic belt along the northern margin of the North China Craton produced in a post-collisional extensional setting, and granites in it formed by crustal melting induced by mantle magma. The Jurassic and Early Cretaceous magmatism was related to the lithospheric delamination in eastern China. The Triassic is the most important metallogenic stage at Qingchengzi. The Pb–Zn deposits, the Pb–Zn–Ag ore at Gaojiabaozi, and the gold deposits were all formed in this stage. They are temporally and spatially associated with the Triassic magmatic activity. Mineralization is very weak in the Jurassic. Ag ore at Gaojiabaozi was formed in the Early Cretaceous, which is suggested by the young Rb–Sr isochron age, field relations, and significantly different Pb isotopic ratios between the Pb–Zn–Ag and Ag ores. Pb isotopic compositions of the Pb–Zn ores suggest binary mixing for the source of the deposits. The magmatic end-member is the Triassic granites and the other metamorphic rocks of the Liaohe Group. Slightly different proportions of the two end-members, or an involvement of materials from hidden Cretaceous granites with slightly different Pb isotopic ratios, is postulated to interpret the difference of Pb isotopic compositions between the Pb–Zn–(Ag) and Ag ores. Sr isotopic ratios support this conclusion. At the western part of the Qingchengzi orefield, hydrothermal fluid driven by the heat provided by the now exposed Triassic granites deposited ore-forming materials in the low and middle horizons of the marbles of the Dashiqiao Formation near the intrusions to form mesothermal Zn–Pb deposits. In the eastern part, hydrothermal fluids associated with deep, hidden Triassic intrusions moved upward along a regional fault over a long distance and then deposited the ore-forming materials to form epithermal Au and Pb–Zn–Ag ores. Young magmatic activities are all represented by dykes across the entire orefield, suggesting that the corresponding main intrusion bodies are situated in the deep part of the crust. Among these, only intrusions with age of ca. 140 Ma might have released sufficient amounts of fluid to be responsible for the formation of the Ag ore at Gaojiabaozi.Our age results support previous conclusions that sphalerite can provide a reliable Rb–Sr age as long as the fluid inclusion phase is effectively separated from the “sulfide” phase. Our work suggests that the separation can be achieved by a step-resolution technique. Moreover, we suggest that pyrargyrite is a promising mineral for Rb–Sr isochron dating.     

大别山东缘郯庐断裂带造山后左行平移活动时间：锆石LA-ICP-MS U-Pb定年结果的限定

郯庐断裂带在造山阶段之后发生了明显的左行平移活动,但到目前为止对于其发生时间仍存在较大争议。大别山东缘郯庐断裂带内存在一系列花岗质、基性岩脉,其形成与郯庐断裂带左行平移活动密切相关,因而对其形成年龄的测定可以为断裂带左行平移时间提供限定。本次工作在大别山东缘郯庐断裂带内糜棱岩及岩脉中采集了6个样品开展锆石LA-ICP-MS年龄测定。两个花岗质糜棱岩样品均得到了新元古代和印支期两组年龄结果,但并未得到早白垩世年龄结果,可能指示了强烈的构造变形抑制了锆石的生长。与断裂带左行平移活动同期的基性岩墙侵位时间为128 Ma左右;斜切糜棱岩面理的基性岩墙侵位于127 Ma 左右;发生韧性变形形成糜棱岩的二长花岗岩侵位时间为128 Ma左右;仅出现NE向劈理的钾长花岗岩侵位于126 Ma。综合以上结果,大别山东缘郯庐断裂带与下扬子地区存在类似的构造背景,其早白垩世左行平移事件的发生时间为128 Ma之前,之后断裂带在区域伸展背景下转变为正断层活动。     

Review of the Tropical Gyre in the Indian Ocean with Its Impact on Heat and Salt Transport and Regional Climate Modes

Due to the IO monsoon impact, the tropical IO circulation has significant seasonal variation, especially in the northern IO. However, in mean-state, a relatively closed current loop is established by eastward current along the equator and westward current south of equator, which is regarded as Tropical Gyre in the Indian Ocean. Based on this circulation system, relevant studies were reviewed. Its impact on heat and salt transports and regional climate changes were discussed.     

全新世以来毛乌素沙地东南缘成壤环境演变研究——以榆林镇北台为例

古土壤是重建古环境重要的信息源。毛乌素沙地东南缘的古土壤在发育程度上尚未有明确解释。陕西省榆林市的镇北台地区位于毛乌素沙地东南边缘,对气候响应敏感。本文选取厚度为524 cm的镇北台(ZBT)剖面,按照古土壤2 cm、风成砂5 cm的间隔共采集古土壤样品156个,风成砂样品58个。基于6个AMS14C和3个OSL年代样品,推测剖面古土壤底部年龄为10 cal.ka B.P.,顶部年龄为3.2 cal.ka B.P.;并结合土壤微形态特征,对镇北台剖面沉积物中常量元素特征与成壤强度进行分析探讨。结果表明,镇北台(ZBT)剖面常量元素组成以SiO2、Al2O3和Na2O为主。CIA指数指示剖面处于脱Ca、Na为主的初级风化阶段,反映了毛乌素沙地东南缘全新世以来可能以相对干旱的气候环境为主,风化成壤作用较弱,但其中也不乏幅度较小的冷暖气候旋回。土壤微形态特征也表明ZBT剖面风化程度较弱,主要矿物由石英、长石、云母和岩屑矿物构成,可见胶结物和泥岩岩屑等土壤形成物。其成壤强度变化与化学元素特征表现一致:10.0~8.1 cal.ka B.P.左右,成壤较弱,气候向暖湿转变;6.9 cal.ka B.P.左右,成壤作用稍有加强;5.5~3.7 cal.ka B.P.左右,成壤作用最强,气候相对暖湿,化学、生物风化加强,但此阶段具有明显的不稳定性.     

基于叠前深度偏移的AVO反演在神狐海域试采区的应用

为了更好地研究神狐海域试采区天然气水合物的展布形态和赋存状况,基于高精度层析速度反演后的叠前深度偏移地震资料进行AVO反演技术研究。为在天然气水合物富集区有效地进行AVO研究,AVO处理前运用叠前深度偏移技术,通过高精度层析反演不断迭代速度模型;然后通过偏移来改善资料的质量,结合实测钻井资料进行AVO正演分析、反演可行性分析、属性交会分析;最后将具有高横向分辨能力的地震资料和高垂向分辨能力的测井资料与地质相结合进行叠前同时反演。该方法可反演出纵、横波阻抗等属性,直接进行岩性和流体识别,结果表明,在AVO反演中引入叠前深度偏移技术,为反演提供了较高质量的叠前共反射点道集和精细的层速度模型,改善了AVO技术在试采区的应用效果,提高了反演的可靠性。反演出的各种属性为AVO分析提供了丰富的信息,能够比较准确地反映地下水合物矿体的展布情况,可用于后续水合物储层的分析及综合研究,对未来的水合物勘探开采具有重要的现实意义。     

富磷矿三阶段动态成矿模式:黔中开阳式高品位磷矿成矿机制

震旦系陡山沱组沉积期形成的黔中开阳、瓮安富磷矿沉积区,矿石产量大、品位高,是国内外重要的磷矿资源产区。黔中磷矿主要分布于黔中古陆周缘的滨浅海环境中,矿石类型以碎屑状磷块岩为主,间夹原生泥晶磷块岩、生物结构磷块岩和次生土状结构磷块岩。开阳式高品位磷块岩的动态沉积成矿过程通常为“三阶段成矿”: 第一阶段为初始成磷作用阶段,在新元古代大规模成磷背景下,上升洋流携带深部富磷海水进入滨浅海地区,并通过生物化学作用使磷质聚集并形成原生磷块岩沉积;第二阶段为簸选成矿作用阶段,高能波浪、风暴水流对原生磷块岩持续的破碎、磨蚀、搬运和再沉积过程中,簸选去除了原生沉积物中的陆源细碎屑、砂泥质成分,保留并聚集磷质碎屑颗粒,形成品位较高的碎屑状矿石;第三阶段为淋滤作用阶段,海平面升降变化使之前形成矿石受暴露事件影响,遭受强烈的风化淋滤作用,碎屑状磷矿石内的碳酸盐岩胶结物和白云石条带被淋滤运移,导致矿层发育大量溶蚀孔洞,甚至形成土状磷块岩,矿石品位再次得到大幅度提升。三阶段成矿作用随古地理条件和海平面变化在沉积成岩过程中多期次、动态进行,最终形成工业价值极高的磷矿石。     

基于数学形态学的位场数据边缘增强方法

位场数据边缘增强对于地质构造研究和矿床勘查具有重要意义。现有的边缘增强方法多数基于位场数据的导数构建,往往存在对噪声敏感的缺点,且处理结果中常有虚假边界的出现。本文基于数学形态学良好的形状分析和噪声压制性能,通过数学形态学基本算子的组合叠加,提出了一种新的位场数据边缘增强方法。该方法容易实现,且不需要计算位场数据的水平和垂向导数。板状体模型试验结果表明,该方法能有效地对重力异常和化极后的磁异常数据进行边缘增强。针对三维模型试验中正负异常同时存在的情况,相比以往几种方法,该方法输出的边缘更清晰且没有额外边缘的产生,并表现出更强的抗噪能力。最后将该方法和以往几种方法应用到老挝万象地区实际重力异常数据的处理中,结果显示该方法刻画出的边缘更加连续清晰;同时结合以往地质资料,推断了成矿的有利部位。