Comparison of Synchrotron Radiation X-Ray Fluorescence with Conventional Techniques for the Analysis of Sedimentary Samples

A comparison is made of elemental analyses of sediment samples (lake bottom sediments and sediments from the petroliferous Bazhenovka Formation) by five competitive methods (synchrotron radiation X-ray fluorescence (SR-XRF), INAA, ICP-MS, AAS and traditional XRF). The object of this study was to identify the most suitable analytical techniques for applications in sedimentary geochemistry. Advantages and shortcomings of the five techniques were considered with respect to applications related to studies of palaeo-climate changes recorded in sedimentary cores from Lake Baikal and the geochemical stratigraphy of the Bazhenovka Formation, which is rich in organic material. We have concluded that SR-XRF was the best technique for producing extensive analytical data series, from the point of view of its speed, ease of application, cost, non-destructive nature and sensitivity, which allowed for the simultaneous determination of more than twenty elements of geochemical interest in small samples of sediments. An additional benefit of the method was demonstrated when used for the independent certification of geological reference materials. International reference samples BIL-1 and SDO-1 were certified by means of this method without use of reference materials. Analyses were based on the physics of the theory of energy transport.     

Kokchetavite: a new potassium-feldspar polymorph from the Kokchetav ultrahigh-pressure terrane

Kokchetavite, a new polymorph of K-feldspar (KAlSi₃O₈), has been identified as micrometer-size inclusions in clinopyroxene and garnet in a garnet-pyroxene rock from the Kokchetav ultrahigh-pressure terrane, Kazakhstan. Kokchetavite has a hexagonal structure with a =5.27(1) Å, c=7.82(1) Å, V=188.09 ų, Z=1, and is found to be associated with phengite + /-cristobalite (or quartz) + siliceous glass ± phlogopite/titanite/calcite/zircon, occurring as multi-phase inclusions in clinopyroxene and garnet. It is concluded that kokchetavite could not be an exsolution phase in host minerals. Instead, it might be metastably precipitated from an infiltrated K-rich melt during rock exhumation. Alternatively, although less likely, kokchetavite might be derived from dehydration of K-cymrite, which, in turn, was formed at high pressures. In either case, kokchetavite is a metastable polymorph of K-feldspar.     

Time-dependent uptake of NO3 by sea salt

Using a coated-insert flow tube reactor coupled to a low-energy electron-impact mass spectrometer with molecular beam sampling, we studied uptake of NO₃ by sea salt at room temperature and [NO₃]?=?8?10¹¹???4?10¹³ molecule cm^?3. The radical uptake coefficient γ(t) is time dependent: its initial value (γ _ini) decreases exponentially with the characteristic time (τ) to its steady-state value (γ _ss) at given [NO₃]. The parameters γ _ini, γ _ss and τ depend on [NO₃], whereas γ _ss is water vapor independent at [H₂O]?=?8?10¹²???1.6?10¹⁵ molecule cm^?3 and RH ≤ 0.5 %. HCl and NO₂ are uptake products detected in the gas phase. We used these findings to estimate γ values under tropospheric conditions for urban coastal and remote marine environments: at high NO₃ (~90 ppt), the time dependence becomes important, and the γ value averaged over the aerosol lifetime is 4?10^?3; at low NO₃ (~1 ppt), the radical uptake is time independent and proceeds faster with γ _ini?=?8?10^?3     

Relation between the extreme angular and areal distortion in cartographic representation

Summary The paper presents the method of deriving representations, optimal from the point of view of global characteristics, for areal and extreme angular distortion (3), (7), if one is optional and the other characteristic is minimized at the same time. If a special minimization method (Section 5) is used for computer processing, the problem can be solved in the region of representation equations in the form of polynomials of the 3rd or 5th degree, while assuming symmetry relative to the equator and the central meridian. Thus, the method enables both the fundamental global characteristics to be regulated freely. Their dependence is illustrated in graphs (Figs 2 and 6) depending on the selected examples of representations of the whole globe. The latter shows that method is a contribution for cartographic practice as well.     

Deep structure of the lithosphere beneath the territory of Bulgaria

Summary Teleseismic P residuals calculated for waves arriving from various azimuths and angles of incidence, and a 3-D inversion of the residuals provided the basis for characterizing the uppermost mantle structure beneath Bulgaria. The Moesian Platform and the Rhodopean Massif are two different blocks characterized by a lithosphere thickness of about 130–140 km with a zone of lithosphere thinning along their contact. Both units have opposite patterns of the directional dependence of relatively high and low P velocities. This directional dependence is interpreted by dipping anisotropic structures in the subcrustal lithosphere, which probably represent remnants of paleosubductions of an old oceanic lithosphere.

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Klasse Äquivalenter,in Meridianen äquidistanter Abbildungen

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Elastic properties of eclogite rocks from the Bohemian massif

Summary Compressional velocity anistropy has been studied in detail at atmospheric pressure for 78 specimens of 23 types of eclogite rocks from the Bohemian massif. For nine of these rock types, compressional and shear velocities were measured as a function of pressure to750 MPa at room temperature. The velocity anisotropy for both compressional and shear waves is less than4% at high pressure. The velocities increase with increasing garnet content and decrease with increasing symplectitization. The Moldanubian eclogites have significantly higher velocities, on the average, than the eclogites from the Kruné hory crystalline complex, although the densities of both groups are comparable.     

On the accuracy of the bathymetry-generated gravitational field quantities for a depth-dependent seawater density distribution

In geophysical studies investigating the lithosphere structure, the gravitational field generated by the ocean density contrast (i.e., bathymetry-generated gravitational field) represents a significant amount of the signal to be modelled and subsequently removed from the Earth’s gravity field. The ocean density contrast is typically calculated as the difference between the mean density values of the Earth’s crust and seawater. The approximation of the actual seawater density distribution by its mean value yields relative errors up to about 2% in computed quantities of the gravitational field. To reduce these errors, a more realistic model of the seawater density distribution is utilized based on the analysis of existing oceanographic data of salinity, temperature, and pressure (depth). We study the accuracy of the bathymetry-generated gravitational field quantities formulated for a depth-dependent model of the seawater density distribution. This density distribution approximates the seawater density variations due to an increasing pressure with depth, whereas smaller lateral density variations caused by salinity, temperature, and other oceanographic factors are not taken into consideration. The error analysis reveals that the approximation of the seawater density by the depth-dependent density model reduces the maximum errors to less than 0.6%. The corresponding depth-averaged errors are below 0.1%. The depth-dependent seawater density model is further facilitated in expressions for computing the bathymetry-generated gravitational field quantities by means of the spherical bathymetric (ocean bottom depth) functions. The numerical realization reveals large differences in the results obtained with and without consideration of the depth-dependent seawater density distribution. The maxima of absolute differences reach 201 m²/s² and 16.5 mGal in computed values of the potential and attraction, respectively. The application of the depth-dependent seawater density model thus significantly improves the accuracy in the forward modelling of the bathymetric gravitational field quantities.     

Joint inversion of teleseismic P waveforms and surface-wave group velocities from ambient seismic noise in the Bohemian Massif

Joint inversion of teleseismic P-waveforms and local group velocities of surface waves retrieved from ambient seismic noise has been performed to model velocity structure of the crust and uppermost mantle of the Bohemian Massif. We analysed P-waveforms of 381 teleseismic earthquakes recorded at 54 broadband seismic stations located on the territory of the Czech Republic and in its close surroundings. Group velocities of Rayleigh and Love surface waves were obtained by cross-correlating long-term recordings of seismic noise. The basis for waveform inversion is the well-known methodology of P-to-S receiver functions constructed from converted phases. Due to instabilities in direct inversion of receiver functions caused by the necessity of applying deconvolution, we propose an alternative formulation to fit observed and calculated radial components of P waveforms. The joint inversion is transformed into a search for the minimum of the cost function defined as a weighted sum of waveform and group velocity misfits. With the use of the robust stochastic optimizer (Differential Evolution Algorithm), neither derivatives nor a starting model are needed. The task was solved for 1D layered isotropic models of the crust and the uppermost mantle. We have performed a sequence of inversions with models containing one, two, three and four layers above a half-space. By using statistical criteria (F-test) we were able to select the simplest velocity models satisfying data and representing local geological structures. Complex crustal models are typical for stations located close to boundaries of major tectonic units. The relatively low average P to S wave-velocity ratio is in agreement with the generally accepted view that the BM crust is predominantly felsic.     

First Data on Au–Sb Mineralization of the Ariadnoe Ultramafic Intrusion,Primor’e

Doklady Earth Sciences - A new promising source of mineral deposits is found in the southern part of the Far East of Russia: the Ti-bearing intrusions of ultramafic rocks of the Sikhote-Alin...