常熟地倾斜观测突跳的深入分析

通过对常熟SQ-70石英丝倾斜仪1996~2005年NS向观测出现的几次显著突跳事件进行深入分析,对地震预报实践中给出的判定意见进行了回顾和反思,同时讨论了该仪器年变幅和M2波潮汐因子的变化,对今后的日常地震预报有较好的参考价值。     

基于线框模型的复杂断层三维建模方法

建立了包含复杂断层面地质体的三维数学模型.为准确表达复杂地质体各要素的空间几何形态及其相互之间的关联关系,设计了线框单元体模型,并提出了整体描述断层面的技术思路,解决了地层交错情况下断层面和地层面的模拟难题;在上述基础上,结合平面地质图数据,实现了复杂地质条件下三维地质体模型的构建.     

青藏高原东北缘共和盆地第四纪磁性地层学研究

共和盆地第四纪剖面磁性地层学研究表明,该剖面包含了四个正极性段,三个负极性段,剖面底部地层年龄约为2.11Ma B.P.。结合剖面的沉积特征和已有的孢粉组合特征分析,可以确定该剖面记录了共和盆地2.11Ma B.P.以来的气候变化,且气候发生转型的主要时期依次为1.92 Ma B.P、1.75Ma B.P.、1.40Ma B.P.、1.02 Ma B.P.和0.87Ma B.P.。其主要原因可能是青藏高原强烈隆升远程效应的结果。共和盆地气候变化时间序列的建立为研究青藏高原隆升及环境效应提供有力证据。      

滇西新生代盆地与砂岩型铀矿成矿

滇西新生代盆地内蕴藏着丰富的铀资源,现已探明8个中、小型砂岩型铀矿床,是中国重要的砂岩型铀矿成矿带之一。本文在收集研究前人施工钻孔资料1200个,施工钻孔25个的基础上,编制岩性-岩相-地球化学剖面图66张,研究了滇西新生代盆地与砂岩型铀矿成矿。认为滇西地区存在2种类型的新生代盆地,其盆地沉积演化、火山活动、地貌景观等不同,砂岩型铀矿成矿条件亦存在差异,成矿的专属性体现在于盆地的差异性。砂岩型铀矿成矿最有利的是北部腾冲地区找矿目的层上覆地层发育了区域性隔水层、存在火山活动、深切割低山-丘陵-河谷阶地地貌的新生代盆地。     

Adsorption of Pentachlorophenol onto Oxide and Clay Minerals： Surface Reaction Model and Environmental Implications

The adsorption of pentachlorophenol （PCP） onto quartz, kaolinite, illite, montmorillonite and iron oxides has been investigated by batch equilibrium techniques. The pH-dependent isotherms are curves with peak values, the position of which is at about pH = 5-6 depending on the mineral species. Based on distribution of both speciation of surface hydroxyls on minerals and PCP in solution a surface reaction model involving surface complexation and surface electrostatic attraction is presented to fit the pH-dependent isotherms, and both reaction constants are calculated. The results show that on quartz and phyllosilicate minerals the predominant adsorption reaction is surface complexation, meanwhile both of surface electrostatic attraction and surface complexation are involved on the iron oxide minerals. The reaction constants of surface electrostatic adsorption are usually one to three orders in magnitude, larger than that of surface complexation. The concentration-dependent isotherms can be well fitted by Langmnir equation with the correlation coefficient R〉0.93 for kaolinite and iron oxides. The maximum adsorption is found in the order： hematite 〉 lepidocrocite 〉 goethite 〉 kaolinite 〉 quartz 〉 montmorillonite ≈ illite, which can be interpreted by consideration of both reaction mechanism and surface hydroxyl density. The significant adsorption of PCP onto mineral surfaces suggests that clay and iron oxide minerals will play an important role as HIOCs are adsorbed in laterite or latertoid soil, which is widespread in South China.     

Mesozoic Bimodal Volcanic Suite in Zhalantun of the Da Hinggan Range and Its Geological Significance： Zircon U-Pb Age and Hf Isotopic Constraints

1 Introduction Mesozoic volcano-intrusive rocks are widely distributed in the Da Hinggan Range of northeastern China, and are considered as one of the most spectacular geological sights in eastern Asia. Recently, studies on granites with high εNd(t) values and Phanerozoic crustal growth in the Centra Asian Orogenic Belt have greatly promoted fundamental research into the geology of this area (Jahn et al., 2000, 2001, 2004; Wu et al., 2000, 2002, 2003). However, work on the eruption time,…     

Absorption of Arsenite on Several Iron （Hydro-）Oxides and Impact from Pre-processing Methods

The absorption reactions of arsenite on Fe （hydro-）oxides are studied. The three absorbent types are Fe（OH）3 gel and two Fe （hydro-）oxides, in which the Fe（OH）3 gel was dried in a microwave oven under vacuum at 80℃. It is found that pH changes from 9.71 to 10.36 in 6 minutes after the Fe （OH）3 gel was mixed with NaAsO2 solution, as the arsenite replaces the OH- in goethite and Fe（OH）3. At the 40th minute after the start of the reaction, pH decreases, which is most probably because that the monodentate surface complex of absorbed arsenite has changed into mononuclear-bidentate complex and released proton. The decline in pH values indicates not the end of the absorption but a change in the reaction type. Temperature and dissolved gas has little effect on these two types of reactions. The total absorption of arsenite increases after the absorbent is irradiated with ultrasound, which also lead to difficulty in separating the solids from solution. The absorption capacity for arsenite of Fe（OH）3 gel dried in a microwave oven under vacuum is 53.18% and 17.22% respectively better than that of Fe （OH）3 gel and gel dried at 80℃. The possible reasons are that the water molecules in the gel vibrates with high frequency under the effect of microwave irradiation, thereby producing higher porosity and improved surface activity.     

基于小波变换的射频干扰消除方法的研究

在射电天文观测中,射频干扰(Radio Frequency Interference, RFI)会以多种形式混入望远镜接收系统,给观测带来误判或者降低观测信噪比.近年来国内国际射电天文快速发展,国内国际大型射电望远镜和阵列先后建设,观测灵敏度大为提高,射频干扰的影响尤为突出.随着科技发展和人类活动的加剧,射频干扰日益严重且不可逆转.提出利用2维离散小波变换的方法分析射电天文观测的数据,对望远镜系统输出的时间频率序列进行小波变换,根据小波系数分离出原始信号中各分量,每个分量统计得到相应的阈值,将各分量与阈值相比较识别干扰成分并标记去除.利用该方法对实际观测数据进行了处理,结果表明该方法能够很好地标记并消减干扰信号,且提高了观测的信噪比.     

Early solar system aqueous activity: K isotope evidence from Allende

The alkali element K is moderately volatile and fluid mobile; thus, it can be influenced by both primary processes (evaporation and recondensation) in the solar nebula and secondary processes (thermal and aqueous alteration) in the parent body. Since these primary and secondary processes would induce different isotopic fractionations, K isotopes could become a potential tracer to distinguish them. Using recently developed methods with improved precision (0.05‰, 95% confidence interval), we systematically measured the K isotopic compositions and major/trace elemental compositions of chondritic components (18 chondrules, 3 CAIs, 2 matrices, and 5 bulks) in the carbonaceous chondrite fall Allende. Among all the components analyzed in this study, CAIs, which formed initially under high‐temperature conditions in the solar nebula and were dominated by nominally K‐free refractory minerals, have the highest K₂O content (average 0.53 wt%) and have K isotope compositions most enriched in heavy isotopes (δ⁴¹K: ?0.30 to ?0.25‰). Such an observation is consistent with previous petrologic studies that show CAIs in Allende have undergone alkali enrichment during metasomatism. In contrast, chondrules contain lower K₂O content (0.003–0.17 wt%) and generally lighter K isotope compositions (δ⁴¹K: ?0.87‰ to ?0.24‰). The matrix and bulks are nearly identical in K₂O content and K isotope compositions (0.02–0.05 wt%; δ⁴¹K: ?0.62 to ? 0.46‰), which are, as expected, right in the middle of CAIs and chondrules. This strongly indicates that most of the chondritic components of Allende suffered aqueous alteration and their K isotopic compositions are the ramification of Allende parent‐body processing instead of primary nebular signatures. Nevertheless, we propose the small K isotope fractionations observed (< 1‰) among Allende components are likely similar to the overall range of K isotopic fractionation that occurred in nebular environment. Furthermore, the K isotope compositions seen in the components of Allende in this study are consistent with MC‐ICP‐MS analyses of the components in ordinary chondrites, which also show an absence of large (10‰) isotope fractionations. This is not expected as evaporation experiments in nebular conditions suggest there should be large K isotopic fractionations. Nevertheless, possible nebular processes such as chondrules back exchanging with ambient gas when they formed could explain this lack of large K isotopic variation.     

福建地壳运动观测网络观测成果初步分析

利用最新GAMIT软件,对福建省地壳运动观测网络的厦门、福州、泉州、龙岩、南平5个GPS基准站2004年3月1日至2005年3月6日的观测资料在ITRF2000全球坐标系统框架下,使用IGS精密星历数据及其核心观测站的坐标和运动速率为控制参数进行了统一解算,并利用GLOBK软件进行联合平差,得到了5个测站的观测精度。结果表明,福建地区形变南强北弱、东强西弱,且该地区随中国大陆较均匀地向SE（SEE）方向运动。