Experimental and numerical investigations on CO2 injection and enhanced gas recovery effects in Altmark gas field (Central Germany)

The feasibility of CO₂ storage and enhanced gas recovery (EGR) effects in the mature Altmark natural gas field in Central Germany has been studied in this paper. The investigations were comprehensive and comprise the characterization of the litho- and diagenetic facies, mineral content, geochemical composition, the petrophysical properties of the reservoir rocks with respect to their potential reactivity to CO₂ as well as reservoir simulation studies to evaluate the CO₂ wellbore injectivity and displacement efficiency of the residual gas by the injected CO₂. The Rotliegend sediments of the Altmark pilot injection area exhibit distinct mineralogical, geochemical, and petrophysical features related to litho- and diagenetic facies types. The reservoir rock reactivity to CO₂ has been studied in autoclave experiments and associated effects on two-phase transport properties have been examined by means of routine and special core analysis before and after the laboratory runs. Dissolution of calcite and anhydrite during the short-term treatments leading to the enhancements of permeability and porosity as well as stabilization of the water saturation relevant for CO₂ injection have been observed. Numerical simulation of the injection process and EGR effects in a sector of the Altmark field coupled with a wellbore model revealed the possibility of injecting the CO₂ gas at temperatures as low as 10 °C and pressures around 40 bar achieving effective inflow in the reservoir without phase transition in the wellbore. The small ratio of injected CO₂ volume versus reservoir volume indicated no significant EGR effects. However, the retention and storage capacity of CO₂ will be maximized. The migration/extension of CO₂ varies as a function of heterogeneity both in the layers and in the reservoir. The investigation of CO₂ extension and pressure propagation suggested no breakthrough of CO₂ at the prospective production well during the 3-year injection period studied.     

The Dnepr Canyon: evidence for a continuous submarine channel link between the outer shelf and the deep-sea basin of the northwestern Black Sea

Multibeam bathymetric surveys and single-beam profiles were collected in 2003–2010 from aboard the Ukrainian RV Professor Vodyanitskiy (cruises PV-58 and PV-60, 2003 and 2004), and the German RV Meteor (cruise M-72, legs 1 and 4, 2007) and RV Maria S. Merian (cruise MSM-15, leg 2, 2010) along the continental margin of the NW Black Sea. Integrating published, reprocessed and novel data has revealed the existence of a major continuous channel extending from the Dnepr paleo-delta into greater water depths. It is more than 90 km long, 1.1 km wide and up to 125 m deep. On the upper slope (120–960 m water depth), a number of smaller channels merge into the large, Y-shaped Dnepr Canyon, which then continues obliquely downslope via this submarine channel to at least 1,815 m water depth off the Crimean continental margin, NW Black Sea. The channel could be an important, hitherto unknown link between the shallow oxic and deep anoxic environments of the Black Sea, along which sediment and organic matter could be funneled into the deep-sea basin. This would have far-reaching implications for investigations dealing with marine geology and biology, climate change, as well as oil and natural gas exploitation. The unusual alignment of the channel along the margin of the basin, as well as the location and mode of channel termination in deeper waters deserve future research.     

Magnetic signature of different vegetation species in polluted environment

Detailed magnetic study on vegetation samples from several strongly polluted and clean sites in Bulgaria is carried out in order to evaluate suitability of different species as passive dust collectors in magnetometry. From each location, available species among lichens, mosses, poplar leaves, dandelion, needles have been sampled. Magnetic susceptibility calculated on mass-specific basis shows wide variability between diamagnetic signal up to 846 × 10⁻⁸ m³/kg. Lichens and mosses are found to be the species, showing magnetic signals with the strongest contrast between clean and polluted environment. The main magnetic phase is magnetite-like according to the results from thermomagnetic analysis of susceptibility on magnetic extracts. Scanning electron microscopy (SEM) microphotographs reveal the presence of abundant particulate matter on vegetation surface both with anthropogenic (spherules) and lithogenic origin. Magnetic grain size deduced by the ratio of saturation remanent magnetization (SIRM) and mass-specific magnetic susceptibility (χ) and coercivities (B_c and B_cr) suggest that different species accumulate preferentially small SD-like grains from pollution emissions. Contrasting relationship of the ratio of anhysteretic remanent magnetization (ARM) and χ for polluted vs clean sites deduced by needles and lichens may be related to transformation of the accumulated dust particles within lichens’ tissue. This finding indicates that the exact species used as biological dust collector is of importance when studying spatial grain size distribution of magnetic dust particles. Pilot study on polycyclic aromatic hydrocarbons (PAH) content and its relation to magnetic parameters shows good correspondence between high levels of PAHs and high SIRM values for locations affected by non-ferrous industrial production.     

Propagating PZ 90 to WGS 84 Transformation Parameters

The 29^th Research Institute recently published its latest transformation parameters for WGS and PZ 90. Because these tranformation parameter estimates were derived from stations located within Russia, variance-covariance propagation was carried out to study the benefits of a better global distribution of stations. An example that includes two stations in North America is presented. The transformation improves significantly. ? 1999 John Wiley & Sons, Inc.     

Stratal composition and stratigraphic organization of stratal elements in an ancient deep‐marine basin‐floor succession,Neoproterozoic Windermere Supergroup,British Columbia,Canada

Despite a globally growing seismic and outcrop analogue data set, the detailed (centimetre to decametre) internal stratal make up of deep‐marine basin‐floor ‘channelized‐lobe’ strata remain poorly known. An ancient analogue for modern, mixed‐sediment, passive margin, deep‐marine basin‐floor fans is the well‐preserved Neoproterozoic Upper and Middle Kaza groups in the southern Canadian Cordillera. This succession is a few kilometres thick and comprises six sedimentary facies representing deposition from different kinds of sediment‐gravity flows. Representative lateral and vertical assemblages of one or more of these facies comprise six stratal elements, including: isolated scours, avulsion splays, feeder channels, distributary channels, terminal splays, and distal and off‐axis fine‐grained turbidite units. The internal characteristics of the various stratal elements do not differ from more distal to more proximal settings, but the relative abundance of the various stratal elements does. The difference in relative abundance of stratal elements in the kilometre‐scale stratigraphy of the Kaza Group results in a systematic upward change in architecture. The systematic arrangement of the stratal elements within the interpreted larger bodies, or lobes, and then lobes within the basin‐floor fan, suggests a hierarchical organization. In this article a hierarchy is proposed that is based on avulsion but, also importantly, the location of avulsion. The proposed avulsion‐based hierarchical scheme will be a useful tool to bridge the scalar gap between outcrop and seismic studies by providing a single stratigraphic framework and terminology for basin‐floor stratal elements.     

The impact of diagenetic fluid–rock reactions on Rotliegend sandstone composition and petrophysical properties (Altmark area, central Germany)

In the framework of the German R&D joint project CLEAN (CO₂ large-scale enhanced gas recovery in the Altmark natural gas field), Rotliegend reservoir sandstones of the Altensalzwedel block in the Altmark area (Saxony-Anhalt, central Germany) have been studied to characterise litho- and diagenetic facies, mineral content, geochemical composition, and petrophysical properties. These sands have been deposited in a playa environment dominated by aeolian dunes, dry to wet sand flats and fluvial channel fills. The sediments exhibit distinct mineralogical, geochemical, and petrophysical features related to litho- and diagenetic facies types. In sandstones of the damp to wet sandflats, their pristine red colours are preserved and porosity and permeability are only low. Rocks of the aeolian environment and most of the channel fill deposits are preferentially bleached and exhibit moderate to high porosity and permeability. Although geochemical element whole rock content in these rocks is very similar, element correlations are different. Variations in porosity and permeability are mainly due to calcite and anhydrite dissolution and differences in clay coatings with Fe-bearing illitic-chloritic composition exposed to the pore space. Moreover, mineral dissolution patterns as well as compositions (of clays and carbonate) and morphotypes of authigenic minerals (chlorite, illite) are different in red and bleached rocks. Comparison of the geochemical composition and mineralogical features of diagenetically altered sandstones and samples exposed to CO₂-bearing fluids in laboratory batch experiments exhibit similar character. Experiments prove an increase in wettability and water binding capacity during CO₂ impact.     

Matching Martian crustal magnetization and magnetic properties of Martian meteorites

Abstract— Magnetic properties of 26 (of 32) unpaired Martian meteorites (SNCs) are synthesized to further constrain the lithology carrying Martian magnetic crustal sources. Magnetic properties of ultramafic cumulates (i.e., Chassigny, Allan Hills [ALH] 84001) and lherzolitic shergottites (ALH 77005, Lewis Cliff [LEW] 88516) are one or two orders of magnitude too weak to account for the crustal magnetizations, assuming magnetization in an Earth‐like field. Nakhlites and some basaltic shergottites, which are the most magnetic SNCs, show the right intensity. Titanomagnetite is the magnetic carrier in the nakhlites (7 meteorites), whereas in most basaltic shergottites (11 meteorites) it is pyrrhotite. Dhofar (Dho) 378, Los Angeles, and NWA 480/1460 and 2046 are anomalous basaltic shergottites, as their magnetism is mainly due to titanomagnetite. Pyrrhotite should be among the candidate minerals for the magnetized Noachian crust.     

Linear MHD Sausage Waves in Compressible Magnetically Twisted Flux Tubes

Oscillations of magnetic flux tubes are of great importance as they contain information about the geometry and fine structure of the flux tubes. Here we derive and analytically solve in terms of Kummer’s functions the linear governing equations of wave propagation for sausage surface and body modes (m=0) of a magnetically twisted compressible flux tube embedded in a compressible uniformly magnetized plasma environment in cylindrical geometry. A general dispersion relation is obtained for such flux tubes. Numerical solutions for the phase velocity are obtained for a wide range of wavenumbers and for varying magnetic twist. The effect of magnetic twist on the period of oscillations of sausage surface modes for different values of the wavenumber and vertical magnetic field strength is calculated for representative photospheric and coronal conditions. These results generalize and extend previous studies of MHD waves obtained for incompressible or for compressible but nontwisted flux tubes. It is found that magnetic twist may change the period of sausage surface waves of the order of a few percent when compared to counterparts in straight nontwisted flux tubes. This information will be most relevant when high-resolution observations are used for diagnostic exploration of MHD wave guides in analogy to solar-interior studies by means of global eigenoscillations in helioseismology.