A non-linear stress-stiffness model for geomaterials at small to intermediate strains

A double exponential fitting model (DEFM) capable of expressing the non-linear stress-stiffness relationship of geomaterials has been proposed by Shibuya et al. (1997). The model comprises two material constants; the elastic stiffness at very small strains and the strength, together with other free parameters to determine the complete stress-stiffness relationship. In this paper, the capability of the original function used for DEFM in simulating the tangent stiffness-stress relationship of geomaterials is first discussed. Second, the methods for determining the free model parameters, as well as its conversion to obtain a stress-strain relationship are proposed. The applicability of DEFM to predicting non-linear stress-stiffness relationship is examined in detail in a total of forty-nine fitting cases of compression test data on sedimentary rock, artificial soft rock and soft clay. It is found that the DEFM is effective in expressing the non-linear stress-stiffness relationship of various kinds of geomaterials at small to intermediate strains, say less than 0.5%. The superiority of this model compared to other fitting models currently in use is also demonstrated in some of the fitting cases.     

Capture-zone design in an aquifer influenced by cyclic fluctuations in hydraulic gradients

Design of a groundwater pumping and treatment system for a wood-treatment facility adjacent to the tidally influenced Fraser River estuary required the development of methodologies to account for cyclic variations in hydraulic gradients. Design of such systems must consider the effects of these cyclic fluctuations on the capture of dissolved-phase contaminants. When the period of the cyclic fluctuation is much less than the travel time of the dissolved contaminant from the source to the discharge point, the hydraulic-gradient variations resulting from these cycles can be ignored. Capture zones are then designed based on the average hydraulic gradient determined using filter techniques on continuous groundwater-level measurements. When the period of cyclic fluctuation in hydraulic gradient is near to or greater than the contaminant travel time, the resulting hydraulic-gradient variations cannot be ignored. In these instances, procedures are developed to account for these fluctuations in the capture-zone design. These include proper characterization of the groundwater regime, assessment of the average travel time and period of the cyclic fluctuations, and numerical techniques which allow accounting for the cyclic fluctuations in the design of the capture zone. Electronic Publication     

18OSO4 and 18OH2O as prospective indicators of elevated arsenic in the Goose River ground-watershed, Maine

Anomalous geogenic arsenic occurs in drinking water from the Goose River crystalline ground-watershed in mid-coastal Maine. Isotope investigations were useful in understanding release areas of arsenic into affected water wells. The isotope composition of sulfate associated with probable arsenian pyrite oxidation is described. Correlation of '¹⁸O_SO4 enrichment [+4.57 to +7.46‰ Vienna Standard Mean Ocean Water (VSMOW)] is discussed with specific and recurring areas of elevated arsenic (10-52 µg l^-1). Although arsenic concentrations were highly variable over 2 years per well, '¹⁸O_SO4 values were always consistent and suggested a specific and consistent risk for elevated arsenic occurrences for each well. The '¹⁸O values in the water molecule (-12.07 to -8.81‰ VSMOW) and the '¹⁸O_SO4 values may serve as prospective indicators of prominent zones of aeration at depth in discrete fracture zones. The '¹⁸O values in the water molecule and sulfate ion appear to indicate that more than 60% of O₂ incorporated into the SO₄^2- ion are from dissolved oxygen and belong to distinct fractured areas. These aeration zones or oxidation fronts, as outlined by oxygen isotopes, are sentinels for high arsenic risk in groundwater.     

Cordieritite and Leucogranite Formation during Emplacement of Highly Peraluminous Magma: the El Pilon Granite Complex (Sierras Pampeanas, Argentina)

Cordieritites and highly peraluminous granites within the ElPilón granite complex, Sierras Pampeanas, Argentina,were emplaced during a medium-P, high-T metamorphic event duringthe initial decompression of a Cambrian orogen along the southwesternmargin of Gondwana. Very fresh orbicular and massive cordierititebodies with up to 90% cordieritite are genetically associatedwith a cordierite monzogranite pluton and a larger body of porphyriticgranodiorite. The petrogenesis of this association has beenstudied using petrographical, mineralogical, thermobarometric,geochemical, geochronological and isotope methods. The graniticmagmas were formed by anatexis of mid-crustal metamorphic rocksformed earlier in the Pampean orogeny. The cordieritites appearat the top of feeder conduits that connected the source regionlocated at     

Mantle Sources and the Highly Variable Role of Continental Lithosphere in Basalt Petrogenesis of the Kerguelen Plateau and Broken Ridge LIP: Results from ODP Leg 183

Ocean Drilling Program (ODP) Leg 183 was designed to investigatethe origin and evolution of the large igneous province composedof the Kerguelen Plateau and Broken Ridge. Of the eight sitesdrilled, basalt was recovered from seven, five on the plateauand two on Broken Ridge. We present results from four of thesesites, 1136, 1138, 1141 and 1142. Although this large igneousprovince is interpreted as being derived from the Kerguelenmantle plume, the geochemical characteristics of basalt fromsome parts of the province indicate a role for continental lithosphere.The 118–119 Ma basalt flows recovered in the SouthernKerguelen Plateau (Site 1136) have a more subtle continentalsignature than shown by basalt at Leg 119 Site 738. A continentalsignature is absent in the 100–101 Ma tholeiitic basaltsat Site 1138 in the Central Kerguelen Plateau (CKP); their age-correctedNd–Sr–Pb isotopic values and incompatible elementratios are similar to those estimated for primitive mantle.These flows may represent a major mantle source in the Kerguelenstarting-plume head. The 20 basalt units identified are a productof magma chamber replenishment, fractional crystallization,and resorption of crystallizing phases. The topmost unit, Unit1, is a dacite that evolved from a basalt magma similar to thoserepresented by Units 3–22; unlike the basalts the dacitemagma was probably influenced by continental material. MiddleCretaceous (     

The Fish Canyon Magma Body, San Juan Volcanic Field, Colorado: Rejuvenation and Eruption of an Upper-Crustal Batholith

More than 5000 km³ of nearly compositionally homogeneous crystal-richdacite (     

Crustal Evolution in the SW Part of the Baltic Shield: the Hf Isotope Evidence

The results of a laser ablation microprobe–inductivelycoupled plasma mass spectrometry Lu–Hf isotope study ofzircons in 0·93–1·67 Ga rocks from southNorway indicate that early Proterozoic protoliths of the BalticShield have present-day ¹⁷⁶Hf/¹⁷⁷Hf