Integrating lysimeter drainage and eddy covariance flux measurements in a groundwater recharge model

Abstract

Field-scale water balance is difficult to characterize because controls exerted by soils and vegetation are mostly inferred from local-scale measurements with relatively small support volumes. Eddy covariance flux and lysimeters have been used to infer and evaluate field-scale water balances because they have larger footprint areas than local soil moisture measurements. This study quantifies heterogeneity of soil deep drainage (D) in four 12.5-m² repacked lysimeters, compares evapotranspiration from eddy covariance (ET_EC) and mass balance residuals of lysimeters (ETwb_Lys), and models D to estimate groundwater recharge. Variation in measured D was attributed to redirection of snowmelt infiltration and differences in lysimeter hydraulic properties caused by surface soil treatment. During the growing seasons of 2010, 2011 and 2012, ETwb_Lys (278, 289 and 269 mm, respectively) was in good agreement with ET_EC (298, 301 and 335 mm). Annual recharge estimated from modelled D was 486, 624 and 613 mm for three calendar years 2010, 2011 and 2012, respectively. In summary, lysimeter D and ET_EC can be integrated to estimate and model groundwater recharge.

Editor D. Koutsoyiannis     

Pyrolisis of phosphorylated molecules and survivability limits during the atmospheric passage in earth-like planets

There is evidence that space energy sources could give place to the appearance of phosphorylated nucleosides outside of Earth. These compounds may have been delivered mainly by interplanetary dust particles due to the lower temperatures experienced during atmospheric deceleration and impacts to the terrestrial surface. In this report, we communicate the results of pyrolytic studies to simulate atmospheric survivability of adenosine-5′-diphosphates (ADP) (and adenosine-5′-monophosphate, adenosine and adenine as degradation products) at temperatures <500°C and at various time intervals. Our results revealed that phosphorylated and non-phosphorylated nucleosides transported by IDPs having sizes of 10⁻⁶- could resist temperatures up to 500°C generated during atmospheric entry. However, atmospheric passage should not exceed a time due to the thermal lability of these molecules. Because of the high half-life showed by ADP in the presence of meteoritic powder, it is thought that extraterrestrial delivery of very complex biomolecules is more suitable under such protected conditions. These data indicate that the formation of a Fe²⁺- and/or Ca²⁺-complex could increase the stability of the molecules in the presence of meteoritic matter. Therefore, if the synthesis of nucleosides, nucleotides or oligonucleotides could take place in icy bodies, then micron-sized dust could have contributed significantly to the availability of phosphorylated nucleosides in the early Earth or in extrasolar early Earth-like planets, and thereby could have allowed the arising of an early biological activity.     

Nitrous oxide emissions from gasohol, ethanol and CNG light duty vehicles

A sample of 21 light duty vehicles powered by Otto cycle engines were tested on a chassis dynamometer to measure the exhaust emissions of nitrous oxide (N₂O). The tests were performed at the Vehicle Emission Laboratory of CETESB (Environmental Company of the State of Sao Paulo) using the US-FTP-75 (Federal Test Procedure) driving cycle. The sample tested included passenger cars running on three types of fuels used in Brazil: gasohol, ethanol and CNG. The measurement of N₂O was made using two methods: Non Dispersive InfraRed (NDIR) analyzer and Fourier Transform InfraRed spectroscopy (FTIR). Measurements of regulated pollutants were also made in order to establish correlations between N₂O and NO_x. The average N₂O emission factors obtained by the NDIR method was 78?±?41?mg.km^?1 for vehicles running with gasohol, 73?±?45?mg.km^?1 for ethanol vehicles and 171?±?69?mg.km^?1 for CNG vehicles. Seventeen results using the FTIR method were also obtained. For gasohol vehicles the results showed a good agreement between the two methods, with an average emission factor of 68?±?41?mg.km^?1. The FTIR measurement results of N₂O for ethanol and CNG vehicles were much lower than those obtained by the NDIR method. The emission factors were 17?±?10?mg.km^?1 and 33?±?17?mg.km^?1, respectively, possibly because of the interference of water vapor (present at a higher concentration in the exhaust gases of these vehicles) on measurements by the NDIR method.     

Application of FLATModel, a 2D finite volume code, to debris flows in the northeastern part of the Iberian Peninsula

FLATModel is a two-dimensional shallow-water approximation code with corrections and modifications that create a simulation tool adapted to debris-flows behaviour. FLATModel uses the finite volume method with the numerical implementation of the Godunov scheme and includes correction terms regarding the effect of flow over high slopes and curvature. Additionally, the stop-and-go phenomenon, the basal entrainment and a correction regarding the front inclination of the final deposit are incorporated into FLATModel. In addition, different flow resistance laws were integrated in the numerical code including Bingham, Herschel–Bulkley and Voellmy fluid model. Firstly, our numerical model was validated using analytical solutions of a dam-break scenario and published data on a laboratory experiment. Secondly, three real events, which occurred in the northeastern part of the Iberian Peninsula, were back-calculated. Although field observations of the three events are not very detailed, the back-analyses revealed interesting patterns on the flow dynamics, and the numerical results generally showed good agreement with field data. Comparing the different flow resistance laws, the Voellmy fluid model presents the best behaviour regarding both the flow behaviour and the deposit characteristics. Preliminary simulation runs incorporating the effect of basal entrainment offered satisfactory results, although the final volume is rather sensitive on the selected friction angle of channel-bed material. The outcomes regarding the correction of the calculated front inclination of the final deposit showed that this implementation strongly improves the simulation results and better represents steep fronts of final deposits.     

Geodetic and geophysical implications of the homogeneous reduction of pole coordinates (1899–1979)

The new series ILS (H) of pole coordinates (1899.9–1979.0) computed in a homogeneous system has been employed for the determination of the period of Chandler's component of polar motion. The comparison with a value derived from a previous series ILS (VY) shows there is no significant variation in the period in spite of the known systematic errors affecting the ILS (VY) series. Any high precision geodetic network adjustment has to take account of the pole coordinates defined by the ILS (H) series. Such long series permitted the identification of another component of polar motion with a period of about 30 years. The polhode derived from the ILS (H) series shows greater regularity than previously deduced polhodes and, therefore, we can conclude that past investigations in geodesy and geophysics trying to correlated the irregularities of the polhode with different geophysical phenomena, for instance, earthquakes, may have to be revised.     

Rhyolitic pumice in the basaltic pyroclasts from the 1971 eruption of Teneguía volcano,Canary Islands

Fragments of acid pumice have been found among the basic pyroclastics thrown out by the Teneguía volcano during its explosive phases. The presence of these pumice fragments brings up the problem of their origin and their relationships to the mechanism of the eruption.The composition of the analysed samples coincides exactly with the low temperature trough in petrogeny's residua system, albits-orthoclase-silica. The samples can be classified as rhyolites and trachytes.The authors propose that the pumice was produced by the fusion of the acid phase in a subvolcanic complex located beneath the island of La Palma.     

Extreme rainfalls in SE South America

Heavy rainfall trends in a region of south-eastern South America during 1959–2002 were discussed using daily data of 52 meteorological stations of Argentina, Brazil and Uruguay. Changes in intensity and frequency were both studied with different statistical tests and approaches to check the significance of trends of single and regional aggregated rainfall series. There were predominant positive trends in the annual maximum rainfalls, as well as a remarkable increment in the frequency of heavy rainfalls over thresholds ranging from 50 to 150 mm. However, significant positive trends were not shown in the series of annual maximums and shown only in 15% to 30% of the series of frequencies over thresholds. This lack of significance is due to the high variability of heavy rainfalls in space and time, which makes difficult their capture by single rain gauges. Thus, when the assessment of the heavy rainfall indicators of intensity and frequency were conducted at the regional and sub-regional level, it showed significant trends, both in intensity and frequency over thresholds, with a clearer signal in central and eastern Argentina between 30° and 40° S.