Mixing of Enriched Lithospheric Mantle-Derived and Crustal Magmas: Evidence from the Habo Cenozoic Porphyry in Western Yunnan

New zircon U–Pb ages, whole-rock geochemistry and zircon Hf isotopes from the Habo porphyry Western Yunnan, China, were determined to provide constraints on the timing of uplift of the Eastern Tibetan Plateau. The intrusive rocks consist of shoshonitic porphyry (syenite porphyry and monzonite porphyry). Zircon laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) U–Pb dating indicates coeval emplacement ages of ~35 Ma. The porphyries have alkaline affinities, enrichment in large ion lithophile elements (LILEs) and light rare earth elements (LREEs) (e.g., Rb, Th, U, Pb), with depletion of high field strength elements (HFSEs) (e.g., Nb, Ti, Ta) and weak Eu anomalies. They display uniform Lu–Hf isotopic compositions with negative zircon εHf(t) values ranging from -3.9 to -0.6. The chemical characteristics of the syenite porphyries indicated that they most likely originated from the lower crust, with mantle-derived material involved in their generation. Geochemically, the monzonite porphyries are similar to the syenite porphyries; however, the lower MgO contents suggest that they were produced by different degrees of partial melting of the same lower crust source. Combined with the geochemical and isotopic data in this paper, imply that the alkali-rich porphyries of the Habo polymetallic deposit were derived from the partial melting of lower crust, enriched by mantle magma, formed in a conversion stage from stress extrusion (a strike-slip shear process) to local stress relaxation (a strike-slip pull-apart process) at the Ailaoshao tectonic zone.     

高效液相色谱-电感耦合等离子体质谱联用检测土壤中的无机硒形态

土壤样品中亚硒酸盐Se(Ⅳ)和硒酸盐Se(Ⅵ)的形态分析中,提取剂的选择和检测方法是技术的关键。以往的提取剂容易导致硒形态发生转变或无法同时提取Se(Ⅳ)和Se(Ⅵ),常用的氢化物发生原子荧光光谱法无法直接测定Se(Ⅵ),而是通过差减法得出Se(Ⅵ)含量。本文对比了不同提取剂的提取能力,确定使用0. 1 mol/L氢氧化钠溶液作为提取剂,在55℃超声萃取土壤样品30 min,提取液经高效液相色谱分离,电感耦合等离子体质谱检测,建立了土壤中Se(Ⅳ)和Se(Ⅵ)的形态分析方法。采用Hamilton PRP X-100色谱柱,以6 mmol/L柠檬酸为流动相,pH=5. 5,在8 min内可完全分离Se(Ⅳ)和Se(Ⅵ),两者的检出限分别为0. 15μg/L、0. 16μg/L,线性相关系数(r~2)均大于0. 999。以土壤为基体进行加标回收试验,Se(Ⅳ)和Se(Ⅵ)的回收率在84. 2%～95. 8%之间,相对标准偏差为1. 4%～5. 3%(n=6)。该方法简单快速,具有良好的精密度和准确度,适用于土壤中无机硒的形态分析。     

内蒙古翁公敖包航磁异常的推断与解释

文章对内蒙古四子王旗—土默特右旗中北部近年发现的翁公敖包航磁异常进行推断与解释,在对找矿有望的航磁异常进行筛选后,对翁公敖包航磁异常进行了野外地质-地球物理查证,确定异常为铁矿所致;采用向上延拓、垂向导数、斜导数及小波变换等方法对航磁异常进行数据转换处理,以获取铁矿体的横向及纵向分布信息,取得了较好的效果。     

郑洛地区史前聚落分布特征的空间自相关分析

针对郑洛地区史前聚落遗址点的空间分布特征的问题,该文提出了一种空间自相关分析方法,以不同的格网尺度研究郑洛地区4个文化时期的遗址点的空间分布特征。研究发现:5 000~12 000m的格网尺度最能表现出裴李岗文化时期、仰韶文化前期、仰韶文化后期和龙山文化时期这4个文化时期全局自相关的差异。从局部自相关所表现出的变化情况来看,6 000~10 000m这一范围的格网尺度是最能保留住郑洛地区这4个文化时期遗址点的空间分布特征。将空间自相关分析应用于史前聚落考古研究中,可以探讨史前聚落考古中遗址点的空间分布模式及其变化。这不仅为史前聚落考古提供了一种新的思维方式,也扩展了史前聚落考古理论方面的研究。     

滇中地区因民角砾岩类型、特征及找矿意义

滇中地区“因民角砾岩”的成因及归属问题目前暂无定论。笔者通过对东川-易门地区前人所划的因民组“因民角砾岩”进行1：5万野外地质调查工作,对其进行了初步的分类。根据其成因及时代划分为复成分砾岩、冰碛砾岩、滑塌角砾岩、引爆角砾岩和构造角砾岩。对“因民角砾岩”成因及时代的研究,特别是“冰碛砾岩、复成分砾岩”的提出,对于解决滇中早前寒武纪地层层序、时代归属、构造格架、大地构造位置及大区域地层对比,探讨滇中元古宙地史演化、古环境研究以及指导找矿都具有重要的指示意义。     

The U-Pb Geochronology and Lu-Hf Isotope Compositions of Detrital Zircons from the Nanhua Group of the Longsheng Region, South China and their Implications for Pan-African Events

It is unclear whether the South China blocks have an affinity with continental Gondwana due to a lack of direct Pan-African magmatic and metamorphic features. In this study, we conducted U-Pb geochronological and Lu-Hf isotopic analyses for detrital zircons from a sandstone of the Chang’an Formation of the Nanhua Group in the Longsheng region of northern Guangxi, with the aim of constraining the timing of sedimentation and information as to its source, as well as seeking evidence for Pan-African events in the South China blocks. The results show that the ages of detrital zircons peaked at 654.7 ± 6.2 Ma, 773.2 ± 4.1 Ma and 821.9 ± 6.5 Ma, with some at 920–870 Ma; the youngest age indicates the existence of the Pan-African thermal event. The εHf(t) and TDM2 values demonstrate that the study area has experienced three stages of crustal growth at 3.0–2.4 Ga, 2.1–1.5 Ga and 1.3–0.9 Ga. With intensively distributed Neoproterozoic mafic-ultramafic and granitic plutons emplaced at 830–810 Ma along the southwestern section of the Jiangnan Orogenic Belt and positive εHf(t) values from a large group of zircon grains, it is proposed that the sediments of the Chang’an Formation (of Nanhua Group) were largely sourced from the southeastern margin of the Yangtze block. Comparison with the zircon age spectra of the Cathaysian block shows that about 79% of the Pan-African aged detrital zircon grains that have TDM2 = 1352–1031 Ma and εHf(t) = 3.68–8.79, were sourced from the recycled Grenvillian crust of the Cathaysian block, suggesting that the Cathaysian block had a close connection with Gondwana.     

西准噶尔达尔布特蛇绿岩带萨尔托海岩体深部结构、构造特征:地质与地球物理证据

西准噶尔地区分布多条蛇绿混杂岩带,地表地质已有大量研究成果,但蛇绿岩深部结构构造研究相对薄弱,一定程度上制约了该地区地质构造演化的深入认识.为此,本文选取达尔布特蛇绿混杂岩带萨尔托海段开展了大比例尺地质填图配套地面重力、磁法和可控源音频大地电磁测深(CSAMT)等综合测量,获得了该蛇绿岩体地表分布、接触关系以及深部的磁性、密度结构和电性特征,精细刻画了蛇绿岩的深部结构与构造,并进一步分析了其侵位机制和动力学过程.萨尔托海蛇绿岩具有低重力、高磁性和变化范围较宽的电阻率值,岩体整体以构造岩块状产出,表现出挤压逆冲、走滑剪切、破碎蚀变等变形变质.本文及前人研究成果表明,萨尔托海岩体是在近东西向挤压兼走滑应力作用下以斜向楔冲形式构造就位,并进一步受到后期左行走滑和岩浆作用的叠加改造.结合区域构造演化,西准噶尔蛇绿岩的构造侵位与晚石炭世板块汇聚背景下残余洋盆的收缩有关,持续的挤压兼走滑应力使残余洋盆下伏基底蛇绿岩沿断裂构造侵位于上覆沉积地层.     

微生物对地下水中萘的降解特性及动力学研究

针对我国东北某石油烃污染场地地下水中的萘污染,筛选出了Acinetobacter和Pseudomonas菌属的高效萘降解菌群。该菌群对萘的耐受性较高,且具有良好的乳化性,能够自动调节细胞表面疏水性和自聚集性。不同pH值、萘初始浓度、温度和菌接种量对萘降解效率的影响研究表明:最适菌群生长的pH范围为7.08.0;萘降解效率和速率在1.005.00 mg/L范围内与其初始浓度成正比;在1030 ℃温度范围内均表现出较高的萘降解效率。在此基础上,利用Guass、GuassAmp、LogNomal、Poisson和Pulse数学模型对萘的降解过程进行拟合,其降解速率更符合GuassAmp模型。通过将降解动力学模型中的常数与影响因素相关联,推导出了拟合度较高的多因素影响下的萘降解动力学方程。